Tri-tert-butylphosphine
Reaction- Product Name
- Tri-tert-butylphosphine
- CAS No.
- 13716-12-6
- Chemical Name
- Tri-tert-butylphosphine
- Synonyms
- P(t-Bu)3;TTBP;TRI-T-BUTYLPHOSPHINE;Tri-tert-butyL;Tris(tert-butyl)phosphine;Butylphosphine;Uncle Ding Jilin;ri-tert-butylphosphine;Tri-t-butylphosphosphin;TRI-TERT-BUTYLPHOSPHINE
- CBNumber
- CB9483150
- Molecular Formula
- C12H27P
- Formula Weight
- 202.32
- MOL File
- 13716-12-6.mol
Tri-tert-butylphosphine Property
- Melting point:
- 30-35 °C(lit.)
- Boiling point:
- 102-103 °C13 mm Hg(lit.)
- Density
- 0.861 g/mL at 25 °C
- Flash point:
- 1 °F
- storage temp.
- Flammables area
- form
- solid
- Specific Gravity
- 0.68
- Water Solubility
- insoluble
- Sensitive
- Air & Moisture Sensitive
- Hydrolytic Sensitivity
- 9: reacts extremely rapidly with atmospheric moisture - may be pyrophoric - glove box or sealed system required
- BRN
- 1738613
- InChIKey
- BWHDROKFUHTORW-UHFFFAOYSA-N
- CAS DataBase Reference
- 13716-12-6(CAS DataBase Reference)
- NIST Chemistry Reference
- Tri-tert-butylphosphine(13716-12-6)
Safety
- Hazard Codes
- F,C
- Risk Statements
- 17-34-67-65-63-48/20-11
- Safety Statements
- 26-45-62-36/37/39-25-43-27-16
- RIDADR
- UN 2846 4.2/PG 1
- WGK Germany
- 3
- F
- 10-19-23
- HazardClass
- 4.2
- PackingGroup
- I
- HS Code
- 29319090
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H250Catches fire spontaneously if exposed to air
H314Causes severe skin burns and eye damage
- Precautionary statements
-
P231+P232Handle under inert gas. Protect from moisture.
P260Do not breathe dust/fume/gas/mist/vapours/spray.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P370+P378In case of fire: Use … for extinction.
N-Bromosuccinimide Price
- Product number
- 901438
- Product name
- Tri-tert-butylphosphine solution
- Purity
- 1.0?M in THF
- Packaging
- 25mL
- Price
- $264
- Updated
- 2024/03/01
- Product number
- 570958
- Product name
- Tri-tert-butylphosphine
- Purity
- 98%
- Packaging
- 1g
- Price
- $91.8
- Updated
- 2024/03/01
- Product number
- 570958
- Product name
- Tri-tert-butylphosphine
- Purity
- 98%
- Packaging
- 5g
- Price
- $232
- Updated
- 2024/03/01
- Product number
- 010178
- Product name
- Tri-tert-butylphosphine
- Purity
- 98%
- Packaging
- 1g
- Price
- $121.65
- Updated
- 2024/03/01
- Product number
- 010178
- Product name
- Tri-tert-butylphosphine
- Purity
- 98%
- Packaging
- 5g
- Price
- $380
- Updated
- 2024/03/01
Tri-tert-butylphosphine Chemical Properties,Usage,Production
Reaction
Useful as a ligand in a variety of palladium-catalyzed C-N, C-O and C-C bond-forming reactions under mild conditions.
Chemical Properties
Colorless to light yellow liqui
Uses
Tri-tert-butylphosphine is used primarily in the preparation of mono- and bidentate phosphine ligands in metal complexes for catalytic chiral asymmetric hydrogenations and other asymmetric reactions as well as transition metal coupling reactions. This reagent is also used in the preparation of other phosphines in catalytic polymerization reactions.
Uses
Valuable ligand for several coupling reactions. This product is offered as the THF solution for more convenient handling.
Tri-tert-butylphosphine Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from Tri-tert-butylphosphine manufacturers
- Product
- Tri-tert-butylphosphine 13716-12-6
- Price
- US $589.00/g
- Min. Order
- 1g
- Purity
- 0.99
- Supply Ability
- 1kg
- Release date
- 2023-10-20
- Product
- Tri-tert-butylphosphine 13716-12-6
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 98%
- Supply Ability
- 20T
- Release date
- 2024-05-26
- Product
- Tri-tert-butylphosphine 13716-12-6
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- >99%
- Supply Ability
- 2000T
- Release date
- 2023-03-20