Uses
ChemicalBook > CAS DataBase List > 5-BROMO-2-NITRO-BENZOIC ACID

5-BROMO-2-NITRO-BENZOIC ACID

Uses
Product Name
5-BROMO-2-NITRO-BENZOIC ACID
CAS No.
6950-43-2
Chemical Name
5-BROMO-2-NITRO-BENZOIC ACID
Synonyms
5-Bromo-2-nitrobenzoicaci;5-BROMO-2-NITRO-BENZOIC ACID;Benzoic acid, 5-bromo-2-nitro-;5-BROMO-2-NITRO-BENZOIC ACID >98%
CBNumber
CB9694158
Molecular Formula
C7H4BrNO4
Formula Weight
246.01
MOL File
6950-43-2.mol
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5-BROMO-2-NITRO-BENZOIC ACID Property

Melting point:
139-141°C
Boiling point:
382.08°C (rough estimate)
Density 
2.0176 (rough estimate)
refractive index 
1.6500 (estimate)
storage temp. 
Sealed in dry,Room Temperature
form 
powder
pka
1.85±0.25(Predicted)
color 
Light creamy gold
InChI
InChI=1S/C7H4BrNO4/c8-4-1-2-6(9(12)13)5(3-4)7(10)11/h1-3H,(H,10,11)
InChIKey
FNINYRSNPGPWEL-UHFFFAOYSA-N
SMILES
C(O)(=O)C1=CC(Br)=CC=C1[N+]([O-])=O
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Safety

Hazard Codes 
Xi
Risk Statements 
20/21/22
Safety Statements 
22-24/25
HS Code 
29163990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H314Causes severe skin burns and eye damage

Precautionary statements

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P330+P331IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P403+P233Store in a well-ventilated place. Keep container tightly closed.

P405Store locked up.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

TRC
Product number
B697960
Product name
5-Bromo-2-nitrobenzoicacid
Packaging
1g
Price
$75
Updated
2021/12/16
Biosynth Carbosynth
Product number
FB37399
Product name
5-Bromo-2-nitrobenzoic acid
Packaging
500mg
Price
$85
Updated
2021/12/16
Biosynth Carbosynth
Product number
FB37399
Product name
5-Bromo-2-nitrobenzoic acid
Packaging
1g
Price
$136.8
Updated
2021/12/16
Apolloscientific
Product number
OR59833
Product name
5-Bromo-2-nitrobenzoicacid
Packaging
25g
Price
$209
Updated
2021/12/16
Biosynth Carbosynth
Product number
FB37399
Product name
5-Bromo-2-nitrobenzoic acid
Packaging
2g
Price
$218.8
Updated
2021/12/16
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5-BROMO-2-NITRO-BENZOIC ACID Chemical Properties,Usage,Production

Uses

5-Bromo-2-nitrobenzoic acid is a carboxylic acid derivative and can be used as an organic intermediate.

Chemical Properties

Colorless crystal

Synthesis

585-76-2

6950-43-2

3-Bromobenzoic acid (249 g, 1.24 mol, 1.0 eq.) was suspended in concentrated sulfuric acid (800 mL), and the suspension was cooled to 0 °C. The solution was then mixed with nitric acid (57.2 mL, 1.2 mol). Nitric acid (57.1 mL, 1.2 mol) was slowly added dropwise with stirring. After the dropwise addition was completed, the reaction mixture was gradually warmed to 20 °C and stirring was continued for 1 hour. After completion of the reaction, the mixture was carefully poured into ice water (2 L). The precipitate precipitated was collected by filtration, washed sequentially with water (1000 mL x 2) and dried to give 5-bromo-2-nitrobenzoic acid (280 g, 1.14 mol, 91.94% yield) as a white solid. The product was characterized by 1H NMR (400 MHz, DMSO-d6): δ= 14.12 (br.s, 1H), 8.00 (d, J = 1.8 Hz, 1H), 7.98-7.90 (m, 2H).

References

[1] Patent: US2017/190713, 2017, A1. Location in patent: Paragraph 0188
[2] Small, 2015, vol. 11, # 33, p. 4090 - 4096

5-BROMO-2-NITRO-BENZOIC ACID Preparation Products And Raw materials

Raw materials

Preparation Products

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5-BROMO-2-NITRO-BENZOIC ACID Suppliers

Nanjing Qishi Biotechnology Co. Ltd.
Tel
19822610310
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3122922726@qq.com
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China
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Anhui Dexinjia Biopharm Co., Ltd
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0531-82375892 15553111391
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3276840968@qq.com
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China
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EXON BIOPHARMA CO., LTD.
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18920309966
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cathrine@263.net
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China
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Wuhan EnTai Technology Development Co,.Ltd
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86-27-82330560
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86-27-82330547
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2536851935@qq.com
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China
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J & K SCIENTIFIC LTD.
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18210857532; 18210857532
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86-10-82849933
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jkinfo@jkchemical.com
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3B Pharmachem (Wuhan) International Co.,Ltd.
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821-50328103-801 18930552037
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86-21-50328109
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3bsc@sina.com
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China
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Wuhan Chemwish Technology Co., Ltd
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86-027-67849912
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86-027-87531808
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sales@chemwish.com
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China
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Shanghai Sinch Parmaceuticals Tech. Co. Ltd.
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+86-21-54098501
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+86-21-54096319
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sales@sinch.com.cn
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China
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Jia Xing Isenchem Co.,Ltd
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0573-85285100 18627885956
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0573-85285100
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isenchem@163.com
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China
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Shanghai Harvest Chemical Industrial Co., Ltd.
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021-31038972,31038973 17321035817
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+86-21-51385350
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sales@harvest-chem.com
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China
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View Lastest Price from 5-BROMO-2-NITRO-BENZOIC ACID manufacturers

Anhui Dexinjia Biopharm Co., Ltd
Product
5-BROMO-2-NITRO-BENZOIC ACID 6950-43-2
Price
US $150.00-450.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
3MT per month
Release date
2023-04-02
Hangzhou ICH Biofarm Co., Ltd
Product
5-Bromo-2-nitrobenzoic acid 6950-43-2
Price
US $0.00/kg
Min. Order
1kg
Purity
98%
Supply Ability
2000kg
Release date
2023-06-09
Zhuozhou Wenxi import and Export Co., Ltd
Product
5-BROMO-2-NITRO-BENZOIC ACID 6950-43-2
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-07-10