Reaction
ChemicalBook > CAS DataBase List > (ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-,2'-BIS[BIS[3,5-BIS(TRIFLUOROMETHYL)PHENYL]PHOSPHINO]FERROCENE

(ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-,2'-BIS[BIS[3,5-BIS(TRIFLUOROMETHYL)PHENYL]PHOSPHINO]FERROCENE

Reaction
Product Name
(ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-,2'-BIS[BIS[3,5-BIS(TRIFLUOROMETHYL)PHENYL]PHOSPHINO]FERROCENE
CAS No.
494227-36-0
Chemical Name
(ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-,2'-BIS[BIS[3,5-BIS(TRIFLUOROMETHYL)PHENYL]PHOSPHINO]FERROCENE
Synonyms
MANDYPHOS SL-M003-1;]-1,1'-bis[di(3,5-trifL;(aR,aR)-1,1#-Bis[-(dimethylamino)benzyl]-(S,S)-2,2#-bis{bis[3,5-bis(trifl;(S,S)-(-)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis[di(3,5-trifluoromethylphenyl)phos;(SP,SμP)-1,1μ-Bis{bis[3,5-bis(trifluoromethyl)phenyl]phosphino}-2,2μ-bis[(R)-α-(dimethylamino)benzyl]ferrocene;(αr,αr)-1,1'-bis[α-(dimethylamino)benzyl]-(s,s)-,2'-bis{bis[3,5-bis(trifluoromethyl)phenyl]phosphino}ferrocene;(SP,S′P)-1,1′-Bis{bis[3,5-bis(trifluoroMethyl)phenyl]phosphino}-2,2′-bis[(R)-α-(diMethylaMino)benzyl]ferrocene;(R,R)-1,1'-BIS[BIS[3,5-BIS(TRIFLUOROMETHYL)PHENYL]PHOSPHINO]-2,2'-BIS[(R)-ALPHA-(DIMETHYLAMINO)BENZYL]FERROCENE;(1R,1'R)-1,1'-Bis[bis[3,5-bis(trifluoromethyl)phenyl]phosphino]-2,2'-bis[(R)-(dimethylamino)phenylmethyl]ferrocene;(1R,1'R)-1,1'-Bis[bis[3,5-bis(trifluoromethyl)phenyl]phosphino]-2,2'-bis[(R)-(dimethylamino)phenylmethyl]ferrocene
CBNumber
CB9671090
Molecular Formula
C60H42F24FeN2P210*
Formula Weight
1364.74
MOL File
494227-36-0.mol
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(ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-,2'-BIS[BIS[3,5-BIS(TRIFLUOROMETHYL)PHENYL]PHOSPHINO]FERROCENE Property

alpha 
-250.2° (c 1.0, CHCl3)
form 
solid
color 
orange-red
Stability:
store cold
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Safety

Risk Statements 
36/37/38
Safety Statements 
26-36/37/39
WGK Germany 
3
HS Code 
29319090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
73467
Product name
(SP,S′P)-1,1′-Bis{bis[3,5-bis(trifluoromethyl)phenyl]phosphino}-2,2′-bis[(R)-α-(dimethylamino)benzyl]ferrocene
Purity
≥97%
Packaging
100mg
Price
$94
Updated
2021/12/16
Sigma-Aldrich
Product number
73467
Product name
(SP,S′P)-1,1′-Bis{bis[3,5-bis(trifluoromethyl)phenyl]phosphino}-2,2′-bis[(R)-α-(dimethylamino)benzyl]ferrocene
Purity
≥97%
Packaging
500mg
Price
$378
Updated
2021/12/16
Strem Chemicals
Product number
26-0244
Product name
(S,S)-(-)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis[di(3,5-trifluoromethylphenyl)phosphino]ferrocene, min. 97%
Packaging
100mg
Price
$96
Updated
2024/03/01
Strem Chemicals
Product number
26-0244
Product name
(S,S)-(-)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis[di(3,5-trifluoromethylphenyl)phosphino]ferrocene, min. 97%
Packaging
500mg
Price
$355
Updated
2024/03/01
Strem Chemicals
Product number
26-0244
Product name
(S,S)-(-)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis[di(3,5-trifluoromethylphenyl)phosphino]ferrocene, min. 97%
Packaging
2g
Price
$1207
Updated
2024/03/01
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(ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-,2'-BIS[BIS[3,5-BIS(TRIFLUOROMETHYL)PHENYL]PHOSPHINO]FERROCENE Chemical Properties,Usage,Production

Reaction

  1. Ligand for Rh-catalyzed asymmetric hydrogenation of α-acetamidoacrylates.
  2. Ligand for Rh-catalyzed hydrogenation of αand β-enamides, acrylic acid derivatives, itaconates, β-ketoesters and 1,3diketones.
  3. Ligand for Rh-catalyzed asymmetric hydrogenation of furyl-substituted (Z)-dehydroamino acid derivatives.
  4. Ligand for Ir-catalyzed asymmetric transfer hydrogenation of ketones.
  5. Ligand for Cu-catalyzed enantioselective hydroboration of αand β-unsaturated esters and nitriles.

Chemical Properties

Orange powder

(ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-,2'-BIS[BIS[3,5-BIS(TRIFLUOROMETHYL)PHENYL]PHOSPHINO]FERROCENE Preparation Products And Raw materials

Raw materials

Preparation Products

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(ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-,2'-BIS[BIS[3,5-BIS(TRIFLUOROMETHYL)PHENYL]PHOSPHINO]FERROCENE Suppliers

China 29 Germany 2 Switzerland 1 United States 3 Global 35
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View Lastest Price from (ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-,2'-BIS[BIS[3,5-BIS(TRIFLUOROMETHYL)PHENYL]PHOSPHINO]FERROCENE manufacturers

Career Henan Chemical Co
Product
(ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-,2'-BIS[BIS[3,5-BIS(TRIFLUOROMETHYL)PHENYL]PHOSPHINO]FERROCENE 494227-36-0
Price
US $1.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
200kgs
Release date
2020-01-10

494227-36-0, (ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-,2'-BIS[BIS[3,5-BIS(TRIFLUOROMETHYL)PHENYL]PHOSPHINO]FERROCENERelated Search:

(ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-2,2'-BIS(DIPHENYLPHOSPHINO)FERROCENE (S)-1-{(R)-2-[BIS(4-METHOXY-3,5-DIMETHYLPHENYL)PHOSPHINO]FERROCENYL}ETHYLDICYCLO (ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-2,2'-BIS(DICYCLOHEXYLPHOSPHINO)FERROCENE (ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-2,2'-BIS[BIS(4-METHOXY-3,5-DIMETHYLPHENYL)PHOSPHINO]FERROCENE (ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-2,2'-BIS[DI(3,5-XYLYL)PHOSPHINO]FERROCENE 1,1'-DIETHYLFERROCENE Ferrocene (R)-(+)-N,N-DIMETHYL-1-FERROCENYLETHYLAMINE (+/-)-N,N-DIMETHYL-1-FERROCENYLETHYLAMINE (R)-N,N-DIMETHYL-1-[(S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLAMINE 1,1'-DIMETHYLFERROCENE 1,1'-Bis(diphenylphosphino)ferrocene (3-AMINOPROPYL)DIPHENYLPHOSPHINE N,N-Dimethylaminomethylferrocene (R)-(-)-ALPHA-[(S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]BENZYLAMINE (R)-(S)-BPPFA BIS(3,5-DI(TRIFLUOROMETHYL)PHENYL)PHOSPHINE (ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-,2'-BIS[BIS[3,5-BIS(TRIFLUOROMETHYL)PHENYL]PHOSPHINO]FERROCENE

  • MANDYPHOS SL-M003-1
  • (ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-,2'-BIS[BIS[3,5-BIS(TRIFLUOROMETHYL)PHENYL]PHOSPHINO]FERROCENE
  • (aR,aR)-1,1#-Bis[<alpha>-(dimethylamino)benzyl]-(S,S)-2,2#-bis{bis[3,5-bis(trifl
  • (S,S)-(-)-2,2'-Bis((R)-(N,N-dimethylamino)-(phenyl)methyl)-1,1'-di(bis(3,5-trifluoromethylphenyl)phosphino)ferrocene
  • (R,R)-1,1'-BIS[BIS[3,5-BIS(TRIFLUOROMETHYL)PHENYL]PHOSPHINO]-2,2'-BIS[(R)-ALPHA-(DIMETHYLAMINO)BENZYL]FERROCENE
  • (S,S)-(-)-2,2'-BIS[(R)-(N,N-DIMETHYLAMINO)(PHENYL)METHYL]-1,1'-DI[BIS(3,5-TRIFLUOROMETHYLPHENYL)PHOSPHINO]FERROCENE
  • (S,S)-(-)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis[di(3,5-trifluoromethylphenyl)phosphino]ferrocene,min.97%
  • (r,r)-1,1'-bis{bis[3,5-bis(trifluoromethyl)phenyl]phosphino}-2,2'-bis[(r)-α-(dimethylamino)benzyl]ferrocene (acc to cas)
  • (αr,αr)-1,1'-bis[α-(dimethylamino)benzyl]-(s,s)-,2'-bis{bis[3,5-bis(trifluoromethyl)phenyl]phosphino}ferrocene
  • (SP,SμP)-1,1μ-Bis{bis[3,5-bis(trifluoromethyl)phenyl]phosphino}-2,2μ-bis[(R)-α-(dimethylamino)benzyl]ferrocene
  • Mandyphos SL-M003-1, (1R,1μR)-1,1μ-Bis[bis[3,5-bis(trifluoromethyl)phenyl]phosphino]-2,2μ-bis[(R)-(dimethylamino)phenylmethyl]ferrocene (acc to CAS)
  • (S,S)-(-)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis[di(3,5-trifluoromethylphenyl) phosphino]ferrocene, min. 97%
  • (S,S)-(-)-2,2'-Bis[(R)-(N,N-diMethylaMino)(phenyl)Methyl]-1,1'-bis[di(3,5-trifluoroMethylphenyl)phosphino]ferrocene
  • (aR,aR)-2,2'-Bis(α-N,N-dimethylaminophenylmethyl)-(S,S)-1,1'-bis[di(bis-(3,5-trifluoromethyl)phenyl)-phosphino]ferrocene
  • (aR,aR)-2,2'-Bis(a-N,N-dimethylaminophenylmethyl)-(S,S)-1,1'-bis[di-(bis(3,5-trifluoromethyl)-phenyl)phosphino]-ferrocene
  • (1R,1'R)-1,1'-Bis[bis[3,5-bis(trifluoromethyl)phenyl]phosphino]-2,2'-bis[(R)-(dimethylamino)phenylmethyl]ferrocene
  • (S,S)-(-)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis[di(3,5-trifluoromethylphenyl)phos
  • ]-1,1'-bis[di(3,5-trifL
  • (S,S)Fc-1,1’-Bis[bis[3,5-bis(trifluoromethyl)phenyl] phosphino]-2,2’-bis[(R,R)C-(N,N-dimethylamino) phenylmethyl]ferrocene
  • (SP,S′P)-1,1′-Bis{bis[3,5-bis(trifluoroMethyl)phenyl]phosphino}-2,2′-bis[(R)-α-(diMethylaMino)benzyl]ferrocene
  • (ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-,2'-BIS[BIS[3,5-BIS(TRIFLUOROMETHYL)PHENYL]PHOSPHINO]FERROCENE
  • (S,S)-(-)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis[di(3,5-trifluoromethylphenyl)phosphino]ferrocene
  • (1R,1'R)-1,1'-Bis[bis[3,5-bis(trifluoromethyl)phenyl]phosphino]-2,2'-bis[(R)-(dimethylamino)phenylmethyl]ferrocene
  • 494227-36-0
  • C60H42F24FeN2P2
  • Solvias Ligands
  • Privileged Ligands
  • Asymmetric Synthesis
  • Chiral Catalysts, Ligands, and Reagents
  • Chiral Phosphine
  • Ferrocene Series
  • Mandyphos Series