4-Aminodiphenylamine

Product Name: 4-Aminodiphenylamine
CAS No.: 101-54-2
Chemical Name: 4-Aminodiphenylamine
Synonyms: N-PHENYL-P-PHENYLENEDIAMINE;4-ADPA;P-AMINODIPHENYLAMINE;VARIAMINE BLUE RT;Variamine Blue RT Base;N-Phenyl-1,4-benzenediamine;N1-phenylbenzene-1,4-diamine;4-N-phenylbenzene-1,4-diamine;UBOB;Semidin
CBNumber: CB9418967
Molecular Formula: C12H12N2
Formula Weight: 184.24
MOL File: 101-54-2.mol

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4-Aminodiphenylamine Property

Melting point:: 69 °C
Boiling point:: 354 °C
Density: 1.09
vapor pressure: 1 hPa
refractive index: 1.6266 (estimate)
Flash point:: 193°C
storage temp.: Store below +30°C.
solubility: ethanol: soluble10mg/mL, clear, very dark red (Violet to brown to black solution)
pka: 5.20±0.10(Predicted)
form: Liquid
Colour Index: 37240
color: Clear
PH: 8.9 (0.5g/l, H2O, 20℃)
Water Solubility: Soluble in water at 20°C 0.6g/L. Soluble in (10 mg/mL) ethanol.
BRN: 908935
Stability:: Stable. Combustible. Incompatible with strong oxidizing agents, strong acids, plastics.
LogP: 1.82 at 20℃ and pH7
Dissociation constant: 5.45-5.47 at 20℃
CAS DataBase Reference: 101-54-2(CAS DataBase Reference)
NIST Chemistry Reference: 1,4-Benzenediamine, N-phenyl-(101-54-2)
EPA Substance Registry System: p-Aminodiphenylamine (101-54-2)

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Safety

Hazard Codes: Xn,Xi,N
Risk Statements: 22-36-43-42/43-36/37/38-20/22-50/53
Safety Statements: 26-36-45-36/37/39-61-60-36/37
RIDADR: UN3077
WGK Germany: 3
RTECS: ST3150000
F: 8
Autoignition Temperature: >500 °C
Hazard Note: Irritant
TSCA: Yes
HazardClass: 9
PackingGroup: III
HS Code: 29215990
Hazardous Substances Data: 101-54-2(Hazardous Substances Data)
Toxicity: LD50 orally in Rabbit: 464 mg/kg LD50 dermal Rabbit > 5000 mg/kg

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H317May cause an allergic skin reaction

H319Causes serious eye irritation

H411Toxic to aquatic life with long lasting effects

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 241393
Product name: N-Phenyl-p-phenylenediamine
Purity: 98%
Packaging: 100g
Price: $51.6
Updated: 2024/03/01

Sigma-Aldrich

Product number: 241393
Product name: N-Phenyl-p-phenylenediamine
Purity: 98%
Packaging: 1kg
Price: $196
Updated: 2024/03/01

Sigma-Aldrich

Product number: 8.14648
Product name: 4-Aminodiphenylamine
Purity: for synthesis
Packaging: 100g
Price: $34.1
Updated: 2022/05/15

Sigma-Aldrich

Product number: 8.14648
Product name: 4-Aminodiphenylamine
Purity: for synthesis
Packaging: 1kg
Price: $141
Updated: 2022/05/15

TCI Chemical

Product number: P0203
Product name: Azoic Diazo Component 22
Purity: >98.0%(HPLC)(T)
Packaging: 25g
Price: $18
Updated: 2024/03/01

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4-Aminodiphenylamine Chemical Properties,Usage,Production

Description

p-Aminodiphenylamine hydrochloride was formerly used as a hair dye. Sensitization, when deteeted by patch testing, is relatively low in hairdressers.

Chemical Properties

Dark grey flake

Uses

Dye intermediate, pharmaceuticals, photographic chemicals.

Uses

4-Aminodiphenylamine is used as an oxidation dye color in hair dyes. It is also promoted as an efficient reagent for oxidase enzymes, including glucose, lactate, xanthine, and lysine oxidases.

Uses

p-Anilinoaniline is an antioxidant that has shown to cause a reduction of NOx emissions from soybean biodiesel powered DI diesel engines but has increased CO and HC emissions. It is also used to produce dyes, pharmaceuticals, and photographic chemicals and frmerly used as a hair dye.

Definition

ChEBI: An aromatic amine that is the 4-amino derivative of diphenylamine.

General Description

Odorless purple-black solid or flake or dark purple chips.

Air & Water Reactions

Insoluble in water.

Reactivity Profile

4-Aminodiphenylamine is incompatible with strong oxidizers. 4-Aminodiphenylamine is also incompatible with strong acids. 4-Aminodiphenylamine may react with plastics.

Fire Hazard

4-Aminodiphenylamine is combustible.

Contact allergens

This substance was formerly used as a hair dye. Sensitization, when detected by patch testing, is relatively low in hairdressers.

Purification Methods

It crystallises from EtOH with m 66o, and from ligroin with m 75o. It can be distilled at high vacuum. [Beilstein 13 IV 113.]

4-Aminodiphenylamine Preparation Products And Raw materials

Raw materials

Anhydrous hydrogen chloride METANIL YELLOW Diphenyl 4-Chloronitrobenzene 4-NITROSODIPHENYLAMINE Sodium sulfide Potassium carbonate Formic acid Cupric oxide Aniline Hydrogen N-Nitrosodiphenylamine 4-Nitrodiphenylamine Nitrobenzene FORMANILIDE

Preparation Products

Direct Blue 106 N-(1,3-Dimethylbutyl)-N'-phenyl-p-phenylenediamine 4-Diazodiphenylamine sulfate N-Isopropyl-N'-phenyl-1,4-phenylenediamine 4-Aminodiphenylamine

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4-Aminodiphenylamine Suppliers

Americas 1 Belgium 2 China 167 Europe 6 France 2 Germany 7 India 14 Italy 2 Japan 6 Russia 1 Slovakia 1 South Korea 1 Switzerland 3 The Netherlands 1 United Kingdom 8 United States 29 Global 251

HBCChem, Inc.

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View Lastest Price from 4-Aminodiphenylamine manufacturers

Hebei Mujin Biotechnology Co.,Ltd

Product: 4-Aminodiphenylamine 101-54-2
Price: US $0.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 50000KG/month
Release date: 2023-09-01

Hebei Mujin Biotechnology Co.,Ltd

Product: 4-Aminodiphenylamine 101-54-2
Price: US $0.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 50000KG/month
Release date: 2023-09-07

Hebei Weibang Biotechnology Co., Ltd

Product: 4-Aminodiphenylamine 101-54-2
Price: US $1.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 10 mt
Release date: 2024-10-28

101-54-2, 4-AminodiphenylamineRelated Search:

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