Chloro(1,5-cyclooctadiene)rhodium(I) dimer

Reaction

Product Name: Chloro(1,5-cyclooctadiene)rhodium(I) dimer
CAS No.: 12092-47-6
Chemical Name: Chloro(1,5-cyclooctadiene)rhodium(I) dimer
Synonyms: Di-μ-chlorobis[(1,2,5,6-η)-1,5-cyclooctadiene]dirhodium;Chloro(1,5-cyclooctadiene)rhodiuM(I);Rhodium, di-mu-chlorobis[(1,2,5,6-eta)-1,5-cyclooctadiene]di-;1,5-Cyclooctadienerhodium(I) chloride dimer, Chloro(1,5-cyclooctadiene)rhodium(I) dimer, Rhodium(I) chloride 1,5-Cyclooctadiene complex dimer;rhodium(1+);[Rh(C8H12)Cl]2;[Rh(1,5-cod)Cl]2;bis(chlororhodium);Chloro(1,5-cycloocta;Di-mu-chlorobis(1,5-cyclooc
CBNumber: CB9406940
Molecular Formula: C16H24Cl2Rh2
Formula Weight: 493.08
MOL File: 12092-47-6.mol

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Chloro(1,5-cyclooctadiene)rhodium(I) dimer Property

Melting point:: 243 °C (dec.) (lit.)
Density: 1.94[at 20℃]
vapor pressure: 0Pa at 25℃
storage temp.: Inert atmosphere,Room Temperature
solubility: Soluble in chloroform, dichloromethane, and methanol. Sparingly soluble in most common solvents.
form: Crystals or Crystalline Powder
color: Orange to orange-brown
Water Solubility: 1.56g/L at 20℃
Sensitive: Air Sensitive & Hygroscopic
Exposure limits: ACGIH: TWA 0.01 mg/m3; TWA 1 mg/m3
NIOSH: IDLH 2 mg/m3; IDLH 100 mg/m3; TWA 0.001 mg/m3; TWA 0.1 mg/m3
Stability:: hygroscopic
LogP: 3.16 at 20℃
NIST Chemistry Reference: Bis(1,5-cyclooctadienerhodium chloride)(12092-47-6)
EPA Substance Registry System: Rhodium, di-.mu.-chlorobis[(1,2,5,6-.eta.)-1,5-cyclooctadiene]di- (12092-47-6)

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Safety

Hazard Codes: Xi
Risk Statements: 36/37/38
Safety Statements: 26-37/39
WGK Germany: 3
F: 3
TSCA: Yes
HS Code: 28439000

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H319Causes serious eye irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P337+P313IF eye irritation persists: Get medical advice/attention.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 227951
Product name: Chloro(1,5-cyclooctadiene)rhodium(I) dimer
Purity: 98%
Packaging: 5g
Price: $3830
Updated: 2024/03/01

TCI Chemical

Product number: B1045
Product name: Chloro(1,5-cyclooctadiene)rhodium(I) Dimer
Purity: >98.0%(T)
Packaging: 1g
Price: $523
Updated: 2024/03/01

TCI Chemical

Product number: B1045
Product name: Chloro(1,5-cyclooctadiene)rhodium(I) Dimer
Purity: >98.0%(T)
Packaging: 100mg
Price: $89
Updated: 2024/03/01

Alfa Aesar

Product number: 010466
Product name: Chloro(1,5-cyclooctadiene)rhodium(I) dimer
Packaging: 250mg
Price: $137
Updated: 2023/06/20

Alfa Aesar

Product number: 010466
Product name: Chloro(1,5-cyclooctadiene)rhodium(I) dimer
Packaging: 1g
Price: $480
Updated: 2023/06/20

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Chloro(1,5-cyclooctadiene)rhodium(I) dimer Chemical Properties,Usage,Production

Reaction

Catalyst for coupling 1,3-dienes with activate methylene compounds.
Rhodium source for various asymmetric hydrogenation systems and asymmetric hydrosilylation of ketones.
Rhodium source for asymmetric reductive aldol reaction.
Cis-hydroboration of terminal alkynes.
Rhodium source for [5 + 2] additions.
Highly enantioselective for [2+2+2] carbocyclization reactions.
Enantioselective hydroboration of cyclopropenes.

Chemical Properties

orange crystals

Uses

It is a widely used precursor to homogeneous catalysts. This is a chiral catalyst capable of asymmetrically hydrogenating certain prochiral alkenes. Chloro(1,5-cyclooctadiene)rhodium(I) dimer is also used in the synthesis of other metal ligands for use in catalysis.

Uses

Chloro(1,5-cyclooctadiene)rhodium(I) dimer ([Rh(COD)Cl]₂) can be:

Employed for the synthesis of rhodium complex of heterocyclic carbenes (NHCs).
Modified and coated on the surface of ferrite magnetic nanoparticles for catalyzing hydroformylation reaction of olefins.
Used for the synthesis of triple-layer structure to be used as a ring-opening polymerization catalyst.
As an effective catalyst for dehydrogenation of amine-borane adducts (hydrogen storage materials) such as ammonia-borane.

General Description

This product has been enhanced for catalytic efficiency.

Flammability and Explosibility

Not classified

Chloro(1,5-cyclooctadiene)rhodium(I) dimer Preparation Products And Raw materials

Raw materials

Ethanol Rhodium(III) chloride hydrate Ethyl acetate 1,5-Cyclooctadiene

Preparation Products

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Chloro(1,5-cyclooctadiene)rhodium(I) dimer Suppliers

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View Lastest Price from Chloro(1,5-cyclooctadiene)rhodium(I) dimer manufacturers

WUHAN FORTUNA CHEMICAL CO., LTD

Product: Chloro(1,5-cyclooctadiene)rhodium(I) dimer 12092-47-6
Price: US $0.00/KG
Min. Order: 1KG
Purity: 98%min
Supply Ability: 30tons/month
Release date: 2023-01-13

Hebei Weibang Biotechnology Co., Ltd

Product: Chloro(1.5-cyclooctadiene)rhodium(I) Dimer 12092-47-6
Price: US $0.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 10 mt
Release date: 2024-10-28

Hebei Weibang Biotechnology Co., Ltd

Product: Chloro(1,5-cyclooctadiene)rhodium(I) dimer 12092-47-6
Price: US $0.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 500000kg
Release date: 2022-11-11

12092-47-6, Chloro(1,5-cyclooctadiene)rhodium(I) dimerRelated Search:

Cyproterone acetate Chlorocyclohexane FLUOROLUBE GREASE, GR-362 Polyvinyl chloride Sodium chloride Thionyl chloride DILINOLEIC ACID 1,3-CYCLOOCTADIENE POLY(ETHYLENE) Cyclopentyl chloride Choline chloride Potassium chloride Rhodium Ammonium chloride Calcium chloride 1,5-Cyclooctadiene Tris(triphenylphosphine)rhodiu Dichloro(1,5-cyclooctadien)ruthenium(II) polymer

Bis(1,5-cyclohexadiene)-mu,mu'-dichlorodirhodium

Bis(cycloocta-1,5-diene)dichlorodirhodium

Chloro(1,5-cyclooctadiene)rhodium dimer

Dichloro-bis-1,5-cyclooctadiene dirhodium

Di-mu-chlorobis(1,5-cyclooctadiene)dirhodium

di-mu-chlorobis[(1,2,5,6-eta)-1,5-cyclooctadiene]di-rhodiu

Rhodium 1,5-cyclooctadiene chloride dimer

Rhodium chloro(cycloocta-1,5-diene) dimer

Rhodium, di-mu-chlorobis(1,5-cyclooctadiene)di-

Rhodium, di-mu-chlorobis[(1,2,5,6-eta)-1,5-cyclooctadiene]di-

RHODIUM(I) CHLORIDE 1,5-CYCLOOCTADIENE COMPLEX DIMER

1,5-Cyclooctadienerhodium(I) chloride dimer, Chloro(1,5-cyclooctadiene)rhodium(I) dimer, Rhodium(I) chloride 1,5-Cyclooctadiene complex dimer

Chloro(1,5-cyclooctadiene)rhodium(I) dimmer,98%

(1,5-Cyclooctadiene)rhodiumchloridedimer

Chloro(1,5-cycloocta

Chloro-(15-cyclooctadiene)-rhodiuM(I)-diMer ([Rh(COD)CI]2

Chloro(1,5-cyclooctadiene)rhodiuM(I)

Chloro(1,5-cyclooctadiene)rhodiuM (I) diMer ,98% [C% : 38.62%-39.22%]

Chloro(1,5-cyclooctadiene)rhodiuM(I) diMer, Min. 40.8% Rh 500MG

Chloro(1,5-cyclooctadiene)rhodiuM(I) diMer,98% [Rh(COD)Cl]2

Bis(1,5-cyclooctadiene)dirhodium(I) Dichloride 1,5-Cyclooctadiene Rhodium(I) Chloride Dimer

Chloro(1,5-cyclooctadiene)rhodiuM(I) diMer/ Bis(1,5-cyclooctadienerhodiuM chloride)

RhodiuM, di-μ-chlorobis[(1,2,5,6-η)-1,5-cyclooctadiene]di-

Dichlorobis(1,5-cyclooctadiene)rhodiuM(I) diMer

Chloro(1,5-cyclooctadiene)rhodium(Ⅰ) dimer

Chloro(1,5-cyclooctadiene)rhodiuM(I) diMer, 41% Rh, Product of UMicore

Chloro(1,5-cyclooctadiene)rhodiuM(I) diMer,[Rh(COD)Cl]2

Chloro(1,5-cyclooctadiene)rhodiuM(Ⅰ) diMer, 41% Rh, Product of UMicore

1,5-CYCLOOCTADIENE RHODIUM(I) CHLORIDE DIMER

DI-MU-CHLOROBIS[(1,2,5,6-N)-1,5-CYCLOOCTADIENE]DIRHODIUM

DI-MU-CHLORO-BIS[(1,2,5,6-ETA)-1,5-CYCLOOCTADIENE]DIRHODIUM

DI-MU-CHLOROBIS[(ETA-CYCLOOCTA-1,5-DIENE)RHODIUM (I)]

CHLORO(1,5-CYCLOOCTADIENE)RHODATE (I) DIMER

CHLORO(1,5-CYCLOOCTADIENE)RHODIUM(I) DIMER

Bis(1,5-cyclooctadienerhodium chloride)

BIS(1,5-CYCLOOCTADIENE)DIRHODIUM(I) DICHLORIDE

BIS(1,5-CYCLOOCTADIENE)-MU,MU'-DICHLORO DIRHODIUM

di-mu-chloro-bis(hapto-1,5-cyclooctadiene)dirhodium(I)

CHLORO(1,5-CYCLOOCTADIENE)RHODIUM(I) DI&

Chloro(1,5-cyclooctadiene)rhodium(I), dimer, 99.9%

DI-CHLORO-BIS-(CYCLOOCTA-1,5-DIENE)DIRHODIUM(I)

Di-μ-chlorobis[(1,2,5,6-η)-1,5-cyclooctadiene]dirhodium

Chloro(1,5-cyclooctadiene)rhodium(I) dimer, min. 40.8% Rh

4-cycloocta-1,5-diene)dirhodium(I)

RhodiuM, di-M-chlorobis[(1,2,5,6-h)-1,5-cyclooctadiene]di-

Chloro(1,5-cyclooctadiene)rhodiuM(I) diMer 98%

Chloro(1,5-cyclooctadiene)rhodium(I)dimer,98%

di- mu -chlorobis[(1,2,5,6- eta)-1,5-cyclooctadiene]di-rhodiu chloro(1,5-cyclooctadiene)rhodium(i) dimer

DICHLORO(1,5-CYCLOOCTADIENE)RHODIUM(I) DIMER

bis((1z,5z)-cycloocta-1,5-diene)

bis(chlororhodium)

[Rh(C8H12)Cl]2

Bis((1,5-cyclooctadiene)(chloro)rhodium)

Chloro(1,5-cyclooctadiene) rhodium(I) dimmer

hloro(1,5-cyclooctadiene)rhodium(I) dimer

[Rh(1,5-cod)Cl]2

Bis(cyclooctadiene)dichlorodirhodium

Di-mu-chlorobis(1,5-cyclooc