ChemicalBook > CAS DataBase List > Benzyl 2-bromoacetate

Benzyl 2-bromoacetate

Product Name
Benzyl 2-bromoacetate
CAS No.
5437-45-6
Chemical Name
Benzyl 2-bromoacetate
Synonyms
BENZYL BROMOACETATE;merbac35;TIMTEC-BB SBB006752;BENZYL 2-BROMOACETATE;Benzyl a-Bromoacetate;BroMine benzyl acetate;Benzylbromoacetate,97%;Benzyl broMoacetate 96%;Bromoacetic acid benzyl;Benzyl Bromoacetate >
CBNumber
CB9413740
Molecular Formula
C9H9BrO2
Formula Weight
229.07
MOL File
5437-45-6.mol
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Benzyl 2-bromoacetate Property

Melting point:
199-201 °C(Solv: water (7732-18-5))
Boiling point:
166-170 °C22 mm Hg(lit.)
Density 
1.446 g/mL at 25 °C(lit.)
refractive index 
n20/D 1.544(lit.)
Flash point:
>230 °F
storage temp. 
Keep in dark place,Sealed in dry,Room Temperature
solubility 
Chloroform, Methanol
form 
Liquid
Specific Gravity
1.446
color 
Clear colorless to light yellow
Water Solubility 
Not miscible or difficult to mix in water.
BRN 
973658
LogP
2.368 (est)
CAS DataBase Reference
5437-45-6(CAS DataBase Reference)
NIST Chemistry Reference
Benzyl 2-bromoacetate(5437-45-6)
EPA Substance Registry System
Benzyl bromoacetate (5437-45-6)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-37/39
RIDADR 
2810
WGK Germany 
3
RTECS 
AF5957215
F 
19
HS Code 
29159080
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
245631
Product name
Benzyl bromoacetate
Purity
96%
Packaging
50g
Price
$40.8
Updated
2024/03/01
Sigma-Aldrich
Product number
245631
Product name
Benzyl bromoacetate
Purity
96%
Packaging
250g
Price
$136
Updated
2024/03/01
TCI Chemical
Product number
B1674
Product name
Benzyl Bromoacetate
Purity
>96.0%(GC)
Packaging
25g
Price
$19
Updated
2024/03/01
TCI Chemical
Product number
B1674
Product name
Benzyl Bromoacetate
Purity
>96.0%(GC)
Packaging
500g
Price
$169
Updated
2024/03/01
Alfa Aesar
Product number
A17630
Product name
Benzyl bromoacetate, 97%
Packaging
50g
Price
$32.65
Updated
2024/03/01
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Benzyl 2-bromoacetate Chemical Properties,Usage,Production

Chemical Properties

Colorless to light yellow liqui

Uses

It is employed in biological research purpose. Benzyl bromoacetate was used in the alkylation of (-)-2,3-O-isopropylidene-D-threitol that afforded lipopeptide, 2-[(4R,5R)-5-({[(9H-fluoren-9-yl)methoxy]carbonylaminomethyl}-2,2-dimethyl-1,3-dioxolan-4-yl)methoxy]acetic acid.

Purification Methods

Dilute the ester with Et2O, wash it with 10% aqueous NaHCO3, H2O, dry (MgSO4) and fractionate it using a Fenske (glass helices packing) column. [Bergmann & Szinai J Chem Soc 1521 1956, Beilstein 6 IV 2265.] LACHRYMATORY.

Benzyl 2-bromoacetate Preparation Products And Raw materials

Raw materials

Preparation Products

Aceclofenac Acemetacin Benazepril
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Benzyl 2-bromoacetate Suppliers

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View Lastest Price from Benzyl 2-bromoacetate manufacturers

Henan Fengda Chemical Co., Ltd
Product
benzyl bromoacetate 5437-45-6
Price
US $8.00-0.80/KG
Min. Order
1KG
Purity
99%
Supply Ability
g-kg-tons, free sample is available
Release date
2024-01-22
Hebei Mojin Biotechnology Co., Ltd
Product
Benzyl 2-bromoacetate 5437-45-6
Price
US $0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
50000KG/month
Release date
2023-07-24
Henan Aochuang Chemical Co.,Ltd.
Product
Benzyl 2-bromoacetate 5437-45-6
Price
US $0.00-0.00/kg
Min. Order
1kg
Purity
98%
Supply Ability
1Ton
Release date
2022-10-17

5437-45-6, Benzyl 2-bromoacetateRelated Search:

Benzyl alcohol Benzyl acetate Benzyl 2-chloroacetate Benzyl nicotinate BENZYL PHENYLACETATE Bromoacetic acid Ethyl bromoacetate Bronopol Methyl bromoacetate tert-Butyl bromoacetate VINYL NEONONANOATE GLYCIDYL NEODECANOATE, MIXTURE OF BRANCHED ISOMERS Decanoyl/octanoyl-glycerides Phenyl bromoacetate Acetic acid Ethyl acetate 1-Bromo-2-methoxyethane Benzyl formate

  • bromo-aceticacibenzylester
  • bromo-aceticaciphenylmethylester
  • acetic acid (phenylmethyl)bromanuidyl ester
  • Benzyl 2-broMoacetate, 96% 50GR
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  • bromo-acetic acid phenylmethyl ester
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  • 1-Bromo-3-oxa-4-phenylbutan-2-one
  • Benzyl 2-broMoacetate, 96% 250GR
  • Benzyl Bromoacetate &gt
  • Acetic acid, 2-bromo-, phenylmethyl ester
  • BENZYL 2-BROMOACETATE CAS 5437-45-6
  • 5437-45-6
  • BrCH2COOCH2C6H5
  • C6H5CH2CO2CH2Br
  • HALOGEN
  • Carbonyl Compounds
  • C8 to C9
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  • Organic Building Blocks
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  • C8 to C9
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