4-BROMO-3-CHLOROANILINE

Product Name: 4-BROMO-3-CHLOROANILINE
CAS No.: 21402-26-6
Chemical Name: 4-BROMO-3-CHLOROANILINE
Synonyms: AKOS 90302;4-Bromo-3-chlo;EINECS 244-370-3;4-Brom-3-chloranilin;Chloro-4-bromoaniline;4-BROMO-3-CHLOROANILINE;3-Chloro-4-Bromoaniline;4-Bromo-3-chloroaniline,96%;4-Bromo-3-chlorobenzenamine;4-Bromo-3-chloroaniline >
CBNumber: CB9382316
Molecular Formula: C6H5BrClN
Formula Weight: 206.47
MOL File: 21402-26-6.mol

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4-BROMO-3-CHLOROANILINE Property

Melting point:: 74 °C
Boiling point:: 276.3±20.0 °C(Predicted)
Density: 1.722±0.06 g/cm3(Predicted)
Flash point:: >100 °C
storage temp.: Keep in dark place,Inert atmosphere,Room temperature
solubility: soluble in Methanol
form: powder to crystal
pka: 2.84±0.10(Predicted)
color: White to Light yellow
BRN: 1210160
InChI: InChI=1S/C6H5BrClN/c7-5-2-1-4(9)3-6(5)8/h1-3H,9H2
InChIKey: QLYHPNUFNZJXOQ-UHFFFAOYSA-N
SMILES: C1(N)=CC=C(Br)C(Cl)=C1
CAS DataBase Reference: 21402-26-6(CAS DataBase Reference)

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Safety

Hazard Codes: Xi,T,Xn
Risk Statements: 20/21/22-33-36/37/38-22
Safety Statements: 28-36/37-36/37/39-26-23
RIDADR: 2811
Hazard Note: Harmful
HazardClass: 6.1
PackingGroup: III
HS Code: 29214200

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H311Toxic in contact with skin

H315Causes skin irritation

H319Causes serious eye irritation

H332Harmful if inhaled

H373May cause damage to organs through prolonged or repeated exposure

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P309IF exposed or if you feel unwell:

P310Immediately call a POISON CENTER or doctor/physician.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

TCI Chemical

Product number: B3709
Product name: 4-Bromo-3-chloroaniline
Purity: >98.0%(GC)(T)
Packaging: 5g
Price: $76
Updated: 2025/07/31

TCI Chemical

Product number: B3709
Product name: 4-Bromo-3-chloroaniline
Purity: >98.0%(GC)(T)
Packaging: 25g
Price: $361
Updated: 2025/07/31

TRC

Product number: B685443
Product name: 4-Bromo-3-chloroaniline
Packaging: 500mg
Price: $70
Updated: 2021/12/16

Oakwood

Product number: 003693
Product name: 4-Bromo-3-chloroaniline
Purity: 99%
Packaging: 1g
Price: $9
Updated: 2021/12/16

Oakwood

Product number: 003693
Product name: 4-Bromo-3-chloroaniline
Purity: 99%
Packaging: 5g
Price: $10
Updated: 2021/12/16

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4-BROMO-3-CHLOROANILINE Chemical Properties,Usage,Production

Chemical Properties

off-white powder

Uses

4-Bromo-3-chloroaniline is a precursor or building block in medicine, pesticide and dyestuffs.

Synthesis

108-42-9

21402-26-6

General method: A solution was prepared by dissolving m-chloroaniline (2a or 2b) in DMF as starting material. Subsequently, another solution was prepared by dissolving NBS (92 mmol, 1.0 eq.) in 100 ml DMF. The DMF solution of m-chloroaniline was added dropwise to the DMF solution of NBS at room temperature. After the dropwise addition, the reaction mixture was stirred continuously for 3 hours at room temperature. After completion of the reaction, the reaction mixture was diluted with 500 ml of ethyl acetate and washed with 2 x 150 ml of brine. The organic phase was separated, dried with anhydrous Na2SO4, filtered and concentrated to give 4-bromo-3-chloroaniline (3a or 3b) as a brown solid in 90-92% yield. In another experiment, m-chloroaniline (2a or 2b, 0.8 mmol) was dissolved in a solvent of choice (1 ml) and a solution of NBS (0.8 mmol) in the same solvent (1 ml) was added in batches at room temperature. The reaction progression was monitored by LC-MS/MS and a final mixture containing traces of the dibrominated product was obtained.

References

[1] Medicinal Chemistry Research, 2016, vol. 25, # 4, p. 539 - 552
[2] Patent: CN107089919, 2017, A. Location in patent: Paragraph 0044; 0045; 0046; 0047
[3] Synthetic Communications, 2009, vol. 39, # 10, p. 1817 - 1824

4-BROMO-3-CHLOROANILINE Preparation Products And Raw materials

Raw materials

Preparation Products

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4-BROMO-3-CHLOROANILINE Suppliers

Americas 1 Belgium 1 Canada 1 China 171 Europe 1 Germany 7 India 21 Japan 1 Russia 1 Switzerland 1 The Netherlands 1 United Kingdom 14 United States 48 Global 269

J & K SCIENTIFIC LTD.

Tel: 18210857532; 18210857532
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Alfa Aesar

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Ark Pharm, Inc.

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Capot Chemical Co., Ltd

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Beijing Ouhe Technology Co., Ltd

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View Lastest Price from 4-BROMO-3-CHLOROANILINE manufacturers

Shaanxi Dideu New Materials Co. Ltd

Product: 4-BROMO-3-CHLOROANILINE 21402-26-6
Price: US $0.00-0.00/KG
Min. Order: 1KG
Purity: 98.0%
Supply Ability: 10000KGS
Release date: 2025-05-26

Honest Joy Holdings Limited

Product: 4-Bromo-3-chloroaniline 21402-26-6
Price: US $0.00/KG
Min. Order: 1KG
Purity: 97.4%
Supply Ability: 100 tons
Release date: 2022-01-14

Career Henan Chemical Co

Product: 4-BROMO-3-CHLOROANILINE 21402-26-6
Price: US $1.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 100kg
Release date: 2019-07-05

21402-26-6, 4-BROMO-3-CHLOROANILINERelated Search:

4-BROMO-3-CHLOROANILINE 4,6-DIBROMO-2,3-DICHLOROANILINE (N,N-Bis-t-Boc)-5-bromo-2-chloroaniline bromchlorenone 1-BROMO-2-CHLORO-4-NITROBENZENE 4-BROMO-3-CHLOROACETANILIDE 2-AMINO-3,5-DIBROMO-6-CHLOROBENZOIC ACID CHLORBROMURON 2-Bromo-5-chloroaniline 97%,2-BROMO-5-CHLOROANILINE 2,6-Dibromo-4-chloroaniline 2-Bromo-4-chloroaniline,98%,2-Bromo-4-chloroaniline 99%,2-BROMO-4-CHLOROANILINE,DISCONTINUED !2-Bromo-4-chloroaniline 5-BROMO-4'-CHLOROSALICYLANILIDE 3-bromo-2-chloroaniline 4-BROMO-2-CHLOROANILINE,4-Bromo-2-chloroaniline 98%,4-BROMO-2-CHLOROANILINE, 98+% 3-Bromo-5-chloroaniline 3-BROMO-6-CHLOROANILINE,5-BROMO-2-CHLOROANILINE 4-BROMO-3-CHLOROPHENYL ISOTHIOCYANATE 2,4-DIBROMO-3,6-DICHLOROANILINE

4-BROMO-3-CHLOROANILINE

AKOS 90302

4-BROMO-3-CHLOROANILINE PESTANAL, 250 MG

3-Chloro-4-Bromoaniline

EINECS 244-370-3

4-BROMO-3-CHLOROANILINE 98+%

4-Bromo-3-chlorobenzenamine

4-Bromo-3-chloroaniline,96%

4-Bromo-3-chlo

Chloro-4-bromoaniline

Benzenamine, 4-bromo-3-chloro-

4-Brom-3-chloranilin

(4-bromo-3-chlorophenyl)amine

4-Bromo-3-chloroaniline &gt

21402-26-6

A-BAlphabetic

Alpha sort

B

BI - BZ

Pesticides&Metabolites

API intermediates

Anilines, Amides & Amines

Bromine Compounds

Chlorine Compounds