(3-(BROMOMETHYL)PHENYL)METHANOL
Uses- Product Name
- (3-(BROMOMETHYL)PHENYL)METHANOL
- CAS No.
- 82072-22-8
- Chemical Name
- (3-(BROMOMETHYL)PHENYL)METHANOL
- Synonyms
- 3-BROMO METHYLBENZYL ALCOHOL;3-(Bromomethyl)benzenemethanol;(3-(BROMOMETHYL)PHENYL)METHANOL
- CBNumber
- CB9708648
- Molecular Formula
- C8H9BrO
- Formula Weight
- 201.06
- MOL File
- 82072-22-8.mol
(3-(BROMOMETHYL)PHENYL)METHANOL Property
- Boiling point:
- 286.0±20.0 °C(Predicted)
- Density
- 1.514±0.06 g/cm3(Predicted)
- storage temp.
- under inert gas (nitrogen or Argon) at 2-8°C
- pka
- 14.23±0.10(Predicted)
- Appearance
- Light yellow to yellow Powder
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H302Harmful if swallowed
H314Causes severe skin burns and eye damage
H317May cause an allergic skin reaction
H400Very toxic to aquatic life
- Precautionary statements
-
P260Do not breathe dust/fume/gas/mist/vapours/spray.
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P270Do not eat, drink or smoke when using this product.
P272Contaminated work clothing should not be allowed out of the workplace.
P273Avoid release to the environment.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P333+P313IF SKIN irritation or rash occurs: Get medical advice/attention.
P363Wash contaminated clothing before reuse.
P391Collect spillage. Hazardous to the aquatic environment
P405Store locked up.
P501Dispose of contents/container to..…
N-Bromosuccinimide Price
- Product number
- B697108
- Product name
- 3-Bromomethylbenzylalcohol
- Packaging
- 1g
- Price
- $295
- Updated
- 2021/12/16
- Product number
- FB140662
- Product name
- (3-(Bromomethyl)phenyl)methanol
- Packaging
- 50mg
- Price
- $60
- Updated
- 2021/12/16
- Product number
- FB140662
- Product name
- (3-(Bromomethyl)phenyl)methanol
- Packaging
- 100mg
- Price
- $100
- Updated
- 2021/12/16
- Product number
- FB140662
- Product name
- (3-(Bromomethyl)phenyl)methanol
- Packaging
- 250mg
- Price
- $175
- Updated
- 2021/12/16
- Product number
- W8601
- Product name
- (3-(Bromomethyl)phenyl)methanol
- Packaging
- 1g
- Price
- $184
- Updated
- 2021/12/16
(3-(BROMOMETHYL)PHENYL)METHANOL Chemical Properties,Usage,Production
Uses
3-Bromomethylbenzyl alcohol can be used as a pharmaceutical synthesis intermediate.
Synthesis
1129-28-8
82072-22-8
Step A: To a stirred solution of methyl 3-bromomethylbenzoate (5 g, 21.8 mmol) in toluene (50 mL) was slowly added DABAL-H (43.6 mL, 43.6 mmol) under ice bath conditions. The reaction temperature was maintained at 0 °C with continuous stirring for 2 hours. Upon completion of the reaction, the reaction was quenched with 1N HCl solution and subsequently separated by extraction with ethyl acetate (EtOAc) and water. The organic layer was collected, dried with anhydrous sodium sulfate (Na2SO4) and concentrated under reduced pressure to give 3-bromomethylbenzyl alcohol (4.0 g, 19.9 mmol, 91% yield) as a colorless oil.
References
[1] Organometallics, 2015, vol. 34, # 9, p. 1627 - 1634
[2] Patent: WO2015/142903, 2015, A2. Location in patent: Page/Page column 94
[3] Patent: WO2015/140133, 2015, A1. Location in patent: Page/Page column 106
[4] Patent: WO2017/68064, 2017, A1. Location in patent: Page/Page column 191; 192
[5] Patent: EP2816023, 2014, A1. Location in patent: Paragraph 0488
(3-(BROMOMETHYL)PHENYL)METHANOL Preparation Products And Raw materials
Raw materials
Preparation Products
(3-(BROMOMETHYL)PHENYL)METHANOL Suppliers
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- enquiries@fluorochem.co.uk
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View Lastest Price from (3-(BROMOMETHYL)PHENYL)METHANOL manufacturers
- Product
- 3-Bromomethylbenzyl alcohol 82072-22-8
- Price
- US $0.00/KG
- Min. Order
- 0.0001KG
- Purity
- 98%min
- Supply Ability
- 500kgs/month
- Release date
- 2022-05-11