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Chlorodiphenylmethane

Product Name
Chlorodiphenylmethane
CAS No.
90-99-3
Chemical Name
Chlorodiphenylmethane
Synonyms
(ChloroMethylene)dibenzene;AI311230;AI3 11230;AI3-11230;AKOS BBS-00004295;alpha-chloroditan;1-Chloro-2-(αBENZHYDRYL CHLORIDE;DIPHENYLCHLOROMETHANE;CHLORODIPHENYLMETHANE
CBNumber
CB9396670
Molecular Formula
C13H11Cl
Formula Weight
202.68
MOL File
90-99-3.mol
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Chlorodiphenylmethane Property

Melting point:
15-17 °C(lit.)
Boiling point:
140 °C3 mm Hg(lit.)
Density 
1.14 g/mL at 25 °C(lit.)
refractive index 
n20/D 1.595(lit.)
Flash point:
>230 °F
storage temp. 
Inert atmosphere,Room Temperature
solubility 
Chloroform (Soluble), Methanol (Sparingly)
form 
Liquid
Specific Gravity
1.14
color 
Clear colorless to yellow
Water Solubility 
slightly soluble
BRN 
607925
CAS DataBase Reference
90-99-3(CAS DataBase Reference)
NIST Chemistry Reference
Benzene, 1,1'-(chloromethylene)bis-(90-99-3)
EPA Substance Registry System
Benzene, 1,1'-(chloromethylene)bis- (90-99-3)
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Safety

Hazard Codes 
Xi,C
Risk Statements 
36/38-36/37/38-36-34
Safety Statements 
26-36-24/25-45-36/37/39-27
RIDADR 
UN 3265 8/PG 2
WGK Germany 
3
TSCA 
Yes
HazardClass 
8
PackingGroup 
III
HS Code 
29036990
Hazardous Substances Data
90-99-3(Hazardous Substances Data)
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H314Causes severe skin burns and eye damage

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P363Wash contaminated clothing before reuse.

P405Store locked up.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
125032
Product name
Chlorodiphenylmethane
Purity
98%
Packaging
5g
Price
$27.8
Updated
2024/03/01
Sigma-Aldrich
Product number
125032
Product name
Chlorodiphenylmethane
Purity
98%
Packaging
100g
Price
$162
Updated
2024/03/01
TCI Chemical
Product number
B1078
Product name
Benzhydryl Chloride
Packaging
25ML
Price
$56
Updated
2024/03/01
TCI Chemical
Product number
B1078
Product name
Benzhydryl Chloride
Packaging
500ML
Price
$460
Updated
2024/03/01
Alfa Aesar
Product number
B24764
Product name
Benzhydryl chloride, 98%
Packaging
25g
Price
$34.65
Updated
2024/03/01
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Chlorodiphenylmethane Chemical Properties,Usage,Production

Chemical Properties

Clear colorless to yellow liquid

Uses

Chlorodiphenylmethane was used as initiator during the controlled radical polymerization of styrene catalyzed by ionic iron complex. It was also used as the starting reagent in the synthesis of trimethylhydroquinone derivatives.

Application

Benzhydryl chloride is used as a pharmaceutical intermediate, such as diphenhydramine intermediate.

Preparation

Chlorodiphenylmethane was synthesized by the radical substitution reaction between diphenylmethane and chlorine gas.

Purification Methods

Diphenylmethyl chloride (benzhydryl chloride) [90-99-3] M 202.7, m 17.0o, b 140o/3mm, 1 6 7o/17mm, n 1.5960. Dry the chloride with Na2SO4 and fractionally distil it under reduced pressure. [Beilstein 5 H 590, 5 I 278, 5 II 500, 5 III 1790, 5 IV 1847.]

Chlorodiphenylmethane Preparation Products And Raw materials

Raw materials

Preparation Products

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Chlorodiphenylmethane Suppliers

J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
96815
Advantage
76
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
4006608290; 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40241
Advantage
62
future industrial shanghai co., ltd
Tel
400-0066400 13621662912
Fax
021-55660885
Email
sales@jonln.com
Country
China
ProdList
1998
Advantage
65
Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30132
Advantage
84
TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
24539
Advantage
81
Yangzhou Aoxin Chemical Co., Ltd
Tel
0514-87754778 13901446058
Fax
+86-514-87752291
Email
sales@aochem.com
Country
China
ProdList
73
Advantage
66
Beijing dtftchem Technology Co., Ltd.
Tel
010-60275820 13031183356
Fax
010-60270825
Email
elainezt@sina.com
Country
China
ProdList
1392
Advantage
62
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44751
Advantage
61
Jinxiang Chemical (Danyang) Products Co., Ltd.
Tel
025-86819862 13913839793
Fax
0086-25-86819859
Email
nancyzong@jinchemical.com
Country
China
ProdList
97
Advantage
74
Beijing Ouhe Technology Co., Ltd
Tel
010-82967028 13552068683
Fax
+86-10-82967029
Email
2355560935@qq.com
Country
China
ProdList
12426
Advantage
60
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View Lastest Price from Chlorodiphenylmethane manufacturers

Henan Fengda Chemical Co., Ltd
Product
Chlorodiphenylmethane 90-99-3
Price
US $100.00-1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
g-kg-tons, free sample is available
Release date
2023-12-25
Qiuxian Baitai New Material Co., LTD
Product
Chlorodiphenylmethane Company Standards 90-99-3
Price
US $0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
20 Tons
Release date
2021-03-11
Zhuozhou Wenxi import and Export Co., Ltd
Product
Chlorodiphenylmethane 90-99-3
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-07-11

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