METHYL 2-BROMO-4-NITROBENZOATE
- Product Name
- METHYL 2-BROMO-4-NITROBENZOATE
- CAS No.
- 100959-22-6
- Chemical Name
- METHYL 2-BROMO-4-NITROBENZOATE
- Synonyms
- methy 2-bromo-4-nitrobenzoate;METHYL 2-BROMO-4-NITROBENZOATE;Methyl2-Bromo-4-nitrobenzoate>Methyl 2-bromo-4-nitrobenzoate 97%;2-Bromo-4-nitro-benzoic acid methyleste;3-Bromo-4-(methoxycarbonyl)nitrobenzene;4-nitro-2-broMobenzoic acid Methyl ester;2-BroMo-4-nitrobenzoic acid Methyl ester;Methyl 2-Bromo-4-Nitrobenzoate(100959-22-6);Benzoic acid, 2-bromo-4-nitro-, methyl ester
- CBNumber
- CB9481000
- Molecular Formula
- C8H6BrNO4
- Formula Weight
- 260.04
- MOL File
- 100959-22-6.mol
METHYL 2-BROMO-4-NITROBENZOATE Property
- Melting point:
- 82.0 to 86.0 °C
- Boiling point:
- 339.2±27.0 °C(Predicted)
- Density
- 1.673±0.06 g/cm3(Predicted)
- storage temp.
- Sealed in dry,Room Temperature
- form
- powder to crystal
- color
- Light orange to Yellow to Green
- InChI
- InChI=1S/C8H6BrNO4/c1-14-8(11)6-3-2-5(10(12)13)4-7(6)9/h2-4H,1H3
- InChIKey
- XYMZAFDNPJLOTP-UHFFFAOYSA-N
- SMILES
- C(OC)(=O)C1=CC=C([N+]([O-])=O)C=C1Br
- CAS DataBase Reference
- 100959-22-6(CAS DataBase Reference)
Safety
- HS Code
- 2916399090
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H302Harmful if swallowed
H315Causes skin irritation
H319Causes serious eye irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- M2123
- Product name
- Methyl 2-Bromo-4-nitrobenzoate
- Purity
- >98.0%(GC)
- Packaging
- 1g
- Price
- $19
- Updated
- 2025/07/31
- Product number
- M2123
- Product name
- Methyl 2-Bromo-4-nitrobenzoate
- Purity
- >98.0%(GC)
- Packaging
- 5g
- Price
- $72
- Updated
- 2025/07/31
- Product number
- M296378
- Product name
- Methyl 2-Bromo-4-nitrobenzoate
- Packaging
- 1g
- Price
- $75
- Updated
- 2021/12/16
- Product number
- OR18260
- Product name
- Methyl 2-bromo-4-nitrobenzoate
- Packaging
- 25g
- Price
- $83
- Updated
- 2021/12/16
- Product number
- 4654-9-Z3
- Product name
- Methyl 2-bromo-4-nitrobenzoate
- Packaging
- 25g
- Price
- $98
- Updated
- 2021/12/16
METHYL 2-BROMO-4-NITROBENZOATE Chemical Properties,Usage,Production
Synthesis
16426-64-5
74-88-4
100959-22-6
Example 54B Synthesis of methyl 2-bromo-4-nitrobenzoate: 2-bromo-4-nitrobenzoic acid (1.0 g, 4.06 mmol) and potassium carbonate (560 mg) were dissolved in N,N-dimethylformamide (5 mL), followed by the addition of iodomethane (500 μL, 8.03 mmol). The reaction mixture was stirred at room temperature for 1 hour. After completion of the reaction, the mixture was poured into water (30 mL) and extracted with ether (3 x 10 mL). The combined ether layers were washed sequentially with water (1 × 10 mL) and brine (1 × 10 mL), dried over anhydrous magnesium sulfate, filtered, and concentrated under reduced pressure to afford the target product methyl 2-bromo-4-nitrobenzoate (970 mg, 92% yield). The product was confirmed by 1H NMR (300 MHz, CDCl3): δ 8.52 (d, 1H, J=2.4 Hz), 8.21 (dd, 1H, J=2.0,8.5 Hz), 7.92 (d, 1H, J=8.8 Hz), 3.99 (s, 3H); the mass spectrum (ESI) showed m/z=259 (M-H).
References
[1] Patent: WO2013/148365, 2013, A1. Location in patent: Paragraph 00101
[2] Patent: US2002/35137, 2002, A1
[3] Bioorganic and Medicinal Chemistry, 2008, vol. 16, # 4, p. 1702 - 1720
METHYL 2-BROMO-4-NITROBENZOATE Preparation Products And Raw materials
Raw materials
Preparation Products
METHYL 2-BROMO-4-NITROBENZOATE Suppliers
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- 03-36680489
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View Lastest Price from METHYL 2-BROMO-4-NITROBENZOATE manufacturers
- Product
- METHYL 2-BROMO-4-NITROBENZOATE 100959-22-6
- Price
- US $1.00/g
- Min. Order
- 1g
- Purity
- 99%
- Supply Ability
- 100000KGS
- Release date
- 2020-01-10