Reaction
ChemicalBook > CAS DataBase List > Tris[5-fluoro-2-(2-pyridinyl-kN)phenyl-kC]iridium(III)

Tris[5-fluoro-2-(2-pyridinyl-kN)phenyl-kC]iridium(III)

Reaction
Product Name
Tris[5-fluoro-2-(2-pyridinyl-kN)phenyl-kC]iridium(III)
CAS No.
370878-69-6
Chemical Name
Tris[5-fluoro-2-(2-pyridinyl-kN)phenyl-kC]iridium(III)
Synonyms
Tris[5-fL;fac-Ir(p-Fppy)3;-kC]iridium(III);Ir(p-F-ppy)3;Tris (2- (4-fluorophenyl) pyridine) iridium;Tris[5-fluoro-2-(2-pyridinyl-kN)phenyl-kC]iridium(III);TRIS[5-FLUORO-2-(2-PYRIDINYL-KN)PHENYL-KC]IRIDIUM(III),95%;Tris[5-fluoro-2-(2-pyridinyl-kN)phenyl-kC]iridium(III), 95%
CBNumber
CB93357135
Molecular Formula
C33H21F3IrN3
Formula Weight
708.76
MOL File
370878-69-6.mol
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Tris[5-fluoro-2-(2-pyridinyl-kN)phenyl-kC]iridium(III) Property

form 
Powder
color 
yellow
Sensitive 
air sensitive
InChI
InChI=1S/3C11H7FN.Ir/c3*12-10-6-4-9(5-7-10)11-3-1-2-8-13-11;/h3*1-4,6-8H;/q3*-1;+3
InChIKey
ZEBLNIAOTYJLBU-UHFFFAOYSA-N
SMILES
FC1=CC=C2C3=CC=CC=N3[Ir+3]34(N5=CC=CC=C5C5=CC=C(F)C=[C-]35)(N3=CC=CC=C3C3=CC=C(F)C=[C-]43)[C-]2=C1
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Safety

Risk Statements 
36/37/38
Safety Statements 
26
TSCA 
No
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
900538
Product name
Ir(p-F-ppy)3
Packaging
100MG
Price
$361
Updated
2025/07/31
Strem Chemicals
Product number
77-6100
Product name
Tris[5-fluoro-2-(2-pyridinyl-kN)phenyl-kC]iridium(III), 95%
Packaging
50mg
Price
$67
Updated
2024/03/01
Strem Chemicals
Product number
77-6100
Product name
Tris[5-fluoro-2-(2-pyridinyl-kN)phenyl-kC]iridium(III), 95%
Packaging
250mg
Price
$264
Updated
2024/03/01
ChemSupplyAustralia
Product number
300997
Product name
Tris[5-?fluoro-?2-?(2-?pyridinyl-?κN)?phenyl-?κC]?iridium(III), 95%
Packaging
50mg
Price
$65
Updated
2021/12/16
ChemSupplyAustralia
Product number
300997
Product name
Tris[5-?fluoro-?2-?(2-?pyridinyl-?κN)?phenyl-?κC]?iridium(III), 95%
Packaging
250mg
Price
$245
Updated
2021/12/16
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Tris[5-fluoro-2-(2-pyridinyl-kN)phenyl-kC]iridium(III) Chemical Properties,Usage,Production

Reaction

  1. Photosensitizer for the enantioselective coupling reaction between (N-arylamino)methanes and (Nmethanesulfonyl)-aldimines catalyzed by P-Spiro chiral (arylamino)phosphonium catalyst.
  2. Photocatalyst for [2+2] styrene cycloadditions.
  3. Photocatalyst for azoylation of trimethoxybenzene by via C−H functionalization. 

Uses

Ir(p-F-ppy)3 is a photocatalyst that readily facilitates the decarboxylative arylation of α-amino acids using visible light.

reaction suitability

core: iridium
reagent type: catalyst
reaction type: Photocatalysis

Tris[5-fluoro-2-(2-pyridinyl-kN)phenyl-kC]iridium(III) Preparation Products And Raw materials

Raw materials

Preparation Products

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Tris[5-fluoro-2-(2-pyridinyl-kN)phenyl-kC]iridium(III) Suppliers

Alfa Chemistry
Tel
1-516-6625404
Fax
1-516-927-0118
Email
support@alfa-chemistry.com
Country
United States
ProdList
9171
Advantage
60
Aladdin Scientific
Tel
Email
tp@aladdinsci.com
Country
United States
ProdList
52923
Advantage
58
Strem Chemicals, Inc.
Tel
--
Fax
--
Email
info@strem.com
Country
United States
ProdList
4910
Advantage
86
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View Lastest Price from Tris[5-fluoro-2-(2-pyridinyl-kN)phenyl-kC]iridium(III) manufacturers

Xian confluore Biological Technology Co., Ltd.
Product
fac-Ir(p-Fppy)3 370878-69-6
Price
US $0.00/mg
Min. Order
250mg
Purity
>95.00%
Supply Ability
250mg
Release date
2024-03-30