ChemicalBook > CAS DataBase List > 2-BOC-HEXAHYDRO-PYRROLO[3,4-C]PYRROLE

2-BOC-HEXAHYDRO-PYRROLO[3,4-C]PYRROLE

Product Name
2-BOC-HEXAHYDRO-PYRROLO[3,4-C]PYRROLE
CAS No.
141449-85-6
Chemical Name
2-BOC-HEXAHYDRO-PYRROLO[3,4-C]PYRROLE
Synonyms
2-Boc-hexahydro-pyrrpol[3...;tert-butyl hexahydropyrrolo[3;4-c]pyrrole-2(1H)-carboxylate;Pyrrolo[3,4-c]Pyrrole-2(1H)-Ca;N-BOC-3,7-Diazabicyclo[3,3,0]octane;2-Boc-Hexahydro-Pyrrol[3,4-c]Pyrrole;2-Boc-octahydropyrrolo[3,4-c]pyrrole;2-BOC-HEXAHYDRO-PYRROLO[3,4-C]PYRROLE;2-Boc-hexahydro-pyrrpol[3,4-c]pyrrole;Octahydropyrrolo[3,4-c]pyrrole, N2-BOC protected
CBNumber
CB9711536
Molecular Formula
C11H20N2O2
Formula Weight
212.29
MOL File
141449-85-6.mol
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2-BOC-HEXAHYDRO-PYRROLO[3,4-C]PYRROLE Property

Boiling point:
295.4±33.0 °C(Predicted)
Density 
1.076±0.06 g/cm3(Predicted)
storage temp. 
under inert gas (nitrogen or Argon) at 2–8 °C
pka
10.72±0.20(Predicted)
form 
solid
color 
White to off-white
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Safety

HS Code 
2933998090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H227Combustible liquid

H314Causes severe skin burns and eye damage

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P330+P331IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P363Wash contaminated clothing before reuse.

P370+P378In case of fire: Use … for extinction.

P403+P235Store in a well-ventilated place. Keep cool.

P405Store locked up.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

TRC
Product number
B695355
Product name
tert-ButylHexahydropyrrolo[3,4-c]pyrrole-2(1H)-carboxylate
Packaging
500mg
Price
$175
Updated
2021/12/16
Usbiological
Product number
265699
Product name
2-Boc-hexahydropyrrolo[3,4-c]pyrrole
Packaging
50mg
Price
$353
Updated
2021/12/16
Biosynth Carbosynth
Product number
FB50885
Product name
2-Boc-hexahydropyrrolo[3,4-c]pyrrole
Packaging
250mg
Price
$55
Updated
2021/12/16
SynQuest Laboratories
Product number
4H56-1-581
Product name
Octahydropyrrolo[3,4-c]pyrrole, N2-Boc protected
Packaging
1g
Price
$225
Updated
2021/12/16
Biosynth Carbosynth
Product number
FB50885
Product name
2-Boc-hexahydropyrrolo[3,4-c]pyrrole
Packaging
2g
Price
$260
Updated
2021/12/16
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2-BOC-HEXAHYDRO-PYRROLO[3,4-C]PYRROLE Chemical Properties,Usage,Production

Uses

2-Boc-Hexahydro-pyrrolo[3,4-C]pyrrole is an organic synthetic intermediate compound used in the preparation of anticancer agent compounds and sigma-2 ligands.

Synthesis

186202-73-3

141449-85-6

Example 6C: Synthesis of tert-butyl hexahydropyrrolo[3,4-c]pyrrole-2(1H)-carboxylate To a solution of tert-butyl 5-benzylhexahydropyrrolo[3,4-c]pyrrole-2(1H)-carboxylate (107.8 g, 0.356 mol), the product of Example 6B, in methanol (250 mL) was added wet 20% Pd(OH)2/C catalyst (10.8 g). The reaction mixture was hydrogenated for 2.5 hours at 50°C and 60 psi under a hydrogen atmosphere. Upon completion of the reaction, the catalyst was removed by filtration and the filtrate was concentrated to afford the title compound tert-butyl hexahydropyrrolo[3,4-c]pyrrole-2(1H)-carboxylate (74 g, 0.35 mol, 98% yield). Mass spectrum (DCI/NH3) m/z: 213 ([M+H]+).

References

[1] Patent: US2005/65178, 2005, A1. Location in patent: Page/Page column 22
[2] Patent: US2005/101602, 2005, A1. Location in patent: Page/Page column 28
[3] Patent: WO2009/111550, 2009, A1. Location in patent: Page/Page column 37
[4] Patent: WO2013/71697, 2013, A1. Location in patent: Paragraph 00250
[5] Patent: US2014/228361, 2014, A1. Location in patent: Paragraph 0371-0372

2-BOC-HEXAHYDRO-PYRROLO[3,4-C]PYRROLE Preparation Products And Raw materials

Raw materials

Preparation Products

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2-BOC-HEXAHYDRO-PYRROLO[3,4-C]PYRROLE Suppliers

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View Lastest Price from 2-BOC-HEXAHYDRO-PYRROLO[3,4-C]PYRROLE manufacturers

Honest Joy Holdings Limited
Product
2-Boc-hexahydro-pyrrolo[3,4-c]pyrrole 141449-85-6
Price
US $0.00/KG
Min. Order
1KG
Purity
98.0%
Supply Ability
100 tons
Release date
2022-01-26
Career Henan Chemical Co
Product
2-BOC-HEXAHYDRO-PYRROLO[3,4-C]PYRROLE 141449-85-6
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
100KG
Release date
2020-01-02

141449-85-6, 2-BOC-HEXAHYDRO-PYRROLO[3,4-C]PYRROLERelated Search:

HEXAHYDRO-PYRROLO[3,4-B]PYRROLE-1-CARBOXYLIC ACID TERT-BUTYL ESTER HEXAHYDRO-PYRROLO[3,2-B]PYRROLE-1-CARBOXYLIC ACID TERT-BUTYL ESTER Pyrrolo[3,4-b]pyrrole-5(1H)-carboxylic acid, hexahydro-, ethyl ester 2-Boc-6-oxo-2-azaspiro[3.4]octane 2-Boc-5-oxo-octahydro-isoindole hexahydrocyclopenta[c]pyrrol-5(1H)-one N-BOC-HEXAHYDRO-5-OXOCYCLOPENTA[C]PYRROLE (3aR,6aS)-benzyl 5-oxohexahydrocyclopenta[c]pyrrole-2(1H)-carboxylate cis-5-Oxohexahydrocyclopenta[c]pyrrole-2(1H)-carboxylic acid tert-butyl ester (Meso-3aR,5r,6aS)-tert-butyl 5-hydroxyhexahydrocyclopenta[c]pyrrole-2(1H)-carboxylate 2-methyl-octahydrocyclopenta[c]pyrrol-5-one 2-methyl-octahydrocyclopenta[c]pyrrol-5-one (cis)-5-Boc-Hexahydro-pyrrolo[3,4-b]pyrrole,5-Boc-Hexahydro-pyrrolo[3,4-b]pyrrole CIS-5-BENZYL-2-BOC-HEXAHYDROPYRROLO[3,4-C]PYRROLE cis-2-Boc-hexahydropyrrolo[3,4-c]pyrrole 2-BOC-HEXAHYDRO-PYRROLO[3,4-C]PYRROLE

  • HEXAHYDRO-PYRROLO[3,4-C]PYRROLE-2-CARBOXYLIC ACID TERT-BUTYL ESTER
  • 2-BOC-HEXAHYDRO-PYRROLO[3,4-C]PYRROLE
  • 2-BOC-HEXAHYDRO-PYRROLO[3,4-C]PYRROLE HYDROCHLORIDE
  • 2-Boc-hexahydro-pyrrpol[3,4-c]pyrrole
  • Pyrrolo[3,4-c]Pyrrole-2(1H)-Ca
  • 2-Boc-octahydropyrrolo[3,4-c]pyrrole
  • 4-c]pyrrole-2(1H)-carboxylate
  • tert-butyl hexahydropyrrolo[3
  • 2-Boc-hexahydro-pyrrpol[3...
  • tert-Butyl octahydropyrrolo[3,4-c]pyrrole-2-carboxylate
  • 2-Boc-Hexahydro-Pyrrol[3,4-c]Pyrrole
  • tert-butyl 2,3,3a,4,6,6a-hexahydro-1H-pyrrolo[3,4-c]pyrrole-5-carboxylate
  • Octahydropyrrolo[3,4-c]pyrrole, N2-BOC protected
  • N-BOC-3,7-Diazabicyclo[3,3,0]octane
  • Hexahydropyrrolo3,4-cpyrrol-2-carboxylic acid tert-butyl ester
  • tert-butyl hexahydropyrrolo[3,4-c]pyrrole-2(1H)-carboxylate 97%
  • 141449-85-6
  • Amines and Anilines
  • Heterocycles