15-Crown-5

ChemicalBook > CAS DataBase List > 15-Crown-5

use Introduction

Product Name: 15-Crown-5
CAS No.: 33100-27-5
Chemical Name: 15-Crown-5
Synonyms: 1,4,7,10,13-PENTAOXACYCLOPENTADECANE;15-CROWN 5-ETHER;15-CROWN-5;15-Crown-6;Crownethers;crown ether;15-CROWN-5,99%;15-Crown-5 98%;JACS-33100-27-5;LEAD IONOPHORE V
CBNumber: CB9707287
Molecular Formula: C10H20O5
Formula Weight: 220.26
MOL File: 33100-27-5.mol

Less

15-Crown-5 Property

Melting point:: -20°C(lit.)
Boiling point:: 93-96 °C/0.05 mmHg (lit.)
Density: 1.113 g/mL at 20 °C (lit.)
vapor pressure: 0.5-0.82Pa at 20-25℃
refractive index: n20/D 1.465(lit.)
Flash point:: >230 °F
storage temp.: room temp
solubility: Miscible with organic solvents.
form: Liquid
color: Clear colorless to light yellow
Specific Gravity: 1.109
Water Solubility: MISCIBLE
Sensitive: Hygroscopic
BRN: 1618144
Stability:: Stable. Incompatible with oxidizing agents, strong acids. Avoid exposure to water or moist air.
LogP: -0.9 at 20℃ and pH7.7
Surface tension: 68.5mN/m at 1g/L and 20℃
CAS DataBase Reference: 33100-27-5(CAS DataBase Reference)
NIST Chemistry Reference: 15-Crown-5(33100-27-5)
EPA Substance Registry System: 1,4,7,10,13-Pentaoxacyclopentadecane (33100-27-5)

Less

Safety

Hazard Codes: Xn,Xi
Risk Statements: 22-36/38-36-20/22-36/37/38-20/21/22
Safety Statements: 26-39-36
RIDADR: 2810
WGK Germany: 3
RTECS: SB0200000
F: 10-21
Hazard Note: Irritant
TSCA: Yes
HazardClass: 6.1(b)
PackingGroup: III
HS Code: 29329995
Toxicity: LD50 orl-rat: 1410 mg/kg DCTODJ 1,339,78

Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word: Warning
Hazard statements: H302Harmful if swallowed

Less

N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 188832
Product name: 15-Crown-5
Purity: 98%
Packaging: 1g
Price: $23.5
Updated: 2024/03/01

Sigma-Aldrich

Product number: 188832
Product name: 15-Crown-5
Purity: 98%
Packaging: 5g
Price: $64
Updated: 2024/03/01

TCI Chemical

Product number: C0859
Product name: 15-Crown 5-Ether
Purity: >97.0%(GC)
Packaging: 5mL
Price: $55
Updated: 2024/03/01

TCI Chemical

Product number: C0859
Product name: 15-Crown 5-Ether
Purity: >97.0%(GC)
Packaging: 25mL
Price: $271
Updated: 2024/03/01

Alfa Aesar

Product number: A12265
Product name: 15-Crown-5, 98%
Packaging: 1g
Price: $19.65
Updated: 2024/03/01

Less

15-Crown-5 Chemical Properties,Usage,Production

use

15-crown-5 has also been used to isolate salts of oxonium ions. For example, from a solution of tetrachloroauric acid, the oxonium ion [H7O3]+ has been isolated as the salt [(H7O3)(15-crown-5)2][AuCl4].

Introduction

The single nitrogen-containing derivative of 15-crown-5 is called aza-15-crown-5; the prefix “mono” is unnecessary. When two or more nitrogen atoms are present, the standard prefixes di-, tri-, etc. are applied. The term “monoazacrowns” is used here to designate the class of macrocycles containing a single nitrogen in combination with oxygen atoms as the macrocyclic donor array.

Chemical Properties

colourless liquid

Uses

15-Crown-5 is used as an efficient phase transfer catalyst and as a complexing agent. It is used to isolate oxonium ion (H7O3)+ salts especially from a solution of tetrchloroauric acid. It catalyzes the O-alkylation of the sodium salts of carboxylic acids in the penicillin and cephalosporin series, thereby facilitating esterification reaction without usage of acid. It is also used to facilitate the Williamson synthesis of ethers with hindered alcohols and sodium hydride. It is used with lithium aluminum hydride, for performing reduction reactions in hydrocarbon solvents. Further, it is involved in the Horner-Wadsworth-Emmons reaction to prepare stilbenes from aldehydes.

Definition

ChEBI: A saturated organic heteromonocyclic parent that is cyclopentadecane in which the carbon atoms at positions 1, 4, 7, 10 and 13 have been replaced by oxygen atoms to give a crown ether.

General Description

15-Crown-5 is a crown ether generally used as a ligand in coordination chemistry because of its strong chelating property with certain alkali cations to form complexes. Some derivatives of 15-crown-5 are used as sensors and probes in different physical-chemical processes, phase-transfer reactions, and selective capture of ions for separation and transport.

Safety Profile

Moderately toxic by ingestion, skin contact, and intraperitoneal routes. A skin and eye . When heated to decomposition it emits acrid smoke and irritating fumes

Purification Methods

Dry it over 3A molecular sieves and distil it in a high vacuum. [Beilstein 19/12 V 252.]

15-Crown-5 Preparation Products And Raw materials

Raw materials

Preparation Products

METHYL 3-((PIPERIDIN-4-YL)METHYL)BENZOATE 4-((1-(TERT-BUTOXYCARBONYL)PIPERIDIN-4-YL)METHYL)BENZOIC ACID METHYL 4-((PIPERIDIN-4-YL)METHYL)BENZOATE 2-((1-(TERT-BUTOXYCARBONYL)PIPERIDIN-4-YL)METHYL)BENZOIC ACID 18-Crown-6 3-((1-(TERT-BUTOXYCARBONYL)PIPERIDIN-4-YL)METHYL)BENZOIC ACID 1-Triacontanol Chlorfluazuron METHYL 2-((PIPERIDIN-4-YL)METHYL)BENZOATE 4-Fluoroaniline

Less

15-Crown-5 Suppliers

Americas 1 Belgium 2 Canada 1 China 348 Europe 4 France 1 Germany 9 India 34 Japan 7 Russia 1 Slovakia 1 South Korea 1 Switzerland 3 Ukraine 1 United Kingdom 19 United States 45 Global 478

Hangzhou Molot Chemical Technology Co., Ltd.

Tel: 0571-56906266 17706505167
Email: sales@morotchem.com
Country: China
ProdList: 500
Advantage: 58

Wuhan Rongcan Biotechnology Co., Ltd

Tel: 18327024450
Fax: 183-27024450
Email: 2130026275@qq.com
Country: China
ProdList: 4590
Advantage: 58

Guangdong wengjiang Chemical Reagent Co., Ltd.

Tel: 0751-2886750 13927877953
Fax: 0751-2886750
Email: 3005811397@qq.com
Country: China
ProdList: 13374
Advantage: 58

Jiangsu laurel Pharma Co., Ltd

Tel: 0517-83966898 15861782979
Email: 32860091@qq.com
Country: China
ProdList: 294
Advantage: 58

Shandong Dexin Fine Chemical Co. LTD

Tel: 18353358123 18353358123
Email: 839877395@qq.com
Country: China
ProdList: 150
Advantage: 58

Guangzhou Yaoguang Technology Co., Ltd.

Tel: 13020159086
Email: yangjue@ygfuture.com
Country: China
ProdList: 482
Advantage: 58

Yangzhou Princechem Co.,Ltd

Tel: 18921928333
Email: david@princechem.com
Country: China
ProdList: 335
Advantage: 58

J & K SCIENTIFIC LTD.

Tel: 010-82848833 400-666-7788
Fax: 86-10-82849933
Email: jkinfo@jkchemical.com
Country: China
ProdList: 96815
Advantage: 76

Meryer (Shanghai) Chemical Technology Co., Ltd.

Tel: 4006608290; 18621169109
Fax: 86-21-61259102
Email: market03@meryer.com
Country: China
ProdList: 40241
Advantage: 62

3B Pharmachem (Wuhan) International Co.,Ltd.

Tel: 821-50328103-801 18930552037
Fax: 86-21-50328109
Email: 3bsc@sina.com
Country: China
ProdList: 15848
Advantage: 69

future industrial shanghai co., ltd

Tel: 400-0066400 13621662912
Fax: 021-55660885
Email: sales@jonln.com
Country: China
ProdList: 1998
Advantage: 65

Alfa Aesar

Tel: 400-6106006
Fax: 021-67582001/03/05
Email: saleschina@alfa-asia.com
Country: China
ProdList: 30132
Advantage: 84

TAIYUAN RHF CO.,LTD.

Tel: +86 351 7031519
Fax: +86 351 7031519
Email: sales@RHFChem.com
Country: China
ProdList: 2341
Advantage: 56

TCI (Shanghai) Development Co., Ltd.

Tel: 021-67121386
Fax: 021-67121385
Email: Sales-CN@TCIchemicals.com
Country: China
ProdList: 24539
Advantage: 81

Suzhou Chireach Biomedical Technology Co., Ltd.

Tel: 0512-65856968
Fax: 0512-65647218
Email: sales@chireach.com
Country: China
ProdList: 60
Advantage: 70

BeiJing Hwrk Chemicals Limted

Tel: 0757-86329057 18501085097
Fax: 010-89508210
Email: sales3.gd@hwrkchemical.com
Country: China
ProdList: 7583
Advantage: 55

Beijing Ouhe Technology Co., Ltd

Tel: 010-82967028 13552068683
Fax: +86-10-82967029
Email: 2355560935@qq.com
Country: China
ProdList: 12426
Advantage: 60

JinYan Chemicals(ShangHai) Co.,Ltd.

Tel: 13817811078
Fax: 86-021-50426522,50426273
Email: sales@jingyan-chemical.com
Country: China
ProdList: 9984
Advantage: 60

Jia Xing Isenchem Co.,Ltd

Tel: 0573-85285100 18627885956
Fax: 0573-85285100
Email: isenchem@163.com
Country: China
ProdList: 9551
Advantage: 66

Accela ChemBio Co.,Ltd.

Tel: 021-50795510 4000665055
Fax: 021-50795055
Email: sales@accelachem.com
Country: China
ProdList: 11660
Advantage: 64

Nanjing Chemlin Chemical Co., Ltd

Tel: 025-83697070
Fax: +86-25-83453306
Email: info@chemlin.com.cn
Country: China
ProdList: 17988
Advantage: 64

Shanghai Hanhong Scientific Co.,Ltd.

Tel: 021-54306202 13764082696;
Email: info@hanhongsci.com
Country: China
ProdList: 42982
Advantage: 64

Beijing Isomersyn Technology CO;LTD

Tel: 010-82954736 13391601435
Email: sales@isomersyn.com
Country: China
ProdList: 3296
Advantage: 57

Shandong Xiya Chemical Co., Ltd

Tel: 13355009207 13355009207
Fax: 0539-6365991
Email: 3007715519@qq.com
Country: China
ProdList: 18739
Advantage: 57

Syntechem Co.,Ltd

Tel
Fax: E-Mail Inquiry
Email: info@syntechem.com
Country: China
ProdList: 12990
Advantage: 57

Tangshan Moneide Trading Co., Ltd.

Tel: 0315-8309571 15633399667
Fax: +86-315-7726572
Email: sales@moneidechem.com
Country: China
ProdList: 704
Advantage: 57

BEST-REAGENT

Tel: 400-1166-196 18981987031
Fax: 028-84555506 800101999
Email: cdhxsj@163.com
Country: China
ProdList: 11726
Advantage: 57

Tianjin heowns Biochemical Technology Co., Ltd.

Tel: 400 638 7771
Email: sales@heowns.com
Country: China
ProdList: 14443
Advantage: 57

Sinopharm Chemical Reagent Co,Ltd.

Tel: 86-21-63210123
Fax: 86-21-63290778 86-21-63218885
Email: sj_scrc@sinopharm.com
Country: China
ProdList: 9823
Advantage: 79

Shanghai Sunway Pharmaceutical Technology Co., Ltd

Tel: +8618575662672 18575662672
Fax: 021 51613951
Email: mzeng@3wpharm.com
Country: China
ProdList: 10053
Advantage: 57

Hunan Hui Bai Shi Biotechnology Co., Ltd.

Tel: 0731-85526065 13308475853
Email: ivy@hnhbsj.com
Country: China
ProdList: 4550
Advantage: 62

Nanjing Vital Chemical Co., Ltd.

Tel: Please Send Email 18652950785
Fax: 025-87193546
Email: chemweiao@163.com
Country: China
ProdList: 4388
Advantage: 65

Chengdu Ai Keda Chemical Technology Co., Ltd.

Tel: 4008-755-333 18080918076
Fax: 028-86757656
Email: 800078821@qq.com
Country: China
ProdList: 9725
Advantage: 55

Shanghai civi chemical technology co.,Ltd

Tel: 86-21-34053660
Fax: 86-21-34053661
Email: sale@labgogo.com
Country: China
ProdList: 9872
Advantage: 52

Suzhou BEC Biological Technology Co., Ltd

Tel: +86-512-68095917 13862064516
Fax: +86-512-68417933
Email: sales@bek.com.cn
Country: China
ProdList: 145
Advantage: 59

Thermo Fisher Scientific

Tel: 800-810-5118
Fax: +86-10-84193589
Email: cnchemical@thermofisher.com
Country: China
ProdList: 17779
Advantage: 75

Beijing HuaMeiHuLiBiological Chemical

Tel: 010-56205725
Fax: 010-65763397
Email: waley188@sohu.com
Country: China
ProdList: 12338
Advantage: 58

Beijing innoChem Science & Technology Co.,Ltd.

Tel: 400-810-7969 010-59572699
Fax: 010-59572688
Email: ningzi.li@inno-chem.com.cn
Country: China
ProdList: 6139
Advantage: 55

Jiangsu Aikon Biopharmaceutical R&D co.,Ltd.

Tel: 025-66099280 17798518460
Fax: (1)02557626880
Email: cfzhang@aikonchem.com
Country: China
ProdList: 19918
Advantage: 55

SuZhou ShiYa Biopharmaceuticals, Inc.

Tel: 86(512)5235 8471 17715136450
Fax: 86(512)5235 6881
Email: sales@shiyabiopharm.com
Country: China
ProdList: 4171
Advantage: 58

9ding chemical ( Shanghai) Limited

Tel: 4009209199
Fax: 86-021-52271987
Email: sales@9dingchem.com
Country: China
ProdList: 18216
Advantage: 56

Shanghai Aladdin Bio-Chem Technology Co.,LTD

Tel: 400-6206333 18521732826;
Fax: 021-50323701
Email: market@aladdin-e.com
Country: China
ProdList: 25015
Advantage: 65

The future of Shanghai Industrial Co., Ltd.

Tel: 021-61552785
Fax: 021-55660885
Email: sales@shshiji.com
Country: China
ProdList: 9552
Advantage: 55

Cantotech Chemicals, Ltd.

Tel: 86-0755-86635001
Fax: 86-0755-22642228
Email: cantotech@126.com
Country: China
ProdList: 4576
Advantage: 55

Chengdu AstaTech Trading Co., Ltd./AstaTech (Chengdu) Pharma. Co., Ltd.

Tel: +86-28-85122536 85324413
Fax: +86-28-85326443
Email: market@astatech.cn
Country: China
ProdList: 8033
Advantage: 55

Wuxi Zhangkun Biochemical Technology Co., Ltd.

Tel: +86 0510-85629785
Fax: +86 0510-85625359
Country: China
ProdList: 2331
Advantage: 58

Quzhou Juhua Friendship Co., Ltd

Tel: 0570-3066667
Fax: 0570-3063388
Country: China
ProdList: 3933
Advantage: 58

ShangHai Zexin Chemical Technology Co., Ltd.

Tel: 021-60136491 15901897992
Fax: 021-60136492
Country: China
ProdList: 455
Advantage: 55

Beijing Universal Century Technology Co., Ltd.

Tel: 400-8706899
Fax: 400-8706899
Email: hysj_bj.com
Country: China
ProdList: 3585
Advantage: 55

Shanghai JONLN Reagent Co., Ltd.

Tel: 400-0066400 13621662912
Fax: 021-55660885
Email: 422131432@qq.com
Country: China
ProdList: 9986
Advantage: 55

Less

View Lastest Price from 15-Crown-5 manufacturers

WUHAN FORTUNA CHEMICAL CO., LTD

Product: 15-Crown-5 33100-27-5
Price: US $0.00/KG
Min. Order: 1KG
Purity: 98%min
Supply Ability: 30tons/month
Release date: 2023-02-23

Hebei Mojin Biotechnology Co., Ltd

Product: 15-Crown-5 33100-27-5
Price: US $0.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 1000tons
Release date: 2023-08-16

Wuhan Silworld Chemical Co.,Ltd

Product: 15-crown-5 33100-27-5
Price: US $0.00/KG
Min. Order: 1KG
Purity: 97%
Supply Ability: 100000
Release date: 2023-04-27

33100-27-5, 15-Crown-5Related Search:

12-Crown-4 CYCLOHEXANO-15-CROWN-5 4-T-BUTYLCYCLOHEXANO-15-CROWN-5,4-TERT-BUTYLCYCLOHEXANO-15-CROWN-5 Hydroxy-15-crown-5,2-(HYDROXYMETHYL)-15-CROWN 5-ETHER,2-HYDROXYMETHYL-15-CROWN-5 4'-FORMYLBENZO-15-CROWN-5,4'-FORMYLBENZO-15-CROWN 5-ETHER 4'-BROMOBENZO-15-CROWN-5,4'-BROMOBENZO-15-CROWN 5-ETHER,4-BROMOBENZO-15-CROWN-5 4'-NITROBENZO-15-CROWN-5,4-NITROBENZO-15-CROWN-5,4'-NITROBENZO-15-CROWN 5-ETHER DIBENZO-15-CROWN-5 4'-CARBOXYBENZO-15-CROWN-5,4-CARBOXYBENZO-15-CROWN-5,4'-CARBOXYBENZO-15-CROWN 5-ETHER 4-AMINOBENZO-15-CROWN-5 HYDROCHLORIDE,4'-AMINOBENZO-15-CROWN-5 HYDROCHLORIDE 4'-AMINOBENZO-15-CROWN 5-ETHER,4'-AMINOBENZO-15-CROWN-5 1-AZA-15-CROWN-5,1-AZA-15-CROWN 5-ETHER 4-TERT-BUTYLBENZO-15-CROWN-5,4-T-BUTYLBENZO-15-CROWN-5,tert-Butylbezno-15-crown-5 Benzo-15-crown-5 4,10-DIAZA-15-CROWN 5-ETHER,1,7-DIAZA-15-CROWN-5 4'-(2,4-DINITRO-6-TRIFLUOROMETHYLPHENYL)-AMINOBENZO-15-CROWN-5,4'-(2'',4''-DINITRO-6''-TRIFLUOROMETHYLPHENYL)-AMINOBENZO-15-CROWN-5 Dibenzodiaza-15-crown-4 2,3-NAPHTHO-15-CROWN-5

1,4,10,13-Pentaoxacyclopentadecane

15-Crown-5,1,4,7,10,13-Pentaoxa-cyclo-pentadecane

Crownethers

Ethyleneoxidecyclicpentamer

15-Crown-5 Vetec(TM) reagent grade, 98%

1,4,7,1,13-Pentaoxacyclopentadecane

15-Crown-5 solution

LABOTEST-BB LT00440921

LEAD IONOPHORE V

CROWN ETHER/15-CROWN-5

15-CROWN-5

15-CROWN 5-ETHER

15-Crown-5, 98% 5GR

15-Crown-5, 98+%

1,4,7,10,13-PENTAOXACYCLOPENTADECANE

Crownpaleyellowliq

15-CROWN-5,99%

CROWN ETHER/15-CROWN-5 FOR SYNTHESIS

1,4,7,10,13-Pentaoxacyclopentadecane 98%

15-crown ether-5

15-Crown-5-Ether SynonyMs 1,4,7,10,13-Pentaoxacyclopentadecane

15 - crown ether

15-Crown-5 98%

JACS-33100-27-5

15-Crown 5-Ether &gt

15-Crown-5, 98%, reagent grade

Hot selling high quality 98% Dimethyl maleate liquid cas 624-48-6 with reasonable price

Octadecylamide dimethylpropyl ammonium chloride

15-Crown-6

crown ether

33100-27-5

33100-21-5

C10H20O5

Macrocycles for Host-Guest Chemistry

Ion Sensor Materials

Ionophores Potentiometric for ISE

Synthetic Reagents

Chelation/Complexation Compounds

Analytical Chromatography Product Catalog

Pyridines

catalyst

crown ether

Crown Ethers

Functional Materials

Macrocycles for Host-Guest Chemistry

bc0001

33100-27-5