ChemicalBook > CAS DataBase List > Chloro(triphenylphosphine)gold

Chloro(triphenylphosphine)gold

Product Name: Chloro(triphenylphosphine)gold
CAS No.: 14243-64-2
Chemical Name: Chloro(triphenylphosphine)gold
Synonyms: (Ph3P)AuCl;Au(PPh3)Cl;phosphine)g;oro(triphenyL;phosphine)goL;Triphenylphosphinechlorogold;Chlorotriphenylphosphino gold;chloro(triphenylphosphine)gold;Chlorotriphenylphosphinegold(Ⅰ);Chloro(triphenylphophine)gold(I)
CBNumber: CB9734179
Molecular Formula: C18H15AuClP
Formula Weight: 494.71
MOL File: 14243-64-2.mol

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Chloro(triphenylphosphine)gold Property

Melting point:: 248-249°C
storage temp.: Keep in dark place,Inert atmosphere,2-8°C
form: Crystalline Powder
color: White
Water Solubility: Soluble in methylene chloride, acetonitrile, benzene and acetone. Insoluble in water and ethanol.
InChI: InChI=1S/C18H15P.Au.ClH/c1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;/h1-15H;;1H/q;+1;/p-1
InChIKey: IFPWCRBNZXUWGC-UHFFFAOYSA-M
SMILES: P(C1C=CC=CC=1)(C1C=CC=CC=1)C1C=CC=CC=1.Cl[Au]
CAS DataBase Reference: 14243-64-2(CAS DataBase Reference)

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Safety

Hazard Codes: Xi
Risk Statements: 36/37/38-22
Safety Statements: 26-36/37/39-37/39
RIDADR: 3464
WGK Germany: 3
HS Code: 71159010

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 254037
Product name: Chloro(triphenylphosphine)gold(I)
Purity: ≥99.9% trace metals basis
Packaging: 500mg
Price: $192
Updated: 2025/07/31

Sigma-Aldrich

Product number: 254037
Product name: Chloro(triphenylphosphine)gold(I)
Purity: ≥99.9% trace metals basis
Packaging: 5g
Price: $663
Updated: 2025/07/31

TCI Chemical

Product number: T2994
Product name: (Triphenylphosphine)gold(I) Chloride
Purity: >95.0%(T)
Packaging: 200mg
Price: $61
Updated: 2025/07/31

TCI Chemical

Product number: T2994
Product name: (Triphenylphosphine)gold(I) Chloride
Purity: >95.0%(T)
Packaging: 1g
Price: $182
Updated: 2025/07/31

Strem Chemicals

Product number: 79-1000
Product name: Chlorotriphenylphosphinegold(I), 98+% (99.9+%-Au)
Packaging: 250mg
Price: $50
Updated: 2024/03/01

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Chloro(triphenylphosphine)gold Chemical Properties,Usage,Production

Chemical Properties

White crystalline powder

Uses

Chloro(triphenylphosphine)gold(I) is a common reagent in gold chemistry. It catalyzes certain rearrangement reactions in organic synthesis. It is also used to prepare 1-methylthyminato-N3-triphenylphosphinegold(I) by reacting with 1-methylthymine. It acts as a precursor for the synthesis of gold(I) and gold(III) organometallic compounds.

Uses

Catalyst employed in the cyclization of O-propargyl carbamates to alkylideneoxazolidinones via a 5-exo-digonal pathway at room temperature. Also catalyzes the cycloisomerization of enynes containing a cyclic olefin into highly-fused, polycyclic dienes at room temperature.

reaction suitability

core: gold
reagent type: catalyst

Chloro(triphenylphosphine)gold Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from Chloro(triphenylphosphine)gold manufacturers

Career Henan Chemical Co

Product: Chloro(triphenylphosphine)gold 14243-64-2
Price: US $1.00/KG
Min. Order: 1KG
Purity: 98%
Supply Ability: 1kg,5kg,100kg
Release date: 2019-08-08

14243-64-2, Chloro(triphenylphosphine)goldRelated Search:

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14243-64-2

C18H15PAuCl

C18H15AuClP

C6H53PAuCl

AuClPC6H53

Gold

Catalysis and Inorganic Chemistry

metal-phosphine complexes