Triethylamine trihydrofluoride

Application

Product Name: Triethylamine trihydrofluoride
CAS No.: 73602-61-6
Chemical Name: Triethylamine trihydrofluoride
Synonyms: HF;TEA.3HF;TRIETHYLAMINE TRIS(HYDROGEN FLUORIDE);TREAT-HF;trihydrofluoride;riethylamine trihydrofluoride;TRIETHYLAMINE TRISHYDROFLUORIDE;HYDROGEN FLUORIDE TRIETHYLAMINE;MEC-82;amine trihydrofL
CBNumber: CB9356360
Molecular Formula: C6H18F3N
Formula Weight: 161.21
MOL File: 73602-61-6.mol

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Triethylamine trihydrofluoride Property

Melting point:: -29--27°C
Boiling point:: 70 °C15 mm Hg(lit.)
Density: 0.989 g/mL at 25 °C(lit.)
refractive index: n20/D 1.3915(lit.)
Flash point:: 190 °F
storage temp.: Store below +30°C.
solubility: soluble in Chloroform, Hexane
form: Liquid
Specific Gravity: 0.989
color: Clear yellow to brown
PH: 3 (H2O, 20℃)(saturated aqueous solution)
Water Solubility: soluble
Sensitive: Hygroscopic
BRN: 5522945
Exposure limits: ACGIH: TWA 2.5 mg/m3
NIOSH: IDLH 250 mg/m3
CAS DataBase Reference: 73602-61-6(CAS DataBase Reference)
EPA Substance Registry System: Ethanamine, N,N-diethyl-, trihydrofluoride (73602-61-6)

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Safety

Hazard Codes: T+,T,C,Xi,F
Risk Statements: 26/27/28-35-36/37/38-20/21/22-11
Safety Statements: 26-36/37/39-45-7/9-36/37-36-61-29-16-3
RIDADR: UN 3265 8/PG 2
WGK Germany: 3
Hazard Note: Corrosive
TSCA: Yes
HazardClass: 8
PackingGroup: II
HS Code: 29211910

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H314Causes severe skin burns and eye damage

Precautionary statements

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P270Do not eat, drink or smoke when using this product.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 8.14371
Product name: Triethylamine trishydrofluoride
Purity: for synthesis
Packaging: 2ml
Price: $25.6
Updated: 2024/03/01

Sigma-Aldrich

Product number: 344648
Product name: Triethylamine trihydrofluoride
Purity: 98%
Packaging: 5g
Price: $28.7
Updated: 2024/03/01

Sigma-Aldrich

Product number: 8.14371
Product name: Triethylamine trishydrofluoride
Purity: for synthesis
Packaging: 10ml
Price: $79.2
Updated: 2024/03/01

Sigma-Aldrich

Product number: 344648
Product name: Triethylamine trihydrofluoride
Purity: 98%
Packaging: 1kg
Price: $1420
Updated: 2024/03/01

TCI Chemical

Product number: T2022
Product name: Triethylamine Trihydrofluoride
Purity: >95.0%(T)
Packaging: 10g
Price: $58
Updated: 2024/03/01

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Triethylamine trihydrofluoride Chemical Properties,Usage,Production

Application

The t-butyldimethylsilyl (TBDMS) group is the most widely used 2'-OH protection in synthesis of oligoribonucleotides. The TBDMS-group became much used particularly after it was combined with phosphoroamidite methodology and was also the choice when H-phosphonate based RNA-synthesis was introduced. Removal of TBDMS-protection is most commonly done with 1 M tetrabutylammonium fluoride (TBAF) in tetrahydrofuran (THF). These conditions has proven efficient.

Chemical Properties

clear yellow liquid

Uses

Triethylamine trihydrofluoride acts as a mild and selective fluorinating agent used in the synthesis of acid fluorides and alkyl fluorides. It is also used in the synthesis of vicinal difluorides from epoxides, 3-fluoroazetidine. It is utilized as a selective reagent for the cleavage of O-silyl groups in carbohydrates, nucleotides and cyanohydrins. It is actively involved in the electrochemical fluorodeiodination of alkyl iodides and fluorodesilylation in beta-lactams.

Uses

Mild and selective reagent that has been used in the fluorination of a wide variety of compounds. For a review, see Aldrichimica Acta.

General Description

Triethylamine trihydrofluoride (TREAT-HF) is a mild and selective reagent for the fluorination of a wide variety of compounds.

Triethylamine trihydrofluoride Preparation Products And Raw materials

Raw materials

Preparation Products

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Triethylamine trihydrofluoride Suppliers

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View Lastest Price from Triethylamine trihydrofluoride manufacturers

Hebei Mojin Biotechnology Co.,Ltd

Product: Triethylamine trihydrofluoride 73602-61-6
Price: US $0.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 50000KG/month
Release date: 2024-09-11

Shaanxi Dideu Medichem Co. Ltd

Product: Triethylamine trihydrofluoride 73602-61-6
Price: US $0.10/KG
Min. Order: 1KG
Purity: 99.0%
Supply Ability: 1000 tons
Release date: 2024-07-14

Henan Aochuang Chemical Co.,Ltd.

Product: Triethylamine trihydrofluoride 73602-61-6
Price: US $0.00-0.00/KG
Min. Order: 1KG
Purity: 98%
Supply Ability: 1Ton
Release date: 2022-10-08

73602-61-6, Triethylamine trihydrofluorideRelated Search:

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73602-61-6

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