Reaction
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Tri-tert-butylphosphine

Reaction
Product Name
Tri-tert-butylphosphine
CAS No.
13716-12-6
Chemical Name
Tri-tert-butylphosphine
Synonyms
P(t-Bu)3;TTBP;TRI-T-BUTYLPHOSPHINE;Tri-tert-butyL;Tris(tert-butyl)phosphine;Butylphosphine;Uncle Ding Jilin;ri-tert-butylphosphine;Tri-t-butylphosphosphin;TRI-TERT-BUTYLPHOSPHINE
CBNumber
CB9483150
Molecular Formula
C12H27P
Formula Weight
202.32
MOL File
13716-12-6.mol
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Tri-tert-butylphosphine Property

Melting point:
30-35 °C(lit.)
Boiling point:
102-103 °C13 mm Hg(lit.)
Density 
0.861 g/mL at 25 °C
Flash point:
1 °F
storage temp. 
Flammables area
form 
solid
Specific Gravity
0.68
Water Solubility 
insoluble
Sensitive 
Air & Moisture Sensitive
Hydrolytic Sensitivity
9: reacts extremely rapidly with atmospheric moisture - may be pyrophoric - glove box or sealed system required
BRN 
1738613
InChIKey
BWHDROKFUHTORW-UHFFFAOYSA-N
CAS DataBase Reference
13716-12-6(CAS DataBase Reference)
NIST Chemistry Reference
Tri-tert-butylphosphine(13716-12-6)
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Safety

Hazard Codes 
F,C
Risk Statements 
17-34-67-65-63-48/20-11
Safety Statements 
26-45-62-36/37/39-25-43-27-16
RIDADR 
UN 2846 4.2/PG 1
WGK Germany 
3
10-19-23
HazardClass 
4.2
PackingGroup 
I
HS Code 
29319090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H250Catches fire spontaneously if exposed to air

H314Causes severe skin burns and eye damage

Precautionary statements

P231+P232Handle under inert gas. Protect from moisture.

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P370+P378In case of fire: Use … for extinction.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
901438
Product name
Tri-tert-butylphosphine solution
Purity
1.0?M in THF
Packaging
25mL
Price
$264
Updated
2024/03/01
Sigma-Aldrich
Product number
570958
Product name
Tri-tert-butylphosphine
Purity
98%
Packaging
1g
Price
$91.8
Updated
2024/03/01
Sigma-Aldrich
Product number
570958
Product name
Tri-tert-butylphosphine
Purity
98%
Packaging
5g
Price
$232
Updated
2024/03/01
Alfa Aesar
Product number
010178
Product name
Tri-tert-butylphosphine
Purity
98%
Packaging
1g
Price
$121.65
Updated
2024/03/01
Alfa Aesar
Product number
010178
Product name
Tri-tert-butylphosphine
Purity
98%
Packaging
5g
Price
$380
Updated
2024/03/01
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Tri-tert-butylphosphine Chemical Properties,Usage,Production

Reaction

Useful as a ligand in a variety of palladium-catalyzed C-N, C-O and C-C bond-forming reactions under mild conditions.

Chemical Properties

Colorless to light yellow liqui

Uses

Tri-tert-butylphosphine is used primarily in the preparation of mono- and bidentate phosphine ligands in metal complexes for catalytic chiral asymmetric hydrogenations and other asymmetric reactions as well as transition metal coupling reactions. This reagent is also used in the preparation of other phosphines in catalytic polymerization reactions.

Uses

Valuable ligand for several coupling reactions. This product is offered as the THF solution for more convenient handling.

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View Lastest Price from Tri-tert-butylphosphine manufacturers

Shanghai UCHEM Inc.
Product
Tri-tert-butylphosphine 13716-12-6
Price
US $589.00/g
Min. Order
1g
Purity
0.99
Supply Ability
1kg
Release date
2023-10-20
Shaanxi Dideu Medichem Co. Ltd
Product
Tri-tert-butylphosphine 13716-12-6
Price
US $1.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
20T
Release date
2024-05-26
Weijer International Trade (Hebei) Co., Ltd
Product
Tri-tert-butylphosphine 13716-12-6
Price
US $1.00/KG
Min. Order
1KG
Purity
>99%
Supply Ability
2000T
Release date
2023-03-20

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