2-(Perfluorobutyl)ethyl acrylate

Product Name: 2-(Perfluorobutyl)ethyl acrylate
CAS No.: 52591-27-2
Chemical Name: 2-(Perfluorobutyl)ethyl acrylate
Synonyms: TEAc-4;DAIKIN R-1420;Perfluorobutylethyl acrylate;2-(Perfluorobutyl)ethyl acrylate;1H,1H,2H,2H-Nonafluorohexyl acrylate;1H,1H,2H,2H-Perfluorohexyl acrylate 97%;3,3,4,4,5,5,6,6,6-Nonafluorohexylacrylate;3,3,4,4,5,5,6,6,6-Nonafluorohexyl acrylate;Acrylic acid 2-(nonafluorobutyl)ethyl ester;Acrylic Acid 1H,1H,2H,2H-Nonafluorohexyl Ester
CBNumber: CB9485109
Molecular Formula: C9H7F9O2
Formula Weight: 318.14
MOL File: 52591-27-2.mol

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2-(Perfluorobutyl)ethyl acrylate Property

Boiling point:: 164 °C
Density: 1.414
refractive index: 1.310
Flash point:: 52 °C
storage temp.: Store at 2-8 ℃
solubility: Chloroform (Soluble), Ethyl Acetate (Slightly)
form: clear liquid
color: Colorless to Light yellow
Specific Gravity: 1.440
EPA Substance Registry System: 1,1,2,2-Tetrahydroperfluorohexyl acrylate (52591-27-2)

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Safety

RIDADR: UN 3272 3/PG III
HazardClass: 3
PackingGroup: III
HS Code: 2916120090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H226Flammable liquid and vapour

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P280Wear protective gloves/protective clothing/eye protection/face protection.

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N-Bromosuccinimide Price

TCI Chemical

Product number: N1107
Product name: 1H,1H,2H,2H-Nonafluorohexyl Acrylate (stabilized with TBC)
Purity: >98.0%(GC)
Packaging: 5g
Price: $48
Updated: 2024/03/01

TCI Chemical

Product number: N1107
Product name: 1H,1H,2H,2H-Nonafluorohexyl Acrylate (stabilized with TBC)
Purity: >98.0%(GC)
Packaging: 25g
Price: $139
Updated: 2024/03/01

TCI Chemical

Product number: N0977
Product name: 1H,1H,2H,2H-Nonafluorohexyl Acrylate (stabilized with MEHQ)
Purity: >98.0%(GC)
Packaging: 5g
Price: $39
Updated: 2021/12/16

Apolloscientific

Product number: PC5906D
Product name: 3,3,4,4,5,5,6,6,6-Nonafluorohex-1ylacrylate
Purity: 97%
Packaging: 5g
Price: $42
Updated: 2021/12/16

SynQuest Laboratories

Product number: 2324-3-Y3
Product name: 1H,1H,2H,2H-Perfluorohexyl acrylate
Purity: 97%
Packaging: 25g
Price: $100
Updated: 2021/12/16

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2-(Perfluorobutyl)ethyl acrylate Chemical Properties,Usage,Production

Uses

2-(Perfluorobutyl)ethyl Acrylate can be used as an acrylic resin surface modifier with high water repellency and oil repellency for coating agents. It can also be used in a super concentrated emulsion method to prepare a solid sheet polycarboxylic acid water reducing agent.

Application

2-(Perfluorobutyl)ethyl acrylate has been used in a wide range of scientific research applications. It has been used to create polymers for biomedical applications, such as drug delivery systems and tissue engineering scaffolds. It has also been used to create polymers for industrial applications, such as coatings and adhesives. In addition, it has been used to create polymers for energy applications, such as fuel cells and solar cells.

Synthesis

1H,1H,2H,2H-nonafluoro-1-hexanol (52.8 g) as fluoro alcohol and triethylamine (50 g) were dissolved in 500 ml of tetrahydrofuran. A solution of 18.1 g of acryloyl chloride as acid chloride in 100 ml of tetrahydrofuran was dropped in this solution over 2 hours while the mixture was being cooled in ice and stirred. After the completion of the dropping, the resulting white precipitate was filtrated and tetrahydrofuran and triethylamine were removed from the filtrate using a rotary evaporator. NMR measurement revealed that the resulting compound was 1H,1H,2H,2H-nonafluorohexyl acrylate.

Research

Since the bioaccumulation of the degradation products of fluoropolymer with a long Rf side chain (C ≥ 8) has a potential environmental risk, it is necessary to design fluoropolymer coating with a short Rf side chain. Honda et al. studied the effect of α-substituent on the wetting behavior and molecular motion at the surfaces of poly{2-(perfluorobutyl)ethyl acrylate} [PFA-C4], poly{2-(perfluorobutyl)ethyl methacrylate} [PFMA-C4], poly{2-(perfluorobutyl)ethyl α-fluoroacrylate} [PFFA-C4], and poly{2-(perfluorobutyl)ethyl α-chloroacrylate} [PFClA-C4] films. In the case of PFA-Cy with long Rf groups [y ≥ 8], the mobility of the side chains is low at room temperature because of the crystallization of the Rf groups at the surface region[1].

References

[1] Koji Honda . "Effect of α-substituents on molecular motion and wetting behaviors of poly(fluoroalkyl acrylate) thin films with short fluoroalkyl side chains." Polymer 55 24 (2014): Pages 6303-6308.

2-(Perfluorobutyl)ethyl acrylate Preparation Products And Raw materials

Raw materials

Preparation Products

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2-(Perfluorobutyl)ethyl acrylate Suppliers

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Shangfluoro

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View Lastest Price from 2-(Perfluorobutyl)ethyl acrylate manufacturers

SHANDONG OUCHEM CO.,LTD.

Product: 2-(Perfluorobutyl)ethyl acrylate 52591-27-2
Price: US $0.00-0.00/kg
Min. Order: 0.1kg
Purity: 98% Min.
Supply Ability: 2000kg
Release date: 2024-01-21

Wuhan Silworld Chemical Co.,Ltd

Product: 2-(Perfluorobutyl)ethyl acrylate 52591-27-2
Price: US $0.00/KG
Min. Order: 1KG
Purity: 98%
Supply Ability: 10000
Release date: 2023-04-28

Henan Aochuang Chemical Co.,Ltd.

Product: 2-(Perfluorobutyl)ethyl acrylate 52591-27-2
Price: US $0.00-0.00/kg
Min. Order: 1kg
Purity: 98%
Supply Ability: 1Ton
Release date: 2022-10-09

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