Synthesis
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Zirconyl chloride octahydrate

Synthesis
Product Name
Zirconyl chloride octahydrate
CAS No.
13520-92-8
Chemical Name
Zirconyl chloride octahydrate
Synonyms
ZIRCONIUM OXYCHLORIDE OCTAHYDRATE;ZirconiuM Chloride octahydrate;Zirconium(Ⅳ)oxychloride octahydrate;ZIRCONIUM CHLORIDE OXIDE OCTAHYDRATE;ZIRCONIUM(IV) OXYCHLORIDE OCTAHYDRATE;oride Octahydrate;zirconyl(di)chloride;Zirconyl chloride oc;ZirconiumOxychlorideGr;ZIRCONIUM CHLORIDE BASIC
CBNumber
CB9696778
Molecular Formula
Cl2H2O2Zr
Formula Weight
322.25
MOL File
13520-92-8.mol
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Zirconyl chloride octahydrate Property

Melting point:
400°C (dec.)
Boiling point:
210°C
Density 
1.91
storage temp. 
Store at +15°C to +25°C.
solubility 
H2O: soluble
form 
Crystalline Powder
Specific Gravity
1.91
color 
White to light yellow
Odor
Odorless
PH
1 (50g/l, H2O, 20℃)
Water Solubility 
SOLUBLE
Sensitive 
Hygroscopic
Merck 
14,10184
Exposure limits
ACGIH: TWA 5 mg/m3; STEL 10 mg/m3
NIOSH: IDLH 25 mg/m3; TWA 5 mg/m3; STEL 10 mg/m3
Stability:
Stable, but may be moisture sensitive. Incompatible with strong oxidizing agents.
CAS DataBase Reference
13520-92-8(CAS DataBase Reference)
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Safety

Hazard Codes 
C
Risk Statements 
34-22-37
Safety Statements 
26-36/37/39-45-27
RIDADR 
UN 3264 8/PG 3
WGK Germany 
1
RTECS 
ZH7250000
TSCA 
Yes
HS Code 
2827 49 90
HazardClass 
8
PackingGroup 
III
Toxicity
LD50 orally in Rabbit: 3500 mg/kg
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H314Causes severe skin burns and eye damage

Precautionary statements

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P330+P331IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
224316
Product name
Zirconyl chloride octahydrate
Purity
reagent grade, 98%
Packaging
5g
Price
$55
Updated
2024/03/01
Sigma-Aldrich
Product number
224316
Product name
Zirconyl chloride octahydrate
Purity
reagent grade, 98%
Packaging
100g
Price
$154
Updated
2024/03/01
Sigma-Aldrich
Product number
1.08917
Product name
Zirconium(IV) oxide chloride octahydrate
Purity
for analysis EMSURE?
Packaging
100g
Price
$178
Updated
2024/03/01
Sigma-Aldrich
Product number
224316
Product name
Zirconyl chloride octahydrate
Purity
reagent grade, 98%
Packaging
500g
Price
$455
Updated
2024/03/01
Alfa Aesar
Product number
A12342
Product name
Zirconium dichloride oxide octahydrate
Purity
98%
Packaging
100g
Price
$64.2
Updated
2023/06/20
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Zirconyl chloride octahydrate Chemical Properties,Usage,Production

Synthesis

Zircon is melted with caustic soda, rinsed, desiliconized, and then reacted with sulfuric acid, and then ammonia water is added to obtain zirconium hydroxide precipitate. Finished zirconium oxychloride.

Chemical Properties

Tetragonal prisms or needles. Deliquescent in moist air, evolves HCl and becomes dull in dry air. Soluble in H3O (slight hydrolysis) and alcohol. Lower hydrates are formed by heating a stream of HCl. It Liberates HCl on heating in air, and the solubility in water is gradually lost; it reverts to the oxide on calcination. Precipitation of an alcoholic solution with ether or acetone yields dizirconyl chloride Zr aO3Cl a -5HaO, which is sparingly soluble in water. The same compound deposits when a dilute aqueous solution of zirconyl chloride is allowed to stand for a month.

Chemical Properties

solid

Uses

Zirconium dichloride oxide is utilized as a precursor to prepare other zirconium compounds. It is employed in acid dyes, pigment toners and antiperspirants. It finds application as a rubber additive and a fiber treatment agent. It is also used in paint drying, refractories, ceramics and glaze.

Production Methods

Since zircon ZrSiO4, a mineral found in nature, is more difficult to work with, it is better to start from zirconia ZrO2 (baddeleyite), which is calcined, finely ground (the coarser particles are screened off with silk gauze) and converted to the sulfate by evaporation or treatment for several days with an excess of the warm cone. H2SO4. The solid residue, which consists of Zr(SO4)2 and unreacted ZrO2, is taken up in water (the solid is added in small portions to prevent solution heating). The sulfate dissolves slowly, and its solution may be aided by acidifying the water with some hydrochloric acid. The resultant milky suspension, which contains solid undissolved ZrO2 and SiO2 (or ZrSiO4), is allowed to stand for several hours and filtered. The weakly acidic sulfuric acid solution is precipitated with ammonia, and the hydroxide is filtered off. If the precipitate still exhibits a high Si content, it is dissolved in cone and hydrochloric acid and the solution is evaporated to dryness; this procedure is repeated several times. SiO2 and some basic zirconium chloride become the insoluble residue when redissolved in water. If no Si is evident in the hydroxide, the fresh gel is dissolved in cold hydrochloric acid, and the oxychloride is allowed to crystallize by adding cone, hydrochloric acid, or saturating it with HCl. The crystals are filtered and washed with 8N HCl.

General Description

This product is used as a potential green catalyst.

Purification Methods

Recrystallise the chloride several times from water [Ferragina et al. J Chem Soc, Dalton Trans 265 1986]. Recrystallisation from 8M HCl gives the octahydrate as white needles on concentrating. It is also formed by hydrolysing ZrCl4 with water. After one recrystallisation from H2O, 99+% grade zirconyl chloride had Ag, Al, As, Cd, Cu, Hf, Mg, Na, Sc and V at 20, 1.8, 0.6, 0.6, 0.4, 8.4, 0.4, 2.4, 80 and 3 ppm, respectively. (See above.) METAL-ORGANIC COMPOUNDS This section contains metal-organic compounds as well as ammonium and metal salts of organic acids. (For Introduction see p 445.)

Zirconyl chloride octahydrate Preparation Products And Raw materials

Raw materials

ZIRCONIUM SILICATE Zirconium hydroxide Hydrochloric acid Sodium hydroxide Sulfuric acid

Preparation Products

Zirconium sulfate tetrahydrate Zirconium dioxide Zirconium acetate Zirconium 2-ethylhexanoate Zirconium dicarbonate Zirconium oxychloride Zirconium naphthenate
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Zirconyl chloride octahydrate Suppliers

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View Lastest Price from Zirconyl chloride octahydrate manufacturers

Hebei Zhuanglai Chemical Trading Co.,Ltd
Product
Zirconium Oxychloride Octahydrate 13520-92-8
Price
US $99.00-35.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
20ton
Release date
2024-05-17
Hebei Chuanghai Biotechnology Co,.LTD
Product
Zirconyl chloride octahydrate 13520-92-8
Price
US $1.60/KG
Min. Order
1KG
Purity
99%
Supply Ability
5000kg
Release date
2024-08-08
Henan Fengda Chemical Co., Ltd
Product
Zirconyl chloride octahydrate 13520-92-8
Price
US $8.00-1.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
g-kg-tons, free sample is available
Release date
2024-04-03

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