METHYL 2-BROMO-4-NITROBENZOATE

Product Name: METHYL 2-BROMO-4-NITROBENZOATE
CAS No.: 100959-22-6
Chemical Name: METHYL 2-BROMO-4-NITROBENZOATE
Synonyms: methy 2-bromo-4-nitrobenzoate;METHYL 2-BROMO-4-NITROBENZOATE;Methyl2-Bromo-4-nitrobenzoate>Methyl 2-bromo-4-nitrobenzoate 97%;2-Bromo-4-nitro-benzoic acid methyleste;3-Bromo-4-(methoxycarbonyl)nitrobenzene;4-nitro-2-broMobenzoic acid Methyl ester;2-BroMo-4-nitrobenzoic acid Methyl ester;Methyl 2-Bromo-4-Nitrobenzoate(100959-22-6);Benzoic acid, 2-bromo-4-nitro-, methyl ester
CBNumber: CB9481000
Molecular Formula: C8H6BrNO4
Formula Weight: 260.04
MOL File: 100959-22-6.mol

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METHYL 2-BROMO-4-NITROBENZOATE Property

Melting point:: 82.0 to 86.0 °C
Boiling point:: 339.2±27.0 °C(Predicted)
Density: 1.673±0.06 g/cm3(Predicted)
storage temp.: Sealed in dry,Room Temperature
form: powder to crystal
color: Light orange to Yellow to Green
InChI: InChI=1S/C8H6BrNO4/c1-14-8(11)6-3-2-5(10(12)13)4-7(6)9/h2-4H,1H3
InChIKey: XYMZAFDNPJLOTP-UHFFFAOYSA-N
SMILES: C(OC)(=O)C1=CC=C([N+]([O-])=O)C=C1Br
CAS DataBase Reference: 100959-22-6(CAS DataBase Reference)

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Safety

HS Code: 2916399090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TCI Chemical

Product number: M2123
Product name: Methyl 2-Bromo-4-nitrobenzoate
Purity: >98.0%(GC)
Packaging: 1g
Price: $19
Updated: 2025/07/31

TCI Chemical

Product number: M2123
Product name: Methyl 2-Bromo-4-nitrobenzoate
Purity: >98.0%(GC)
Packaging: 5g
Price: $72
Updated: 2025/07/31

TRC

Product number: M296378
Product name: Methyl 2-Bromo-4-nitrobenzoate
Packaging: 1g
Price: $75
Updated: 2021/12/16

Apolloscientific

Product number: OR18260
Product name: Methyl 2-bromo-4-nitrobenzoate
Packaging: 25g
Price: $83
Updated: 2021/12/16

SynQuest Laboratories

Product number: 4654-9-Z3
Product name: Methyl 2-bromo-4-nitrobenzoate
Packaging: 25g
Price: $98
Updated: 2021/12/16

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METHYL 2-BROMO-4-NITROBENZOATE Chemical Properties,Usage,Production

Synthesis

16426-64-5

74-88-4

100959-22-6

Example 54B Synthesis of methyl 2-bromo-4-nitrobenzoate: 2-bromo-4-nitrobenzoic acid (1.0 g, 4.06 mmol) and potassium carbonate (560 mg) were dissolved in N,N-dimethylformamide (5 mL), followed by the addition of iodomethane (500 μL, 8.03 mmol). The reaction mixture was stirred at room temperature for 1 hour. After completion of the reaction, the mixture was poured into water (30 mL) and extracted with ether (3 x 10 mL). The combined ether layers were washed sequentially with water (1 × 10 mL) and brine (1 × 10 mL), dried over anhydrous magnesium sulfate, filtered, and concentrated under reduced pressure to afford the target product methyl 2-bromo-4-nitrobenzoate (970 mg, 92% yield). The product was confirmed by 1H NMR (300 MHz, CDCl3): δ 8.52 (d, 1H, J=2.4 Hz), 8.21 (dd, 1H, J=2.0,8.5 Hz), 7.92 (d, 1H, J=8.8 Hz), 3.99 (s, 3H); the mass spectrum (ESI) showed m/z=259 (M-H).

References

[1] Patent: WO2013/148365, 2013, A1. Location in patent: Paragraph 00101
[2] Patent: US2002/35137, 2002, A1
[3] Bioorganic and Medicinal Chemistry, 2008, vol. 16, # 4, p. 1702 - 1720

METHYL 2-BROMO-4-NITROBENZOATE Preparation Products And Raw materials

Raw materials

Preparation Products

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METHYL 2-BROMO-4-NITROBENZOATE Suppliers

Americas 1 China 138 Europe 3 India 8 Japan 2 Slovakia 1 United Kingdom 5 United States 17 Global 175

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View Lastest Price from METHYL 2-BROMO-4-NITROBENZOATE manufacturers

Career Henan Chemical Co

Product: METHYL 2-BROMO-4-NITROBENZOATE 100959-22-6
Price: US $1.00/g
Min. Order: 1g
Purity: 99%
Supply Ability: 100000KGS
Release date: 2020-01-10

100959-22-6, METHYL 2-BROMO-4-NITROBENZOATERelated Search:

3-Bromo-2-methoxy-5-trifluoromethylpyridine METHYL 4-BROMO-3-NITROBENZOATE Methyl 3-bromo-5-nitrobenzoate,Methyl 3-bromo-5-nitrobenzoate 98% METHYL 2-BROMO-3-NITROBENZOATE METHYL 2-BROMO-5-NITROBENZOATE,Methyl 2-bromo-5-nitrobenzoate, 98+% METHYL 2-BROMO-4-NITROBENZOATE 2-BROMO-4-NITROBENZOIC ACID 2-BROMO-4-AMINOBENZOIC ACID 2-Bromo-4-nitrotoluene

methy 2-bromo-4-nitrobenzoate

2-BroMo-4-nitrobenzoic acid Methyl ester

3-Bromo-4-(methoxycarbonyl)nitrobenzene

4-nitro-2-broMobenzoic acid Methyl ester

Methyl 2-bromo-4-nitrobenzoate 97%

METHYL 2-BROMO-4-NITROBENZOATE

2-Bromo-4-nitro-benzoic acid methyleste

Methyl2-Bromo-4-nitrobenzoate&gt

Benzoic acid, 2-bromo-4-nitro-, methyl ester

Methyl 2-Bromo-4-Nitrobenzoate(100959-22-6)

2-Bromo-4-nitro-benzoic acid methyl ester - [B71903]

100959-22-6

blocks

Bromides

Carboxes

NitroCompounds