4-(Methylmercapto)aniline

Product Name: 4-(Methylmercapto)aniline
CAS No.: 104-96-1
Chemical Name: 4-(Methylmercapto)aniline
Synonyms: 4-(METHYLTHIO)ANILINE;AKOS 91153;P-THIOANISIDINE;P-AMINOTHIOANISOLE;4-AMINOTHIOANISOLE;TIMTEC-BB SBB006658;p-Thiomethoxyaniline;4-(Methylmercapto)an;p-(methylthio)-anilin;P-(METHYLTHIO)ANILINE
CBNumber: CB9685172
Molecular Formula: C7H9NS
Formula Weight: 139.22
MOL File: 104-96-1.mol

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4-(Methylmercapto)aniline Property

Melting point:: 156-158 °C
Boiling point:: 272-273 °C(lit.)
Density: 1.119 g/mL at 25 °C(lit.)
refractive index: n20/D 1.639(lit.)
Flash point:: >230 °F
storage temp.: Keep in dark place,Inert atmosphere,Room temperature
form: Liquid
pka: 4.35(at 25℃)
color: Clear orange to brown-red
Sensitive: Stench
BRN: 774506
InChI: InChI=1S/C7H9NS/c1-9-7-4-2-6(8)3-5-7/h2-5H,8H2,1H3
InChIKey: YKFROQCFVXOUPW-UHFFFAOYSA-N
SMILES: C1(N)=CC=C(SC)C=C1
CAS DataBase Reference: 104-96-1(CAS DataBase Reference)
NIST Chemistry Reference: 4-Methylmercaptoaniline(104-96-1)
EPA Substance Registry System: Benzenamine, 4-(methylthio)- (104-96-1)

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Safety

Hazard Codes: Xi,Xn
Risk Statements: 36/37/38-22
Safety Statements: 26-36-37/39
RIDADR: 2810
WGK Germany: 3
RTECS: BY6302000
F: 2-8-10-13
Hazard Note: Irritant/Stench
TSCA: T
HazardClass: IRRITANT, STENCH
HazardClass: 6.1
PackingGroup: III
HS Code: 29309090
Toxicity: LD50 orl-qal: 562 mg/kg AECTCV 12,355,83

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: M54503
Product name: 4-(Methylthio)aniline
Purity: 98%
Packaging: 5g
Price: $31.2
Updated: 2024/03/01

Sigma-Aldrich

Product number: M54503
Product name: 4-(Methylthio)aniline
Purity: 98%
Packaging: 25g
Price: $54.06
Updated: 2024/03/01

TCI Chemical

Product number: M1674
Product name: 4-(Methylthio)aniline
Purity: >98.0%(GC)(T)
Packaging: 25g
Price: $154
Updated: 2024/03/01

Alfa Aesar

Product number: L04950
Product name: 4-(Methylthio)aniline, 98%
Packaging: 5g
Price: $34.65
Updated: 2024/03/01

Alfa Aesar

Product number: L04950
Product name: 4-(Methylthio)aniline, 98%
Packaging: 25g
Price: $139.65
Updated: 2024/03/01

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4-(Methylmercapto)aniline Chemical Properties,Usage,Production

Chemical Properties

clear orange to brown-red liquid

Definition

ChEBI: 4-(methylthio) aniline is an aryl sulfide.

Synthesis Reference(s)

Tetrahedron Letters, 35, p. 7867, 1994 DOI: 10.1016/0040-4039(94)80139-8

Safety Profile

Moderately toxic by ingestion.When heated to decomposition it emits toxic vapors ofNOx and SOx.

Purification Methods

Purify the aniline by fractional distillation in an inert atmosphere. The hydrochloride has m 242-246o (from aqueous EtOH/HCl). The sulfone has m 137o (from H2O), pK2 5 1.48, and the sulfone hydrochloride has m 260-261o (from aqueous EtOH/HCl). [Lumbroso & Passerini Bull Soc Chim Fr 311 1957, Mangini & Passerini J Chem Soc 4954 1956, Beilstein 13 H 533, 13 II 297, 13 IV 1221.]

4-(Methylmercapto)aniline Preparation Products And Raw materials

Raw materials

Preparation Products

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4-(Methylmercapto)aniline Suppliers

Americas 1 Belgium 2 China 138 Europe 2 Germany 5 India 9 Japan 8 Slovakia 1 South Korea 2 Switzerland 3 The Netherlands 1 Ukraine 2 United Kingdom 12 United States 33 Global 219

J & K SCIENTIFIC LTD.

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Email: jkinfo@jkchemical.com
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Advantage: 76

Meryer (Shanghai) Chemical Technology Co., Ltd.

Tel: 021-61259108 18621169109
Fax: 86-21-61259102
Email: market03@meryer.com
Country: China
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Advantage: 62

Alfa Aesar

Tel: 400-6106006
Fax: 021-67582001/03/05
Email: saleschina@alfa-asia.com
Country: China
ProdList: 30123
Advantage: 84

TAIYUAN RHF CO.,LTD.

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TCI (Shanghai) Development Co., Ltd.

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Email: Sales-CN@TCIchemicals.com
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Energy Chemical

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Wuhan Chemwish Technology Co., Ltd

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Capot Chemical Co., Ltd

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Beijing Ouhe Technology Co., Ltd

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View Lastest Price from 4-(Methylmercapto)aniline manufacturers

Hebei Mojin Biotechnology Co., Ltd

Product: 4-(Methylmercapto)aniline 104-96-1
Price: US $200.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 5000KG
Release date: 2023-03-03

Zhuozhou Wenxi import and Export Co., Ltd

Product: 4-(Methylmercapto)aniline 104-96-1
Price: US $15.00-10.00/KG
Min. Order: 1KG
Purity: 99%+ HPLC
Supply Ability: Monthly supply of 1 ton
Release date: 2021-06-27

Career Henan Chemical Co

Product: 4-(Methylmercapto)aniline 104-96-1
Price: US $3.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 100kg
Release date: 2019-07-11

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