ChemicalBook > CAS DataBase List > 3-Furanboronic acid pinacol ester

3-Furanboronic acid pinacol ester

Uses

Product Name: 3-Furanboronic acid pinacol ester
CAS No.: 248924-59-6
Chemical Name: 3-Furanboronic acid pinacol ester
Synonyms: pinacol ester;Trandolapril Impurity 26;FURAN-3-BORONIC ACID PINACOL ESTER;3-FURANBORONIC ACID, PINACOL ESTER;3-Furanboronic acid pinacol ester 98%;3-(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)FURAN;3-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)furane;2-(3-Furanyl)-4,4,5,5-tetraMethyl-1,3,2-dioxaborolane;2-(furan-3-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane;1,3,2-Dioxaborolane, 2-(3-furanyl)-4,4,5,5-tetramethyl-
CBNumber: CB9486979
Molecular Formula: C10H15BO3
Formula Weight: 194.04
MOL File: 248924-59-6.mol

Less

3-Furanboronic acid pinacol ester Property

Melting point:: 62-65 °C (lit.)
Boiling point:: 255.0±13.0 °C(Predicted)
Density: 1.03±0.1 g/cm3(Predicted)
storage temp.: under inert gas (nitrogen or Argon) at 2-8°C
solubility: Chloroform (Slightly), Methanol (Slightly)
form: crystal
color: white
CAS DataBase Reference: 248924-59-6(CAS DataBase Reference)

Less

Safety

Safety Statements: 24/25
WGK Germany: 3
HS Code: 2932190090

Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

Less

N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 575054
Product name: 3-Furanboronic acid pinacol ester
Purity: 98%
Packaging: 1g
Price: $67.9
Updated: 2023/06/20

Sigma-Aldrich

Product number: 575054
Product name: 3-Furanboronic acid pinacol ester
Purity: 98%
Packaging: 5g
Price: $312
Updated: 2023/06/20

Strem Chemicals

Product number: 05-1039
Product name: 3-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)furan, min. 97%
Packaging: 1g
Price: $72
Updated: 2024/03/01

Strem Chemicals

Product number: 05-1039
Product name: 3-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)furan, min. 97%
Packaging: 5g
Price: $289
Updated: 2024/03/01

TRC

Product number: B414225
Product name: 2-(Furan-3-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
Packaging: 100mg
Price: $75
Updated: 2021/12/16

Less

3-Furanboronic acid pinacol ester Chemical Properties,Usage,Production

Uses

2-(furan-3-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane is a useful research chemical.

Chemical Properties

Furan-3-boronic acid pinacol ester is white to off-white solid powder at room temperature and pressure, it is insoluble in water but soluble in most organic solvents. It has high chemical reactivity, it has rich electron cloud density and is sensitive to strong oxidizing agents. Its chemical reaction activity mainly focuses on the borate unit in its structure, which can participate in oxidation, coupling and other reactions.

Synthesis

22037-28-1

73183-34-3

248924-59-6

GENERAL METHOD: 3-bromofuran (1 mmol), pinacol ester of bisboronic acid (1.2 mmol) and dioxane (5 mL) were added to a 25 mL round bottom flask. KOAc (2 mmol) was then added and the mixture was stirred for 5 min at room temperature. PdII-TpTP catalyst (0.15 mol%) was added and the reaction mixture was placed in an oil bath preheated to 110 °C and refluxed with continuous stirring in the open system. The reaction progress was monitored by thin layer chromatography (TLC). Upon completion of the reaction, the mixture was cooled to room temperature, diluted with water (20 mL) and extracted with tert-butyl methyl ether (3 x 10 mL). The organic layers were combined and concentrated to give the crude product. The crude product was purified by silica gel column chromatography using a mixture of ethyl acetate and hexane (1:30) as eluent.

References

[1] Organic Letters, 2014, vol. 16, # 17, p. 4562 - 4565
[2] Journal of the American Chemical Society, 2017, vol. 139, # 2, p. 607 - 610
[3] Synlett, 2018, vol. 29, # 8, p. 1055 - 1060

3-Furanboronic acid pinacol ester Preparation Products And Raw materials

Raw materials

Preparation Products

Less

3-Furanboronic acid pinacol ester Suppliers

China 96 Europe 3 France 1 Germany 3 India 1 Japan 1 Switzerland 1 Ukraine 1 United Kingdom 3 United States 27 Global 137

J & K SCIENTIFIC LTD.

Tel: 18210857532; 18210857532
Fax: 86-10-82849933
Email: jkinfo@jkchemical.com
Country: China
ProdList: 96815
Advantage: 76

PharmaBlock Sciences (Nanjing),Inc.

Tel: 025-86918202 4000255188
Fax: 86-025-86918232
Email: sales@pharmablock.com
Country: China
ProdList: 5000
Advantage: 55

Energy Chemical

Tel: 021-021-58432009 400-005-6266
Fax: 021-58436166
Email: sales8178@energy-chemical.com
Country: China
ProdList: 44801
Advantage: 61

Wuhan Chemwish Technology Co., Ltd

Tel: 86-027-67849912
Fax: 86-027-87531808
Email: sales@chemwish.com
Country: China
ProdList: 35896
Advantage: 56

Capot Chemical Co., Ltd

Tel: +86 (0) 571 85 58 67 18
Fax: 0086-571-85864795
Country: China
ProdList: 18207
Advantage: 66

Nanjing Chemlin Chemical Co., Ltd

Tel: 025-83697070
Fax: +86-25-83453306
Email: info@chemlin.com.cn
Country: China
ProdList: 16075
Advantage: 64

Shanghai Hanhong Scientific Co.,Ltd.

Tel: 021-54306202 13764082696
Email: info@hanhongsci.com
Country: China
ProdList: 42934
Advantage: 64

Shanghai Sunway Pharmaceutical Technology Co., Ltd

Tel: 18270980682
Fax: 021 51613951
Email: mlcheng@sunwaypharm.cn
Country: China
ProdList: 8669
Advantage: 57

Dalian GoldenGate Biotech Co., Ltd.

Tel: 137328113 15524772882
Fax: 0411-86724203
Email: dlgoldengate@163.com
Country: China
ProdList: 53
Advantage: 50

Thermo Fisher Scientific

Tel: 800-810-5118
Fax: +86-10-84193589
Email: cnchemical@thermofisher.com
Country: China
ProdList: 17770
Advantage: 75

Shanghai Topbiochem Technology Co., Ltd

Tel: 021-58170097
Email: info@topbiochem.com
Country: China
ProdList: 9510
Advantage: 58

Shanghai Jian Chao Chemical Technology Co., Ltd.

Tel: 150-2103-5486 18017383231
Fax: qq：2817624287
Email: 983544897@qq.com
Country: China
ProdList: 9342
Advantage: 55

9ding chemical ( Shanghai) Limited

Tel: 4009209199
Fax: 86-021-52271987
Email: sales@9dingchem.com
Country: China
ProdList: 22514
Advantage: 55

Bide Pharmatech Ltd.

Tel: 400-164-7117 13681763483
Fax: +86-21-61629029
Email: product02@bidepharm.com
Country: China
ProdList: 39966
Advantage: 60

Shanghai Balmxy Pharmaceutical Co., Ltd

Tel: 021-24206007 13764915196
Fax: 86-021-23027023
Email: sales@balmxy.com
Country: China
ProdList: 6874
Advantage: 55

Hangzhou J&H Chemical Co., Ltd.

Tel: 0571-87396432
Fax: 0571-87396431
Email: sales@jhechem.com
Country: China
ProdList: 14912
Advantage: 59

Sigma-Aldrich

Tel: 021-61415566 800-8193336
Email: orderCN@merckgroup.com
Country: China
ProdList: 51395
Advantage: 80

Shanghai Send Pharmaceutical Technology Co., Ltd.

Tel: 021-58088081 Q2635253576
Fax: QQ3382968513
Email: hailey@shsendpharm.com
Country: China
ProdList: 2081
Advantage: 55

Wuhan Chemwish Technology Co.， Ltd

Tel: 027-67849912
Fax: 027-87531808
Email: sales@chemwish.com
Country: China
ProdList: 9148
Advantage: 60

Boron Technology (Beijing) Co., Ltd.

Tel: 010-010-15313962280 15313962280
Fax: 010-51669040
Email: 3004509780@qq.com
Country: China
ProdList: 824
Advantage: 55

Henan CoreyChem Co., Ltd

Tel: 0371-86658258
Fax: 0371-60996044
Email: info@coreychem.com
Country: China
ProdList: 10453
Advantage: 58

Shanghai YuanYe Biotechnology Co., Ltd.

Tel: 021-61312847; 18021002903
Fax: QQ:3008007432
Email: 3008007409@qq.com
Country: China
ProdList: 71826
Advantage: 60

Changzhou Hopschain Chemical Co.,Ltd.

Tel: 0519-85528066 13775048983
Fax: 0519-85528066
Email: sales@hopschem.com
Country: China
ProdList: 31553
Advantage: 55

Shandong Xiya Chemical Co., Ltd.

Tel: 4009903999 13395398332
Fax: 0539-6365991
Email: sales@xiyashiji.com
Country: China
ProdList: 20794
Advantage: 60

Grader reagent

Tel: 18221735425
Email: sales@xinpingchem.com
Country: China
ProdList: 9942
Advantage: 58

ChengDu TongChuangYuan Pharmaceutical Co.Ltd

Tel: 028-83379370 13880556291
Fax: 028-87747383
Email: tcy@tcypharm.com
Country: China
ProdList: 7218
Advantage: 58

Amadis Chemical Company Limited

Tel: 571-89925085
Fax: 0086-571-89925065
Email: sales@amadischem.com
Country: China
ProdList: 131957
Advantage: 58

Shandong Ono Chemical Co., Ltd.

Tel: 0539-6362799 20）
Fax: 0539-6362799（To 20）
Country: China
ProdList: 10007
Advantage: 58

Wuxi AppTec

Tel: 022-59987777 13552403979
Email: jia_guoqiang@wuxiapptec.com
Country: China
ProdList: 22345
Advantage: 58

Capot Chemical Co.,Ltd.

Tel: +86-（0）57185586718; +8613336195806
Fax: +86-571-85864795
Email: sales@capot.com
Country: China
ProdList: 29735
Advantage: 60

SHANGHAI FDC-CHEMICAL CO.,LTD

Tel: 021-61469567 13482353728
Fax: 021-61161605
Email: sales@fdc-chemical.com
Country: China
ProdList: 9717
Advantage: 58

Tianjin heowns Biochemical Technology Co., Ltd.

Tel: 400-6387771-6039 18920764717
Email: sales@heowns.com
Country: China
ProdList: 23771
Advantage: 60

Hangzhou SuGuan Chemical Technology Co., Ltd.

Tel: 15958048562
Fax: -
Email: 2032153781@qq.com
Country: China
ProdList: 463
Advantage: 58

Yujinpharma(Tianjin) Technology Co.,Ltd.

Tel: 13370351217 kungfu1217@1
Fax: QQ1400885609
Email: kungfu1217@163.com
Country: China
ProdList: 2720
Advantage: 58

3A Chemicals

Tel: 400-668-9898
Fax: 010-51582189
Email: service@3achem.com
Country: China
ProdList: 20557
Advantage: 58

Nanjing holy chemical co., LTD

Tel: 19951936396
Email: 1815156226@qq.com
Country: China
ProdList: 2947
Advantage: 58

Shanghai Jizhi Biochemical Technology Co. Ltd.

Tel: 4009004166/18616739031 18616739031
Email: 3007523370@qq.com
Country: China
ProdList: 52687
Advantage: 58

Henan Alpha Chemical Co., Ltd.

Tel: 0371-55055611 18137792234
Fax: QQ：3002694073
Email: 3002694073@qq.com
Country: China
ProdList: 9987
Advantage: 58

Hefei TNJ Chemical Industry Co.,Ltd.

Tel: +86-0551-65418684 +8618949823763
Fax: 0086-551-65418684
Email: sales@tnjchem.com
Country: China
ProdList: 25356
Advantage: 58

CD Chemical Group Limited

Tel: +8615986615575
Fax: 0086-13651442114
Email: info@codchem.com
Country: China
ProdList: 20342
Advantage: 58

Dayang Chem (Hangzhou) Co.,Ltd.

Tel: +86-0571-88938639 +8617705817739
Fax: +86-571-88938652，+86-571- 88492614
Email: info@dycnchem.com
Country: China
ProdList: 52846
Advantage: 58

Hefei Hirisun Pharmatech Co., Ltd

Tel: +8615056975894
Fax: 86-0551-62678551
Email: shawn@hirisunpharm.com
Country: CHINA
ProdList: 9911
Advantage: 58

Shanghai Jiange Chemical Co., Ltd.

Tel: 15921040873
Email: 1434142450@qq.com
Country: CHINA
ProdList: 7649
Advantage: 58

Wuhan Chemwish Technology Co., Ltd

Tel: 027-67849912
Email: sales@chemwish.com
Country: CHINA
ProdList: 10821
Advantage: 58

career henan chemical co

Tel: +86-0371-86658258 +8613203830695
Fax: 0086-371-86658258
Email: factory@coreychem.com
Country: China
ProdList: 29798
Advantage: 58

Antai Fine Chemical Technology Co.,Limited

Tel: 18503026267
Email: info@antaichem.com
Country: CHINA
ProdList: 9636
Advantage: 58

Guangzhou Yuheng Pharmaceutical Technology Co., Ltd

Tel: +8613580539051
Email: joe@yuhengpharm.com
Country: CHINA
ProdList: 21142
Advantage: 58

Taizhou Nanfeng Pharmaceutical Research Institute

Tel: nanfengdrug@163.com; 18616377689
Email: nanfengdrug@163.com
Country: China
ProdList: 20009
Advantage: 58

Changzhou Kechem Bio-Scientific Co., LTD.

Tel: 0519-68985668 13685222090
Fax: qq735434464
Email: sales@kechem.cn
Country: China
ProdList: 26028
Advantage: 58

Meng Cheng Technology (Shanghai) Co., LTD

Tel: 400-820-6829
Email: sales@mitachieve.com
Country: China
ProdList: 8860
Advantage: 58

Less

View Lastest Price from 3-Furanboronic acid pinacol ester manufacturers

Career Henan Chemical Co

Product: 3-Furanboronic acid pinacol ester 248924-59-6
Price: US $1.00/g
Min. Order: 1g
Purity: 99%
Supply Ability: 10000KGS
Release date: 2020-01-09

248924-59-6, 3-Furanboronic acid pinacol esterRelated Search:

Propyleneglycol alginate Pinacol Methyl acrylate 3-Furanboronic acid Tris(trimethylsilyl)phosphate Furan 2,2,4-Trimethyl-1,3-pentanediol monoisobutyrate Diethyl phthalate Carbamic acid, 3-furanyl-, 1,1-dimethylethyl ester (9CI) 2-Furanboronic acid Pinacolborane 3-FURANECARBOXAMIDE 5-FORMYLFURAN-3-BORONIC ACID PINACOL ESTER 2-Furanboronic acid pinacol ester 2-Methylfurane-5-boronic acid pinacol ester 2-FORMYLFURAN-3-BORONIC ACID PINACOL ESTER 2-Methylfuran-3-boronic acid, pinacol ester 3-Furanboronic acid pinacol ester

FURAN-3-BORONIC ACID PINACOL ESTER

3-(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)FURAN

3-FURANBORONIC ACID, PINACOL ESTER

3-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)furane

3-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)furan,min.97%

3-(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)FURAN, MIN. 97%

2-(furan-3-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

pinacol ester

2-(3-Furanyl)-4,4,5,5-tetraMethyl-1,3,2-dioxaborolane

3-Furanboronic acid pinacol ester 98%

3-hydroxy-2,3-dimethylbutan-2-yl hydrogen furan-3-ylboronate

1,3,2-Dioxaborolane, 2-(3-furanyl)-4,4,5,5-tetramethyl-

Trandolapril Impurity 26

248924-59-6

C10H15BO3

C10H15BO3c

Boronic Acids and Derivatives

Boronate Esters

Organometallic Reagents

Heteroaryl

organic or inorganic borate

Boronic acids

Boronic ester

Furan

Organoborons