Ammonium iron(III) sulfate

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Ammonium iron(III) sulfate

Synthesis Physical Properties Uses Preparation

Product Name: Ammonium iron(III) sulfate
CAS No.: 10138-04-2
Chemical Name: Ammonium iron(III) sulfate
Synonyms: FERRIC AMMONIUM SULFATE;FERRIC ALUM;IRON ALUM;AMMONIUM FERRIC SULPHATE;FERRIC AMMONIUM SULPHATE;0,1mol/l(0,1N)SV;AMMoniuM iron(III);Ammoniumeisen(III)-sulfat;ammonium ferric disulfate;ammoniumironbis(sulphate)
CBNumber: CB9724969
Molecular Formula: FeH5NO4S
Formula Weight: 170.95
MOL File: 10138-04-2.mol

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Ammonium iron(III) sulfate Property

Melting point:: 39–41℃ [ALD94]
Density: 1.710
solubility: very soluble in H2O; insoluble in ethanol
form: Liquid
color: Clear amber
Water Solubility: very soluble H2O; insoluble alcohol [MER06]
Stability:: Stable.
CAS DataBase Reference: 10138-04-2(CAS DataBase Reference)
EPA Substance Registry System: Monoammonium ferric sulfate (10138-04-2)

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Safety

Hazard Codes: Xi
Risk Statements: 36/38
Safety Statements: 26
RIDADR: UN 3264 8/PG 3

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H318Causes serious eye damage

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P310Immediately call a POISON CENTER or doctor/physician.

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N-Bromosuccinimide Price

BLDpharm

Product number: BD130300
Product name: Ammoniumiron(III)sulfate
Purity: 98+%
Packaging: 1kg
Price: $5
Updated: 2021/12/16

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Ammonium iron(III) sulfate Chemical Properties,Usage,Production

Synthesis

Dissolve industrial crystalline ferrous sulfate in water. Filtration, adding sulfuric acid to the filtrate, heating to 30-45 ° C, and then adding 25-30 mL of nitric acid for oxidation. The solution gradually turned from tan to light reddish brown. Use potassium ferricyanide solution to check whether the ferrous ions in the solution are completely oxidized. The solution was slowly heated until it was smoking and a thick slurry was formed, and the nitric acid and nitrogen oxides were removed. Add water to dissolve, re-evaporate until a crystalline film appears, add water and filtered hot solution of ammonium sulfate to this saturated solution, and add concentrated sulfuric acid. Cool to 0°C under stirring, and filter and crystallize to obtain pure ferric ammonium sulfate.

Physical Properties

The dodecahydrate is lilac to violet crystal (anhydrous compound is colorless); hydrated crystals lose all water molecules at 230°C; readily dissolves in water; insoluble in alcohol; aqueous solution is acidic.

Uses

Iron(III) ammonium sulfate is a mordant in dyeing and printing of fabrics and textiles. The compound also is an analytical reagent; and is used in medicine.

Preparation

Ferric ammonium sulfate is prepared by mixing an equimolar solution of ferric sulfate, Fe2(SO4)3, and ammonium sulfate, (NH4)2SO4. Hydrated crystals are obtained following evaporation and cooling of the solution.

Chemical Properties

pale violet crystals

Preparation

Ferric ammonium sulfate is prepared by mixing an equimolar solution offerric sulfate, Fe₂(SO₄)3, and ammonium sulfate, (NH₄)2SO4. Hydrated crystals are obtained following evaporation and cooling of the solution.

Flammability and Explosibility

Not classified

Purification Methods

Crystallise it from aqueous ethanol.

Ammonium iron(III) sulfate Preparation Products And Raw materials

Raw materials

Ferric sulfate Ammonium sulfate

Preparation Products

potassium ferricyanide Quinhydrone

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View Lastest Price from Ammonium iron(III) sulfate manufacturers

Hebei Yanxi Chemical Co., Ltd.

Product: Ammonium iron(III) sulfate 10138-04-2
Price: US $0.00/kg
Min. Order: 1kg
Purity: 0.99
Supply Ability: 20 tons
Release date: 2023-11-16

Hebei Weibang Biotechnology Co., Ltd

Product: Ammonium iron(III) sulfate 10138-04-2
Price: US $0.00-0.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 500000kg
Release date: 2024-10-25

Zhuozhou Wenxi import and Export Co., Ltd

Product: Ammonium iron(III) sulfate 10138-04-2
Price: US $15.00-10.00/KG
Min. Order: 1KG
Purity: 99%+ HPLC
Supply Ability: Monthly supply of 1 ton
Release date: 2021-06-27

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10138-04-2

FeH4NO8S2

Inorganics

A - FChemical Synthesis

IronVolumetric Solutions

Reference Material Potassium permanganate

By Reference Material

Catalysis and Inorganic Chemistry

Salt Solutions

Volumetric Solutions