ChemicalBook > CAS DataBase List > 2-(Perfluorobutyl)ethyl acrylate

2-(Perfluorobutyl)ethyl acrylate

Product Name
2-(Perfluorobutyl)ethyl acrylate
CAS No.
52591-27-2
Chemical Name
2-(Perfluorobutyl)ethyl acrylate
Synonyms
TEAc-4;DAIKIN R-1420;Perfluorobutylethyl acrylate;2-(Perfluorobutyl)ethyl acrylate;1H,1H,2H,2H-Nonafluorohexyl acrylate;1H,1H,2H,2H-Perfluorohexyl acrylate 97%;3,3,4,4,5,5,6,6,6-Nonafluorohexylacrylate;3,3,4,4,5,5,6,6,6-Nonafluorohexyl acrylate;Acrylic acid 2-(nonafluorobutyl)ethyl ester;Acrylic Acid 1H,1H,2H,2H-Nonafluorohexyl Ester
CBNumber
CB9485109
Molecular Formula
C9H7F9O2
Formula Weight
318.14
MOL File
52591-27-2.mol
More
Less

2-(Perfluorobutyl)ethyl acrylate Property

Boiling point:
164 °C
Density 
1.414
refractive index 
1.310
Flash point:
52 °C
storage temp. 
Store at 2-8 ℃
solubility 
Chloroform (Soluble), Ethyl Acetate (Slightly)
form 
clear liquid
color 
Colorless to Light yellow
Specific Gravity
1.440
EPA Substance Registry System
1,1,2,2-Tetrahydroperfluorohexyl acrylate (52591-27-2)
More
Less

Safety

RIDADR 
UN 3272 3/PG III
HazardClass 
3
PackingGroup 
III
HS Code 
2916120090
More
Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H226Flammable liquid and vapour

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P280Wear protective gloves/protective clothing/eye protection/face protection.

More
Less

N-Bromosuccinimide Price

TCI Chemical
Product number
N1107
Product name
1H,1H,2H,2H-Nonafluorohexyl Acrylate (stabilized with TBC)
Purity
>98.0%(GC)
Packaging
5g
Price
$48
Updated
2024/03/01
TCI Chemical
Product number
N1107
Product name
1H,1H,2H,2H-Nonafluorohexyl Acrylate (stabilized with TBC)
Purity
>98.0%(GC)
Packaging
25g
Price
$139
Updated
2024/03/01
TCI Chemical
Product number
N0977
Product name
1H,1H,2H,2H-Nonafluorohexyl Acrylate (stabilized with MEHQ)
Purity
>98.0%(GC)
Packaging
5g
Price
$39
Updated
2021/12/16
Apolloscientific
Product number
PC5906D
Product name
3,3,4,4,5,5,6,6,6-Nonafluorohex-1ylacrylate
Purity
97%
Packaging
500mg
Price
$10
Updated
2021/12/16
Matrix Scientific
Product number
005258
Product name
2-(Perfluorobutyl)ethyl acrylate
Purity
97%
Packaging
1g
Price
$14
Updated
2021/12/16
More
Less

2-(Perfluorobutyl)ethyl acrylate Chemical Properties,Usage,Production

Uses

2-(Perfluorobutyl)ethyl Acrylate can be used as an acrylic resin surface modifier with high water repellency and oil repellency for coating agents. It can also be used in a super concentrated emulsion method to prepare a solid sheet polycarboxylic acid water reducing agent.

Application

2-(Perfluorobutyl)ethyl acrylate has been used in a wide range of scientific research applications. It has been used to create polymers for biomedical applications, such as drug delivery systems and tissue engineering scaffolds. It has also been used to create polymers for industrial applications, such as coatings and adhesives. In addition, it has been used to create polymers for energy applications, such as fuel cells and solar cells.

Synthesis


1H,1H,2H,2H-nonafluoro-1-hexanol (52.8 g) as fluoro alcohol and triethylamine (50 g) were dissolved in 500 ml of tetrahydrofuran. A solution of 18.1 g of acryloyl chloride as acid chloride in 100 ml of tetrahydrofuran was dropped in this solution over 2 hours while the mixture was being cooled in ice and stirred. After the completion of the dropping, the resulting white precipitate was filtrated and tetrahydrofuran and triethylamine were removed from the filtrate using a rotary evaporator. NMR measurement revealed that the resulting compound was 1H,1H,2H,2H-nonafluorohexyl acrylate.

Research

Since the bioaccumulation of the degradation products of fluoropolymer with a long Rf side chain (C ≥ 8) has a potential environmental risk, it is necessary to design fluoropolymer coating with a short Rf side chain. Honda et al. studied the effect of α-substituent on the wetting behavior and molecular motion at the surfaces of poly{2-(perfluorobutyl)ethyl acrylate} [PFA-C4], poly{2-(perfluorobutyl)ethyl methacrylate} [PFMA-C4], poly{2-(perfluorobutyl)ethyl α-fluoroacrylate} [PFFA-C4], and poly{2-(perfluorobutyl)ethyl α-chloroacrylate} [PFClA-C4] films. In the case of PFA-Cy with long Rf groups [y ≥ 8], the mobility of the side chains is low at room temperature because of the crystallization of the Rf groups at the surface region[1].

References

[1] Koji Honda . "Effect of α-substituents on molecular motion and wetting behaviors of poly(fluoroalkyl acrylate) thin films with short fluoroalkyl side chains." Polymer 55 24 (2014): Pages 6303-6308.

2-(Perfluorobutyl)ethyl acrylate Preparation Products And Raw materials

Raw materials

Preparation Products

More
Less

2-(Perfluorobutyl)ethyl acrylate Suppliers

Americas 1 China 94 Europe 1 France 1 Germany 1 India 3 Japan 3 Russia 1 United Kingdom 2 United States 10 Global 117
Aladdin Scientific
Tel
+1-+1(833)-552-7181
Email
sales@aladdinsci.com
Country
United States
ProdList
57505
Advantage
58
Alfa Chemistry
Tel
--
Fax
--
Email
info@Alfa-Chemistry.com
Country
United States
ProdList
6814
Advantage
0
Aagile Labs Division of Tyger Scientific
Tel
--
Fax
--
Email
tygersci@yahoo.com
Country
United States
ProdList
6568
Advantage
68
SynQuest Laboratories, Inc.
Tel
--
Fax
--
Email
info@synquestlabs.com
Country
United States
ProdList
6871
Advantage
62
TCI America
Tel
--
Fax
--
Email
sales@tciamerica.com
Country
United States
ProdList
6909
Advantage
75
Matrix Scientific
Tel
--
Fax
--
Email
sales@matrixscientific.com
Country
United States
ProdList
6632
Advantage
80
Fluoryx, Inc.
Tel
--
Fax
--
Email
irene@fluoryx.com
Country
United States
ProdList
106
Advantage
50
Oakwood Products, Inc.
Tel
--
Fax
--
Email
sales@oakwoodchemical.com
Country
United States
ProdList
6193
Advantage
74
3B Scientific Corporation
Tel
--
Fax
--
Email
sales@3bsc.com
Country
United States
ProdList
6718
Advantage
47
INDOFINE Chemical Company, Inc.
Tel
--
Fax
--
Email
chemical@indofinechemical.com
Country
United States
ProdList
6176
Advantage
69
More
Less

View Lastest Price from 2-(Perfluorobutyl)ethyl acrylate manufacturers

SHANDONG OUCHEM CO.,LTD.
Product
2-(Perfluorobutyl)ethyl acrylate 52591-27-2
Price
US $0.00-0.00/kg
Min. Order
0.1kg
Purity
98% Min.
Supply Ability
2000kg
Release date
2024-01-21
Wuhan Silworld Chemical Co.,Ltd
Product
2-(Perfluorobutyl)ethyl acrylate 52591-27-2
Price
US $0.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
10000
Release date
2023-04-28
Henan Aochuang Chemical Co.,Ltd.
Product
2-(Perfluorobutyl)ethyl acrylate 52591-27-2
Price
US $0.00-0.00/kg
Min. Order
1kg
Purity
98%
Supply Ability
1Ton
Release date
2022-10-09

52591-27-2, 2-(Perfluorobutyl)ethyl acrylateRelated Search:

Tris(trimethylsilyl)phosphate Trinexapac-ethyl 6-Benzylaminopurine Ethyl acetate Ethanol Ethyl cyanoacetate Ethylparaben Methyl acrylate Methyl propiolate Perfluoroalkylethyl acrylate Ethyl acrylate Acrylic acid ISOXADIFEN-ETHYL 1H,1H,2H,2H-Perfluorohexan-1-ol 2-(Perfluorobutyl)ethyl methacrylate 4,4,5,5,6,6,6-HEPTAFLUOROHEXAN-1-OL 2-(Perfluorobutyl)ethyl acrylate,2-(PERFLUOROBUTYL)ETHYL ACRYLATE 97% Polyacrylate rubber

  • 9-formyl-3-hydroxy-6-oxo-7-(1-oxopentyl)-1-pentyl-2-benzo[b][1,4]benzodioxepincarboxylic acid
  • 1H,1H,2H,2H-Nonafluorohexyl Acrylate (stabilized with TBC)
  • 1<i>H</i>,1<i>H</i>,2<i>H</i>,2<i>H</i>-Nonafluorohexyl Acrylate (stabilized with MEHQ)
  • Perfluorobutylethyl acrylate
  • 2-Propenoic acid 3,3,4,4,5,5,6,6,6-nonafluorohexyl ester
  • 3,3,4,4,5,5,6,6,6-Nonafluorohexyl acrylate
  • 3,3,4,4,5,5,6,6,6-Nonafluorohexylacrylate
  • Acrylic acid 2-(nonafluorobutyl)ethyl ester
  • Acrylic acid 3,3,4,4,5,5,6,6,6-nonafluorohexyl ester
  • Propenoic acid 3,3,4,4,5,5,6,6,6-nonafluorohexyl ester
  • 1H,1H,2H,2H-Perfluorohexyl acrylate 97%
  • 2-(Perfluorobut-1-yl)ethyl acrylate, 3,3,4,4,5,5,6,6,6-Nonafluorohex-1-yl prop-2-enoate, TEAc-4
  • DAIKIN R-1420
  • 1H,1H,2H,2H-Nonafluorohexyl acrylate
  • 2-(Perfluorobutyl)ethyl acrylate
  • 3,3,4,4,5,5,6,6,6-Nonafluorohex-1yl acrylate 97%
  • 1H,1H,2H,2H-Nonafluorohexyl Acrylate (stabilized with MEHQ)
  • 1H,1H,2H,2H-Nonafluorohexyl Acrylate (stabilized with MEHQ) &gt
  • 2-Propenoic acid,3,3,4,4,5,5,6,6,6-nonafluorohexyl ester，>98.0%(GC)
  • Acrylic Acid 1H,1H,2H,2H-Nonafluorohexyl Ester
  • TEAc-4
  • 52591-27-2
  • C9H7F9O2
  • Halogenated Heterocycles ,Isoquinolines ,Quinolines ,Quinaldines