ChemicalBook > CAS DataBase List > METHYL 2-BROMO-4-NITROBENZOATE

METHYL 2-BROMO-4-NITROBENZOATE

Product Name
METHYL 2-BROMO-4-NITROBENZOATE
CAS No.
100959-22-6
Chemical Name
METHYL 2-BROMO-4-NITROBENZOATE
Synonyms
methy 2-bromo-4-nitrobenzoate;METHYL 2-BROMO-4-NITROBENZOATE;Methyl2-Bromo-4-nitrobenzoate>Methyl 2-bromo-4-nitrobenzoate 97%;2-Bromo-4-nitro-benzoic acid methyleste;3-Bromo-4-(methoxycarbonyl)nitrobenzene;4-nitro-2-broMobenzoic acid Methyl ester;2-BroMo-4-nitrobenzoic acid Methyl ester;Methyl 2-Bromo-4-Nitrobenzoate(100959-22-6);Benzoic acid, 2-bromo-4-nitro-, methyl ester
CBNumber
CB9481000
Molecular Formula
C8H6BrNO4
Formula Weight
260.04
MOL File
100959-22-6.mol
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METHYL 2-BROMO-4-NITROBENZOATE Property

Melting point:
82.0 to 86.0 °C
Boiling point:
339.2±27.0 °C(Predicted)
Density 
1.673±0.06 g/cm3(Predicted)
storage temp. 
Sealed in dry,Room Temperature
form 
powder to crystal
color 
Light orange to Yellow to Green
InChI
InChI=1S/C8H6BrNO4/c1-14-8(11)6-3-2-5(10(12)13)4-7(6)9/h2-4H,1H3
InChIKey
XYMZAFDNPJLOTP-UHFFFAOYSA-N
SMILES
C(OC)(=O)C1=CC=C([N+]([O-])=O)C=C1Br
CAS DataBase Reference
100959-22-6(CAS DataBase Reference)
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Safety

HS Code 
2916399090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TCI Chemical
Product number
M2123
Product name
Methyl 2-Bromo-4-nitrobenzoate
Purity
>98.0%(GC)
Packaging
1g
Price
$19
Updated
2025/07/31
TCI Chemical
Product number
M2123
Product name
Methyl 2-Bromo-4-nitrobenzoate
Purity
>98.0%(GC)
Packaging
5g
Price
$72
Updated
2025/07/31
TRC
Product number
M296378
Product name
Methyl 2-Bromo-4-nitrobenzoate
Packaging
1g
Price
$75
Updated
2021/12/16
Apolloscientific
Product number
OR18260
Product name
Methyl 2-bromo-4-nitrobenzoate
Packaging
25g
Price
$83
Updated
2021/12/16
SynQuest Laboratories
Product number
4654-9-Z3
Product name
Methyl 2-bromo-4-nitrobenzoate
Packaging
25g
Price
$98
Updated
2021/12/16
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METHYL 2-BROMO-4-NITROBENZOATE Chemical Properties,Usage,Production

Synthesis

16426-64-5

74-88-4

100959-22-6

Example 54B Synthesis of methyl 2-bromo-4-nitrobenzoate: 2-bromo-4-nitrobenzoic acid (1.0 g, 4.06 mmol) and potassium carbonate (560 mg) were dissolved in N,N-dimethylformamide (5 mL), followed by the addition of iodomethane (500 μL, 8.03 mmol). The reaction mixture was stirred at room temperature for 1 hour. After completion of the reaction, the mixture was poured into water (30 mL) and extracted with ether (3 x 10 mL). The combined ether layers were washed sequentially with water (1 × 10 mL) and brine (1 × 10 mL), dried over anhydrous magnesium sulfate, filtered, and concentrated under reduced pressure to afford the target product methyl 2-bromo-4-nitrobenzoate (970 mg, 92% yield). The product was confirmed by 1H NMR (300 MHz, CDCl3): δ 8.52 (d, 1H, J=2.4 Hz), 8.21 (dd, 1H, J=2.0,8.5 Hz), 7.92 (d, 1H, J=8.8 Hz), 3.99 (s, 3H); the mass spectrum (ESI) showed m/z=259 (M-H).

References

[1] Patent: WO2013/148365, 2013, A1. Location in patent: Paragraph 00101
[2] Patent: US2002/35137, 2002, A1
[3] Bioorganic and Medicinal Chemistry, 2008, vol. 16, # 4, p. 1702 - 1720

METHYL 2-BROMO-4-NITROBENZOATE Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from METHYL 2-BROMO-4-NITROBENZOATE manufacturers

Career Henan Chemical Co
Product
METHYL 2-BROMO-4-NITROBENZOATE 100959-22-6
Price
US $1.00/g
Min. Order
1g
Purity
99%
Supply Ability
100000KGS
Release date
2020-01-10

100959-22-6, METHYL 2-BROMO-4-NITROBENZOATERelated Search:

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  • Methyl 2-bromo-4-nitrobenzoate 97%
  • METHYL 2-BROMO-4-NITROBENZOATE
  • 2-Bromo-4-nitro-benzoic acid methyleste
  • Methyl2-Bromo-4-nitrobenzoate&gt
  • Benzoic acid, 2-bromo-4-nitro-, methyl ester
  • Methyl 2-Bromo-4-Nitrobenzoate(100959-22-6)
  • 2-Bromo-4-nitro-benzoic acid methyl ester - [B71903]
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