Trifluoromethanesulfonimide

ChemicalBook > CAS DataBase List > Trifluoromethanesulfonimide

Trifluoromethanesulfonimide

Product Name: Trifluoromethanesulfonimide
CAS No.: 82113-65-3
Chemical Name: Trifluoromethanesulfonimide
Synonyms: Bis(trifluoromethanesulfonyl)imide;bis(Trifluoromethanesulphonyl)imide;bis(trifluoromethanesulfonyl)amide;BISTRIFLUOROMETHANESULFONIMIDE;BIS(TRIFLUOROMETHANESULFONYL)AMINE;Bis[(trifluoroMethyl)sulphonyl]aMine;SKL1549;Trifluoromethansulfonimide;TRIFLUOROMETHANSULFONAMIDE;TRIFLUOROMETHANESULFONIMIDE
CBNumber: CB9355545
Molecular Formula: C2HF6NO4S2
Formula Weight: 281.15
MOL File: 82113-65-3.mol

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Trifluoromethanesulfonimide Property

Melting point:: 52-56 °C
Boiling point:: 90-91 °C(lit.)
Density: 1.36
storage temp.: 2-8°C
solubility: 800g/l Risk of violent reaction.
form: Crystals
pka: -10.42±0.40(Predicted)
color: Colorless to brownish
PH: 0.8 (100g/l, H2O, 20℃)Risk of violent reaction.
BRN: 4754101
Stability:: Stable. Incompatible with strong oxidizing agents. Reacts violently with water.
InChIKey: ZXMGHDIOOHOAAE-UHFFFAOYSA-N
LogP: -0.771 at 25.5℃ and pH6.7
CAS DataBase Reference: 82113-65-3(CAS DataBase Reference)
EPA Substance Registry System: Methanesulfonamide, 1,1,1-trifluoro-N-[(trifluoromethyl)sulfonyl]- (82113-65-3)

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Safety

Hazard Codes: C
Risk Statements: 34-40-14-67-37
Safety Statements: 26-36/37/39-45-8
RIDADR: UN 3265 8/PG 2
WGK Germany: 3
F: 3-10-21
Hazard Note: Corrosive
HazardClass: 8
PackingGroup: I
HS Code: 29350090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H301Toxic if swalloed

H318Causes serious eye damage

H412Harmful to aquatic life with long lasting effects

Precautionary statements

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 15220
Product name: Bis(trifluoromethane)sulfonimide
Purity: purum, ≥95.0% (19F-NMR)
Packaging: 5g
Price: $172
Updated: 2024/03/01

Sigma-Aldrich

Product number: 15220
Product name: Bis(trifluoromethane)sulfonimide
Purity: purum, ≥95.0% (19F-NMR)
Packaging: 25g
Price: $283
Updated: 2024/03/01

TCI Chemical

Product number: B2541
Product name: Bis(trifluoromethanesulfonyl)imide
Purity: >99.0%(T)
Packaging: 5g
Price: $48
Updated: 2024/03/01

TCI Chemical

Product number: B2541
Product name: Bis(trifluoromethanesulfonyl)imide
Purity: >99.0%(T)
Packaging: 25g
Price: $141
Updated: 2024/03/01

Sigma-Aldrich

Product number: 464635
Product name: Trifluoromethanesulfonimide
Purity: ≥95.0% (19F-NMR)
Packaging: 5g
Price: $109
Updated: 2024/03/01

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Trifluoromethanesulfonimide Chemical Properties,Usage,Production

Chemical Properties

light yellow to brown liquid

Uses

1,1,1-Trifluoro-N-((trifluoromethyl)sulfonyl)methanesulfonamide is commonly used as a strong acid to prepare Lewis Acid catalysts. It can also be used to improve efficiency of graphene/silicon Schottky solar cells by chemical doping and as a solvent for recycling battery electrodes.

Uses

Trifluoromethanesulfonimide may be used as a catalyst for the preparation of 1-substituted-1H-1,2,3,4-tetrazoles.

Uses

Trifluoromethanesulfonimide is a strong acid, used in the preparation of highly efficient Lewis acid catalysts.

Application

Trifluoromethanesulfonimide may be used in the following studies:
As catalyst during the polymerization of octamethylcyclotetrasiloxane in the presence of hexamethyldisiloxane.
As efficient catalyst in the synthesis of various non-reducing disaccharides, via ketopyranosylation of 2,3,4,6-tetra-O-benzyl-1-C-methyl-D-hexopyranoses.
Starting material for preparing the N-fluoro derivative, a reactive fluorinating agent.
As a component of solid polymer electrolytes.

General Description

Bis(trifluoromethane)sulfonimide (TFSI, Tf₂N) is utilized as anion species to form 1-ethyl-3-methylimidazolium molten salts. It undergoes acid-base complexation with rod-like poly(2,5-pyridine) to afford highly-ordered lamellar self-assemblies in the hydrated films.

Trifluoromethanesulfonimide Preparation Products And Raw materials

Raw materials

Preparation Products

1-BUTYL-1-METHYLPYRROLIDINIUM BIS(TRIFLUOROMETHYLSULFONYL)IMIDE

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View Lastest Price from Trifluoromethanesulfonimide manufacturers

Shanghai UCHEM Inc.

Product: Bis(trifluoromethane)sulfonimide 82113-65-3
Price: US $24.00-327.00/g
Min. Order: 25g
Purity: 0.98
Supply Ability: 100kg
Release date: 2023-11-23

Hebei Yanxi Chemical Co., Ltd.

Product: TRIFLUOROMETHANESULFONIMIDE 82113-65-3
Price: US $25.00-5.00/kgkg
Min. Order: 1kgkg
Purity: 0.99
Supply Ability: 20tons
Release date: 2023-10-09

Hebei Guanlang Biotechnology Co., Ltd.

Product: TRIFLUOROMETHANESULFONIMIDE 82113-65-3
Price: US $0.00-0.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 500000kg
Release date: 2023-01-04

82113-65-3, TrifluoromethanesulfonimideRelated Search:

Bis(4-biphenylyl)amine Bis(triphenylphosphine)palladium(II) chloride Didecyl dimethyl ammonium chloride Didecyldimethylammonium bromide Dicyclopropane methylamine Triethylsulfonium bis(trifluoromethylsulfonyl)imide Trifluoromethanesulfonimide 1-BUTYL-1-METHYLPYRROLIDINIUM BIS(TRIFLUOROMETHYLSULFONYL)IMIDE N-(5-CHLORO-2-PYRIDYL)BIS(TRIFLUOROMETHANESULFONIMIDE) 1-BUTYL-3-METHYLIMIDAZOLIUM BIS(TRIFLUOR N-Phenyl-bis(trifluoromethanesulfonimide) TRIHEXYL(TETRADECYL)PHOSPHONIUM BIS(TRIFLUOROMETHYLSULFONYL)IMIDE N-(2-PYRIDYL)BIS(TRIFLUOROMETHANESULFONIMIDE) 1-ETHYL-3-METHYLIMIDAZOLIUM BIS(TRIFLUOROMETHYLSULFONYL)IMIDE Lithium bis(trifluoromethanesulphonyl)imide MAGNESIUM TRIFLUOROMETHANESULFONIMIDE Methanesulfonamide Trifluoromethane

TRIFLUOROMETHANESULFONIMIDE

Bis(trifluoromethanesulfonyl)amine, Bis(trifluoromethylsulfonyl)amine

Bis(trifluoromethane)sulfonimide,Bis(trifluoromethanesulfonyl)amine, Bis(trifluoromethylsulfonyl)amine

Trifluoromethanesulfonimide,Bis(trifluoromethanesulfonyl)amine

Trifluoromethansulfonimide

bis(Trifluoromethanesulphonyl)imide

BISTRIFLUOROMETHANESULFONIMIDE SOL., ~0. 5 M IN DICHLOROM.

N,N-Bis(trifluoromethylsulfonyl)amine

bis(trifluoromethane)sulfonimide solution

Methanesulfonamide, 1,1,1-trifluoro-N-((trifluoromethyl)sulfonyl)-

N,N-Bis-(trifluoromethylsulfonyl)-imide

TRIFLUOROMETHANSULFONAMIDE

Bis(trifluoromethanesulfonyl)imide,99%

bis(trifluroMethanesulfonyl) iMide

Bis(trifluoroMethanesulfonyl)iMide, 99% 5GR

TrifluoroMethanesulfoniMide 95%

Bis(trifluoromethylsulfonyl)imide for synthesis

TRIFLUOROMETHANESULFONIMIDE 82113-65-3 Bis(trifluoromethane)sulfonimide

bis(trifluoromethanesulfonyl)amide

Bis(trifluoromethane)sulfonimide in stock Factory

N,N-Bis(trifluoromethanesulfonyl)imide, 20mM in nitromethane

Bis[(trifluoroMethyl)sulphonyl]aMine

1,1,1-Trifluoro-N-[(trifluoromethyl)sulphonyl]methanesulphonamide

Bis(trifluoromethanesulfonyl)imide

BIS(TRIFLUOROMETHANESULFONYL)AMINE

BIS(TRIFLUOROMETHYLSULFONYL)AMINE

BIS(TRIFLUOROMETHANE)SULFONAMIDE

BISTRIFLUOROMETHANESULFONIMIDE

bistrifluoromethanesulfonimidesol.

1,1,1-TRIFLUORO-N-[(TRIFLUOROMETHYL)SULFONYL]METHANESULFONAMIDE

Bis(trifluoroMethane)sulfoniMide puruM, >=95.0% (19F-NMR)

N,N-BIS(TRIFLUOROMETHYLSULPHONYL)AMINE

N,N-BIS(TRIFLUOROMETHANESULFONYL)IMIDE

N,N-BIS(TRIFLUOROMETHANESULFONYL)IMIDE ACID

SKL1549

82113-65-3

822113-65-3

CF3SO22NH

C2HF6NO4S2

Synthetic Reagents

Sulfonimides/Sulfinimides

Building Blocks

Organic Building Blocks

Fluorination

C-X Bond Formation (Halogen)

Sulfur Compounds

Trifluoromethylation

Chemical Synthesis

Fluorination

Fluorination Reagents

Synthetic Reagents

Building Blocks

Organic Building Blocks

Sulfonimides/Sulfinimides

Sulfur Compounds