ChemicalBook > CAS DataBase List > 4-Vinyl-1,3-dioxolan-2-one

4-Vinyl-1,3-dioxolan-2-one

Product Name
4-Vinyl-1,3-dioxolan-2-one
CAS No.
4427-96-7
Chemical Name
4-Vinyl-1,3-dioxolan-2-one
Synonyms
Vinyl Ethylene Carbonate;VEC)4-Vinyl-1,3-d;4-Vinyl-1,3-dioxolan-2-one;2-Oxo-4-vinyl-1,3-dioxolane;4-Ethenyl-1,3-dioxolan-2-one;Vinyl Ethylene Carbonate(VEC);4-VINYL-1,3-DIOXOLAN-2-ONE 99%;4-VINYL-1 3-DIOXOLAN-2-ONE 99;1,3-Dioxolan-2-one, 4-ethenyl-;4-Vinyl-1,3-dioxolan-2-one(VEC)
CBNumber
CB9504374
Molecular Formula
C5H6O3
Formula Weight
114.1
MOL File
4427-96-7.mol
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4-Vinyl-1,3-dioxolan-2-one Property

Boiling point:
237 °C/733 mmHg (lit.)
Density 
1.188 g/mL at 25 °C (lit.)
vapor pressure 
4.58Pa at 25℃
refractive index 
n20/D 1.45(lit.)
Flash point:
206 °F
storage temp. 
2-8°C
form 
Liquid
color 
Colorless to Almost colorless
Water Solubility 
Insoluble in water.
LogP
-0.24 at 25℃ and pH6.5
Surface tension
70.403mN/m at 1g/L and 20℃
CAS DataBase Reference
4427-96-7(CAS DataBase Reference)
EPA Substance Registry System
1,3-Dioxolan-2-one, 4-ethenyl- (4427-96-7)
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Safety

Hazard Codes 
T
Risk Statements 
25
Safety Statements 
45
RIDADR 
UN 2810 6.1/PG 3
WGK Germany 
1
TSCA 
Yes
HazardClass 
6.1
PackingGroup 
III
HS Code 
29209090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H301Toxic if swalloed

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
496820
Product name
4-Vinyl-1,3-dioxolan-2-one
Purity
99%
Packaging
1kg
Price
$243
Updated
2024/03/01
Sigma-Aldrich
Product number
496820
Product name
4-Vinyl-1,3-dioxolan-2-one
Purity
99%
Packaging
5kg
Price
$997
Updated
2024/03/01
TCI Chemical
Product number
V0114
Product name
4-Vinyl-1,3-dioxolan-2-one
Purity
>98.0%(GC)
Packaging
25g
Price
$42
Updated
2024/03/01
TCI Chemical
Product number
V0114
Product name
4-Vinyl-1,3-dioxolan-2-one
Purity
>98.0%(GC)
Packaging
100g
Price
$119
Updated
2024/03/01
Alfa Aesar
Product number
H60822
Product name
4-Vinyl-1,3-dioxolan-2-one, 99%
Packaging
50g
Price
$73.4
Updated
2023/06/20
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4-Vinyl-1,3-dioxolan-2-one Chemical Properties,Usage,Production

Chemical Properties

Colorless liquid

Uses

It is used to synthesize functional polymers.

Uses

4-Vinyl-1,3-dioxolan-2-one may be used in the preparation of 2-arylbenzo[d]thiazole scaffolds.
It may be used in the synthesis of the following multi-functional cyclic carbonates:

  • 4,4′-((hexane-1,6-diylbis(sulfanediyl))bis-(ethane-2,1-diyl))bis(1,3-dioxolan-2-one) (Bis-CC)
  • 2-ethyl-2-(((3-((2-(2-oxo-1,3-dioxolan-4-yl)-ethyl)thio)propanoyl)oxy) methyl)propane-1,3-diyl bis(3-((2-(2-oxo-1,3-dioxolan-4-yl)ethyl)thio)propanoate) (Tris-CC)
  • 2,2-bis(((3-((2-(2-oxo-1,3-dioxolan-4-yl)ethyl)-thio)propanoyl)oxy) methyl)propane-1,3-diyl bis(3-((2-(2-oxo-1,3-dioxolan-4-yl)ethyl)thio)propanoate) (Tetra-CC)

Synthesis Reference(s)

Journal of the American Chemical Society, 69, p. 2955, 1947 DOI: 10.1021/ja01204a008

General Description

4-Vinyl-1,3-dioxolan-2-one (VEC) is a cyclic carbonate, that can be synthesized from acrolein by reacting with sulfur ylide and CO2. The ruthenium-catalyzed transfer hydrogenation (TH) of VEC in the presence of 2-propanol forms 1,2-butanediol. Indolines and indoles undergo selective C-H allylation with VEC in the presence of rhodium(III) catalyst.

4-Vinyl-1,3-dioxolan-2-one Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from 4-Vinyl-1,3-dioxolan-2-one manufacturers

hebei hongtan Biotechnology Co., Ltd
Product
Vinyl Ethylene Carbonate 4427-96-7
Price
US $30.00/kg
Min. Order
1kg
Purity
98%
Supply Ability
2000kg
Release date
2024-03-25
Henan Fengda Chemical Co., Ltd
Product
4-Vinyl-1,3-dioxolan-2-one 4427-96-7
Price
US $8.00-3.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
g-kg-tons, free sample is available
Release date
2024-04-03
Longyan Tianhua Biological Technology Co., Ltd
Product
4-VINYL-1,3-DIOXOLAN-2-ONE 4427-96-7
Price
US $20.00/Kg/Bag
Min. Order
1Kg/Bag
Purity
99
Supply Ability
999
Release date
2020-11-06

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