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4-Bromo-2-chloroaniline

Product Name
4-Bromo-2-chloroaniline
CAS No.
38762-41-3
Chemical Name
4-Bromo-2-chloroaniline
Synonyms
Benzenamine, 4-bromo-2-chloro-;4-Bromo-2-chloroanil;-Bromo-2-chloroaniline;4-BROMO-2-CHLOROANILINE;4-Bromo-2-chloroanilinev;4-Bromo-2-chloroaniline >4-Bromo-2-chloroaniline 98%;4-Bromo-2-chloroaniline,99%;4-Bromo-2-chloro-phenylamine;4-BROMO-2-CHLOROANILINE, 98+%
CBNumber
CB7218516
Molecular Formula
C6H5BrClN
Formula Weight
206.47
MOL File
38762-41-3.mol
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4-Bromo-2-chloroaniline Property

Melting point:
70-72 °C (lit.)
Boiling point:
241.8±20.0 °C(Predicted)
Density 
1.6567 (rough estimate)
refractive index 
1.5400 (estimate)
storage temp. 
Keep in dark place,Inert atmosphere,Room temperature
pka
1.95±0.10(Predicted)
form 
Crystalline Powder
color 
Slightly yellow to light brown
BRN 
3117740
InChI
InChI=1S/C6H5BrClN/c7-4-1-2-6(9)5(8)3-4/h1-3H,9H2
InChIKey
INMZDDDQLHKGPF-UHFFFAOYSA-N
SMILES
C1(N)=CC=C(Br)C=C1Cl
CAS DataBase Reference
38762-41-3(CAS DataBase Reference)
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Safety

Hazard Codes 
Xn,T,Xi
Risk Statements 
20/21/22-20/21
Safety Statements 
36-23
WGK Germany 
3
Hazard Note 
Toxic
HazardClass 
IRRITANT
HS Code 
29214200
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H311Toxic in contact with skin

H315Causes skin irritation

H319Causes serious eye irritation

H332Harmful if inhaled

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P309IF exposed or if you feel unwell:

P310Immediately call a POISON CENTER or doctor/physician.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

TCI Chemical
Product number
B1993
Product name
4-Bromo-2-chloroaniline
Purity
>98.0%(GC)
Packaging
5g
Price
$39
Updated
2025/07/31
TCI Chemical
Product number
B1993
Product name
4-Bromo-2-chloroaniline
Purity
>98.0%(GC)
Packaging
25g
Price
$130
Updated
2025/07/31
TRC
Product number
B699468
Product name
4-Bromo-2-chloroaniline
Packaging
50mg
Price
$45
Updated
2021/12/16
Apolloscientific
Product number
OR0849
Product name
4-Bromo-2-chloroaniline
Purity
98%
Packaging
25g
Price
$22
Updated
2021/12/16
SynQuest Laboratories
Product number
3630-D-X8
Product name
4-Bromo-2-chloroaniline
Purity
98.0%
Packaging
25g
Price
$24
Updated
2021/12/16
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4-Bromo-2-chloroaniline Chemical Properties,Usage,Production

Chemical Properties

SLIGHTLY YELLOW TO LIGHT BROWN CRYSTALLINE POWDER

Uses

4-Bromo-2-chloroaniline was used in the peparation of 3,4-dichloro-α-trichloromethylbenzyl alcohol.

Synthesis

95-51-2

38762-41-3

The general procedure for the synthesis of 4-bromo-2-chloroaniline from o-chloroaniline was as follows: 254 mg (2 mmol) of o-chloroaniline and 143 mg (1.2 mmol) of potassium bromide were dissolved in 10 mL of a solvent mixture of acetic acid (AcOH) and water (9:1, v/v), and the solution was subsequently transferred to a 50 mL three-neck flask. The reaction temperature was controlled by magnetic stirring at 25°C for 1 h in a thermostatic water bath with continuous stirring. Within the first 15 min of the start of the reaction, 1.8 g (1.8 mmol) of ZnAl-BrO3-LDHs was slowly added.After completion of the reaction, the reaction mixture was extracted with dichloromethane (2 × 10 mL) and the organic phases were combined. Two silica gels (200-300 mesh) were added to the combined organic phases, and the dichloromethane was subsequently removed by distillation under reduced pressure. Finally, purification was carried out using column chromatography (eluent was a solvent mixture of petroleum ether and ethyl acetate in a 10:1 ratio, v/v) to give 321 mg of gray solid product in 78% yield.

References

[1] Tetrahedron Letters, 2005, vol. 46, # 51, p. 8959 - 8963
[2] Russian Journal of Applied Chemistry, 2009, vol. 82, # 9, p. 1570 - 1576
[3] Chinese Chemical Letters, 2012, vol. 23, # 4, p. 387 - 390
[4] Monatshefte fur Chemie, 2013, vol. 144, # 2, p. 179 - 181
[5] Journal of the Iranian Chemical Society, 2012, vol. 9, # 3, p. 321 - 326

4-Bromo-2-chloroaniline Preparation Products And Raw materials

Raw materials

Preparation Products

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4-Bromo-2-chloroaniline Suppliers

Changzhou Buddy Chemical Technology Co., Ltd.
Tel
18351236123
Fax
QQ:1253649407
Email
buddychem@foxmail.com
Country
China
ProdList
226
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58
Suzhou Baynoe Biotechnology Co., Ltd.
Tel
18100675867
Email
sales06@baynoe.com
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China
ProdList
525
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58
CHANGZHOU MALONG CHEMICALS CO., LTD.
Tel
18651958646
Email
info@malongchem.com
Country
China
ProdList
180
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58
Changzhou Hongda New Material Technology Co., Ltd.
Tel
15262235181
Email
545789914@qq.com
Country
China
ProdList
290
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58
Sanjing New Materials Technology (Taizhou) Co., Ltd.
Tel
15250805028
Fax
QQ:1048979734
Email
1048979734@qq.com
Country
China
ProdList
339
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58
Changzhou Yuxiang Chemical Co., Ltd
Tel
13809076511
Email
344679571@qq.com
Country
China
ProdList
311
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Nanjing Wanpu Pharmaceutical Technology Co.,Ltd
Tel
13814527050
Email
3773605130@qq.com
Country
China
ProdList
361
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58
J & K SCIENTIFIC LTD.
Tel
18210857532; 18210857532
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
96815
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Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
4006356688 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40228
Advantage
62
Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30123
Advantage
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View Lastest Price from 4-Bromo-2-chloroaniline manufacturers

Jinan Ruitong Biotech Co., Ltd.
Product
4-bromo-2-chloroaniline 38762-41-3
Price
US $0.00-0.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
1
Release date
2025-08-28
Shaanxi Dideu New Materials Co. Ltd
Product
4-Bromo-2-chloroaniline 38762-41-3
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
98.0%
Supply Ability
10000KGS
Release date
2025-05-26
Henan Aochuang Chemical Co.,Ltd.
Product
4-Bromo-2-chloroaniline 38762-41-3
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
1Ton
Release date
2022-10-13

38762-41-3, 4-Bromo-2-chloroanilineRelated Search:


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