ChemicalBook > CAS DataBase List > 4-Vinyl-1,3-dioxolan-2-one

4-Vinyl-1,3-dioxolan-2-one

Product Name
4-Vinyl-1,3-dioxolan-2-one
CAS No.
4427-96-7
Chemical Name
4-Vinyl-1,3-dioxolan-2-one
Synonyms
Vinyl Ethylene Carbonate;VEC)4-Vinyl-1,3-d;4-Vinyl-1,3-dioxolan-2-one;2-Oxo-4-vinyl-1,3-dioxolane;4-Ethenyl-1,3-dioxolan-2-one;Vinyl Ethylene Carbonate(VEC);4-VINYL-1,3-DIOXOLAN-2-ONE 99%;4-VINYL-1 3-DIOXOLAN-2-ONE 99;1,3-Dioxolan-2-one, 4-ethenyl-;4-Vinyl-1,3-dioxolan-2-one(VEC)
CBNumber
CB9504374
Molecular Formula
C5H6O3
Formula Weight
114.1
MOL File
4427-96-7.mol
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4-Vinyl-1,3-dioxolan-2-one Property

Boiling point:
237 °C/733 mmHg (lit.)
Density 
1.188 g/mL at 25 °C (lit.)
vapor pressure 
4.58Pa at 25℃
refractive index 
n20/D 1.45(lit.)
Flash point:
206 °F
storage temp. 
2-8°C
form 
Liquid
color 
Colorless to Almost colorless
Water Solubility 
Insoluble in water.
LogP
-0.24 at 25℃ and pH6.5
Surface tension
70.403mN/m at 1g/L and 20℃
CAS DataBase Reference
4427-96-7(CAS DataBase Reference)
EPA Substance Registry System
1,3-Dioxolan-2-one, 4-ethenyl- (4427-96-7)
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Safety

Hazard Codes 
T
Risk Statements 
25
Safety Statements 
45
RIDADR 
UN 2810 6.1/PG 3
WGK Germany 
1
TSCA 
Yes
HazardClass 
6.1
PackingGroup 
III
HS Code 
29209090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H301Toxic if swalloed

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
496820
Product name
4-Vinyl-1,3-dioxolan-2-one
Purity
99%
Packaging
1kg
Price
$243
Updated
2024/03/01
Sigma-Aldrich
Product number
496820
Product name
4-Vinyl-1,3-dioxolan-2-one
Purity
99%
Packaging
5kg
Price
$997
Updated
2024/03/01
TCI Chemical
Product number
V0114
Product name
4-Vinyl-1,3-dioxolan-2-one
Purity
>98.0%(GC)
Packaging
25g
Price
$42
Updated
2024/03/01
TCI Chemical
Product number
V0114
Product name
4-Vinyl-1,3-dioxolan-2-one
Purity
>98.0%(GC)
Packaging
100g
Price
$119
Updated
2024/03/01
Alfa Aesar
Product number
H60822
Product name
4-Vinyl-1,3-dioxolan-2-one, 99%
Packaging
50g
Price
$73.4
Updated
2023/06/20
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4-Vinyl-1,3-dioxolan-2-one Chemical Properties,Usage,Production

Chemical Properties

Colorless liquid

Uses

It is used to synthesize functional polymers.

Uses

4-Vinyl-1,3-dioxolan-2-one may be used in the preparation of 2-arylbenzo[d]thiazole scaffolds.
It may be used in the synthesis of the following multi-functional cyclic carbonates:

  • 4,4′-((hexane-1,6-diylbis(sulfanediyl))bis-(ethane-2,1-diyl))bis(1,3-dioxolan-2-one) (Bis-CC)
  • 2-ethyl-2-(((3-((2-(2-oxo-1,3-dioxolan-4-yl)-ethyl)thio)propanoyl)oxy) methyl)propane-1,3-diyl bis(3-((2-(2-oxo-1,3-dioxolan-4-yl)ethyl)thio)propanoate) (Tris-CC)
  • 2,2-bis(((3-((2-(2-oxo-1,3-dioxolan-4-yl)ethyl)-thio)propanoyl)oxy) methyl)propane-1,3-diyl bis(3-((2-(2-oxo-1,3-dioxolan-4-yl)ethyl)thio)propanoate) (Tetra-CC)

Synthesis Reference(s)

Journal of the American Chemical Society, 69, p. 2955, 1947 DOI: 10.1021/ja01204a008

General Description

4-Vinyl-1,3-dioxolan-2-one (VEC) is a cyclic carbonate, that can be synthesized from acrolein by reacting with sulfur ylide and CO2. The ruthenium-catalyzed transfer hydrogenation (TH) of VEC in the presence of 2-propanol forms 1,2-butanediol. Indolines and indoles undergo selective C-H allylation with VEC in the presence of rhodium(III) catalyst.

4-Vinyl-1,3-dioxolan-2-one Preparation Products And Raw materials

Raw materials

Preparation Products

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4-Vinyl-1,3-dioxolan-2-one Suppliers

China 209 Europe 1 Germany 1 India 2 Japan 2 Slovakia 1 South Korea 1 Switzerland 1 United Kingdom 2 United States 13 Global 233
SIGMA-RBI
Tel
--
Fax
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Country
Switzerland
ProdList
6896
Advantage
91
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View Lastest Price from 4-Vinyl-1,3-dioxolan-2-one manufacturers

hebei hongtan Biotechnology Co., Ltd
Product
Vinyl Ethylene Carbonate 4427-96-7
Price
US $30.00/kg
Min. Order
1kg
Purity
98%
Supply Ability
2000kg
Release date
2024-05-15
Shaanxi Dideu Medichem Co. Ltd
Product
4-Vinyl-1,3-dioxolan-2-one 4427-96-7
Price
US $1.00-0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
200000KG
Release date
2020-01-08
Shaanxi Dideu Medichem Co. Ltd
Product
4-VINYL-1,3-DIOXOLAN-2-ONE 4427-96-7
Price
US $1.00-0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
10000KG
Release date
2020-01-10

4427-96-7, 4-Vinyl-1,3-dioxolan-2-oneRelated Search:

Diethyl carbonate VINYL PROPIONATE Ethyl methyl carbonate Triethyl phosphite ETHYLENE Ethylene carbonate Calcium carbonate Dimethyl carbonate ETHYLENE OXIDE Diethyl phosphite Ethylene glycol Sodium carbonate Vinyl acetate Vinylene carbonate ALLYL PHENYL CARBONATE 97 LANTHANUM CARBONATE HOLMIUM CARBONATE Guanidine carbonate Vinyl Ethylene Carbonate

  • 4-VINYL-1 3-DIOXOLAN-2-ONE 99
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  • 4-Vinyl-1,3-dioxolan-2-one ,99.5%
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  • VEC)4-Vinyl-1,3-d
  • Vinyl Ethylene Carbonate(VEC)
  • 1,3-Dioxolan-2-one, 4-ethenyl-
  • 4-Vinyl-1,3-dioxolan-2-one(VEC)
  • 2-Oxo-4-vinyl-1,3-dioxolane
  • 4427-96-7
  • Fine Chemical