ChemicalBook > CAS DataBase List > Benzophenone imine
Benzophenone imine
- Product Name
- Benzophenone imine
- CAS No.
- 1013-88-3
- Chemical Name
- Benzophenone imine
- Synonyms
- DIPHENYLMETHANIMINE;BENZOPHENONIMINE;BENZHYDRYLIDENEAMINE;Benzophone imine;Benzenemethanimine, α-phenyl-;90-97%;Benzhydrylimine;Diphenylketimine;Benzophononeamine;Benophenone imine
- CBNumber
- CB9734740
- Molecular Formula
- C13H11N
- Formula Weight
- 181.23
- MOL File
- 1013-88-3.mol
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Benzophenone imine Property
- Melting point:
- -30 °C
- Boiling point:
- 151-153 °C10 mm Hg(lit.)
- Density
- 1.08 g/mL at 25 °C(lit.)
- vapor pressure
- 0.082Pa at 20℃
- refractive index
- n20/D 1.618(lit.)
- Flash point:
- 145 °C
- storage temp.
- Inert atmosphere,Room Temperature
- solubility
- DMSO (Slightly), Ethyl Acetate (Slightly)
- form
- Liquid
- pka
- pK1:6.82 (25°C)
- color
- Clear colorless to light yellow-brownish
- Water Solubility
- 0.3 g/L (25 ºC)
- BRN
- 1100371
- InChIKey
- SXZIXHOMFPUIRK-UHFFFAOYSA-N
- CAS DataBase Reference
- 1013-88-3(CAS DataBase Reference)
- NIST Chemistry Reference
- Benzenemethanimine, «alpha»-phenyl-(1013-88-3)
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Safety
- Hazard Codes
- Xi,N,Xn
- Risk Statements
- 36/37/38-51/53-38-22
- Safety Statements
- 26-36-61-37
- RIDADR
- UN3082
- WGK Germany
- 3
- HS Code
- 29252900
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Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P271Use only outdoors or in a well-ventilated area.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
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N-Bromosuccinimide Price
Sigma-Aldrich
- Product number
- 293733
- Product name
- Benzophenone imine
- Purity
- 95%
- Packaging
- 5g
- Price
- $122
- Updated
- 2025/07/31
Sigma-Aldrich
- Product number
- 293733
- Product name
- Benzophenone imine
- Purity
- 95%
- Packaging
- 25g
- Price
- $253.12
- Updated
- 2025/07/31
TCI Chemical
- Product number
- B1912
- Product name
- Benzophenone Imine
- Purity
- >95.0%(GC)
- Packaging
- 5g
- Price
- $41
- Updated
- 2025/07/31
TCI Chemical
- Product number
- B1912
- Product name
- Benzophenone Imine
- Purity
- >95.0%(GC)
- Packaging
- 25g
- Price
- $118
- Updated
- 2025/07/31
TRC
- Product number
- B287290
- Product name
- Benzophenone Imine
- Packaging
- 50g
- Price
- $140
- Updated
- 2021/12/16
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Benzophenone imine Chemical Properties,Usage,Production
Chemical Properties
clear colorless to light yellow-brownish liquid
Uses
Useful in the preparation of nitrile ylide dimers.Benzophenone imine as ammonia surrogate. As intermediate material for synthesis of organic chemicals. Catalytic enantioselective alkylation of the benzophenone imine of glycine t-butyl ester using phosphazene (Schwesinger) bases and chiral quaternary ammonium salts yields either enantiomer of amino acid derivatives in excellent yield.
Uses
Benzophenone imine is useful in the preparation of nitrile ylide dimers.
Application
Benzophenone imine is a multifunctional reagent in organic synthesis, its core role being as an ammonia equivalent and a protecting group for primary amines. It reacts with primary amines to form stable Schiff bases, thereby protecting the functional groups of primary amines and preventing them from undergoing side reactions in subsequent reactions.
Synthesis Reference(s)
Synthetic Communications, 18, p. 1501, 1988 DOI: 10.1080/00397918808081307
Flammability and Explosibility
Not classified
Benzophenone imine Preparation Products And Raw materials
Raw materials
Phenylmagnesium bromide
Benzophenone oxime
Benzophenone
Diethyl ether
Ethyl acetate
Benzonitrile
Titanium tetrachloride
Ammonia
Preparation Products
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View Lastest Price from Benzophenone imine manufacturers
Shandong Vital Biotechnology Co., Ltd.
- Product
- Benzophenone imine 1013-88-3
- Price
- US $0.00-0.00/kg
- Min. Order
- 1kg
- Purity
- 98%
- Supply Ability
- 100tons
- Release date
- 2025-11-20
Hebei Chuanghai Biotechnology Co., Ltd
- Product
- Benzophenone imine 1013-88-3
- Price
- US $0.00-0.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 500000kg
- Release date
- 2024-11-01
Hebei Yanxi Chemical Co., Ltd.
- Product
- Benzophenone imine 1013-88-3
- Price
- US $30.00-10.00/kg
- Min. Order
- 1kg
- Purity
- 0.99
- Supply Ability
- 10 tons
- Release date
- 2023-11-21
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