ChemicalBook > CAS DataBase List > (R)-(+)-4-Isopropyl-2-oxazolidinone

(R)-(+)-4-Isopropyl-2-oxazolidinone

Product Name
(R)-(+)-4-Isopropyl-2-oxazolidinone
CAS No.
95530-58-8
Chemical Name
(R)-(+)-4-Isopropyl-2-oxazolidinone
Synonyms
(R)-4-isopropyloxazolidin-2-one;TB-2042;(R)-(+)-4-Isopropyl-;(R)-Isopropyloxazolidinone;4-isopropyl-2-oxazolidinone;R-4-Isopropyl-2-oxazolidone;-4-Isopropyloxazolidin-2-one;4-R-ISOPROPYL-OXAZOLIDIN-2-ONE;(R)-4-ISOPROPYL-2-OXAZOLIDINONE;(R)-(+)-4-Isopropyl-2-oxazolinone
CBNumber
CB9749445
Molecular Formula
C6H11NO2
Formula Weight
129.16
MOL File
95530-58-8.mol
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(R)-(+)-4-Isopropyl-2-oxazolidinone Property

Melting point:
70-73 °C
alpha 
-18 º (c=1, ethanol)
Boiling point:
239.22°C (rough estimate)
Density 
1.04 g/cm3
refractive index 
1.4300 (estimate)
storage temp. 
Sealed in dry,Room Temperature
solubility 
very faint turbidity in EtOH
pka
12.72±0.40(Predicted)
form 
Crystalline Powder
color 
White
optical activity
[α]20/D +17°, c = 6 in ethanol
Water Solubility 
Soluble
BRN 
5376658
InChI
InChI=1S/C6H11NO2/c1-4(2)5-3-9-6(8)7-5/h4-5H,3H2,1-2H3,(H,7,8)/t5-/m0/s1
InChIKey
YBUPWRYTXGAWJX-YFKPBYRVSA-N
SMILES
O1C[C@@H](C(C)C)NC1=O
CAS DataBase Reference
95530-58-8(CAS DataBase Reference)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
22-24/25-36-26
WGK Germany 
3
F 
3
HS Code 
29349990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H332Harmful if inhaled

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TCI Chemical
Product number
I0572
Product name
(R)-4-Isopropyl-2-oxazolidinone
Purity
>98.0%(GC)
Packaging
1g
Price
$50
Updated
2025/07/31
TCI Chemical
Product number
I0572
Product name
(R)-4-Isopropyl-2-oxazolidinone
Purity
>98.0%(GC)
Packaging
5g
Price
$150
Updated
2025/07/31
TCI Chemical
Product number
I0572
Product name
(R)-4-Isopropyl-2-oxazolidinone
Purity
>98.0%(GC)
Packaging
25g
Price
$598
Updated
2025/07/31
TRC
Product number
I872978
Product name
(R)-4-Isopropyl-2-oxazolidinone
Packaging
250mg
Price
$55
Updated
2021/12/16
Frontier Specialty Chemicals
Product number
JK471029
Product name
(R)-(+)-4-Isopropyl-2-oxazolidinone
Purity
99%
Packaging
1g
Price
$61
Updated
2021/12/16
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(R)-(+)-4-Isopropyl-2-oxazolidinone Chemical Properties,Usage,Production

Chemical Properties

white to light yellow crystal powde

Uses

(R)-4-Isopropyloxazolidin-2-one is a biochemical reagent that can be used as a biological material or organic compound for life science related research.

Synthesis

4276-09-9

124-38-9

95530-58-8

To a dry Schlenk tube containing DMSO-d6 (1 mL) and cesium carbonate (33 mg, 0.1 mmol) was added (S)-1a (0.1114 mL, 1 mmol). The reaction mixture was frozen in a liquid nitrogen bath (-196 °C), followed by evacuation to remove air and replacement with CO2 gas. After thawing to 25 °C, a balloon (1 L) containing CO2 was connected to the reaction tube. The reaction system was stirred at 150°C for 24 hours. Upon completion of the reaction, the crude product was analyzed by 1H NMR and the yield was calculated using the internal standard N,N-dimethylformamide as reference. Subsequently, DMSO-d6 was removed by distillation under reduced pressure conditions (6 mmHg, 50 °C).The residue was purified by silica gel column chromatography (eluent: hexane/ethyl acetate, 3:1) to afford the target product (S)-4-isopropyloxazolidin-2-one ((S)-2a) as a white solid in 80% isolated yield (103.3 mg, 0.80 mmol).

References

[1] Journal of Organic Chemistry, 2000, vol. 65, # 15, p. 4759 - 4761
[2] Tetrahedron Letters, 2013, vol. 54, # 35, p. 4717 - 4720

(R)-(+)-4-Isopropyl-2-oxazolidinone Preparation Products And Raw materials

Raw materials

Preparation Products

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(R)-(+)-4-Isopropyl-2-oxazolidinone Suppliers

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View Lastest Price from (R)-(+)-4-Isopropyl-2-oxazolidinone manufacturers

Henan Fengda Chemical Co., Ltd
Product
(R)-(+)-4-Isopropyl-2-oxazolidinone 95530-58-8
Price
US $200.00-1.00/KG
Min. Order
1KG
Purity
99%, 99.5% Sublimated
Supply Ability
g-kg-tons, free sample is available
Release date
2023-12-31
Career Henan Chemical Co
Product
(R)-(+)-4-Isopropyl-2-oxazolidinone 95530-58-8
Price
US $1.00/KG
Min. Order
1KG
Purity
95%-99.99%
Supply Ability
1kg-10MT
Release date
2019-05-24

95530-58-8, (R)-(+)-4-Isopropyl-2-oxazolidinoneRelated Search:

Isopropyl alcohol 2-Methyl-4-isothiazolin-3-one 1,2-Benzisothiazol-3(2H)-one 3-Methyl-2-butanone Isopropyl acetate Methylchloroisothiazolinone/methylisothiazolinone mixture (MCIT/MIT) ISOXAFLUTOLE ISOPROPYL LAURATE CETHROMYCIN (R)-(+)-4-ISOPROPYL-5,5-DIPHENYL-2-OXAZOLIDINONE (R)-(+)-4-TERT-BUTYL-2-OXAZOLIDINONE (-)-CHIRACAMPHOX (R)-(-)-3-PROPIONYL-4-ISOPROPYL-2-OXAZOLIDINONE,N-PROPIONYL-(4R)-ISOPROPYL- 2-OXAZOLIDINONE (4S)-(-)-4-Isopropyl-2-oxazolidinone N-PROPIONYL-(4S)-ISOPROPYL- 2-OXAZOLIDINONE,(S)-3-PROPIONYL-4-ISOPROPYL-2-OXAZOLIDINONE Oxazole Oxazoline 2-Oxazolidone

  • (R)-(+)-4-ISOPROPYL-2-OXAZOLIDINONE
  • (R)-4-ISOPROPYL-2-OXAZOLIDINONE
  • (4R)-4-ISOPROPYL-1,3-OXAZOLIDIN-2-ONE
  • (4R)-(+)-4-ISOPROPYL-2-OXAZOLIDINONE
  • (4R)-(+)-ISOPROPYL-2-OXAZOLIDINONE
  • 4-R-ISOPROPYL-OXAZOLIDIN-2-ONE
  • (<i>R</i>)-4-Isopropyl-2-oxazolidinone
  • -4-Isopropyloxazolidin-2-one
  • (R)-4-Isopropyl-2-oxazolidinone,99%e.e.
  • (4R)-(+)-4-Isopropyl-2-oxazolidinone for synthesis
  • (R)-(+)-4-ISOPROPYL-2-OXAZOLIDINONE, 99% (99% EE/GLC)
  • (R)-Isopropyloxazolidinone
  • (4R)-(+)-4-Isopropyl-2-oxazolidinone, 99% (99% ee)
  • 2-Oxazolidinone, 4-(1-methylethyl)-, (4R)-
  • (4R)-(+)-4-Isopropyl-2-oxazolidinone, 98+%
  • 4-isopropyl-2-oxazolidinone
  • R-4-Isopropyl-2-oxazolidone
  • (4R)-(+)-4-Isopropyl-2-oxazolidone
  • (4R)-4-Propan-2-yl-1,3-oxazolidin-2-one
  • (R)-4-isopropyloxazolidin-2-one
  • (R)-(+)-4-Isopropyl-
  • (4R)-(+)-4-Isopropyl-2-oxazolidinone, 98% 1GR
  • (D)-(+)-4-Isopropyl-2-oxazolidinone
  • (4R)-4-(Prop-2-yl)-1,3-oxazolidin-2-one, (4R)-2-Oxo-4-(prop-2-yl)-1,3-oxazolidine
  • (R)-(+)-4-Isopropyl-2-oxazolidinone, ee: 99%
  • (R)-4-Isopropyl-2-oxazolidinone&gt
  • (R)-(+)-4-Isopropyl-2-oxazolidinone USP/EP/BP
  • TB-2042
  • (R)-(+)-4-Isopropyl-2-oxazolinone
  • 95530-58-8
  • Oxazolidinone Derivatives
  • Chiral Auxiliaries
  • Asymmetric Synthesis
  • Glycidyl Compounds, etc. (Chiral)
  • Chiral Building Blocks
  • Asymmetric Synthesis
  • Chiral Auxiliaries
  • Oxazolidinone Derivatives
  • chiral
  • Asymmetric Synthesis
  • Chiral Building Blocks
  • Glycidyl Compounds, etc. (Chiral)
  • Synthetic Organic Chemistry
  • Peptide
  • Oxazolidinone
  • Pyrazoles,Pyrazines