Cyclohexyl chloroformate
- Product Name
- Cyclohexyl chloroformate
- CAS No.
- 13248-54-9
- Chemical Name
- Cyclohexyl chloroformate
- Synonyms
- AT-51099;cyclohcxyl chlrorformate;CYCLOHEXYL CHLOROFORMATE;cyclohexyl chloromethanoate;Cyclohexyl carbonochloridate;chloroformic acid cyclohexyl ester;carbonochloridicacid,cyclohexylester
- CBNumber
- CB9766031
- Molecular Formula
- C7H11ClO2
- Formula Weight
- 162.61
- MOL File
- 13248-54-9.mol
Cyclohexyl chloroformate Property
- Boiling point:
- 87.5℃
- Density
- 1.14±0.1 g/cm3(Predicted)
- storage temp.
- Hygroscopic, Refrigerator, under inert atmosphere
- solubility
- Chloroform (Sparingly), Ethyl Acetate (Slightly)
- form
- Oil
- color
- Colourless
- CAS DataBase Reference
- 13248-54-9(CAS DataBase Reference)
- EPA Substance Registry System
- Carbonochloridic acid, cyclohexyl ester (13248-54-9)
Safety
- Risk Statements
- 23/24/25-34
- Safety Statements
- 26-36/37/39
- RIDADR
- 3277
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H302Harmful if swallowed
H315Causes skin irritation
H319Causes serious eye irritation
H332Harmful if inhaled
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- C987325
- Product name
- CyclohexylChloroformate
- Packaging
- 1g
- Price
- $1060
- Updated
- 2021/12/16
- Product number
- HCH0025726
- Product name
- CYCLOHEXYL CHLOROFORMATE
- Purity
- 95.00%
- Packaging
- 100G
- Price
- $2868.16
- Updated
- 2021/12/16
- Product number
- FC145349
- Product name
- Cyclohexyl chloroformate
- Packaging
- 100mg
- Price
- $400
- Updated
- 2021/12/16
- Product number
- FC145349
- Product name
- Cyclohexyl chloroformate
- Packaging
- 250mg
- Price
- $450
- Updated
- 2021/12/16
- Product number
- FC145349
- Product name
- Cyclohexyl chloroformate
- Packaging
- 500mg
- Price
- $500
- Updated
- 2021/12/16
Cyclohexyl chloroformate Chemical Properties,Usage,Production
Chemical Properties
transparency liquid
Uses
Cyclohexyl Chloroformate acts as a protecting group for amines and indoles in peptide synthesis.
Synthesis
The Preparative Method of Cyclohexyl Chloroformate: a 1 L round-bottomed flask equipped with a delivery tube extending to the bottom of the flask, a pressure-equalizing addition funnel and a cold-finger condenser cooled with dry ice-acetone were placed in an ice bath. The exit tube of the condenser was connected to a CaCl2 drying tube and a suitable trap for phosgene and HCl. Phosgene was introduced into the flask until 109 g (1.1 mol) had been condensed. The reaction flask was stirred while 100 g (1 mol) of cyclohexyl alcohol was added through the dropping funnel at a rate to keep the mixture in gentle reflux for 1 h. The flask was allowed to stand at room temperature with stirring for 2 h. The solution was then concentrated under reduced pressure at room temperature to remove HCl and the excess phosgene. The residue may be used without further purification.
Precautions
When stored for a prolonged period, it decomposes to CO2 and cyclohexyl chloride. Store in a refrigerator. Bottles may develop pressure and should be cooled before opening. Use in a fume hood. It is irritating to skin, eyes, and mucous membranes.
References
1. Fourneau, M. E.; Montaigne, M.; Puyal, J., J. Anales Soc. Espanol Fis. Quim. 1920, 73, 323.
2. McKay, F. C.; Albertson, N. F., J. Am. Chem. Soc. 1957, 79, 4686.
3. Sakakibara, S.; Shimonishi, Y.; Kishida, Y.; Okada, M.; Sugihara, H., Bull. Chem. Soc. Jpn 1967, 40, 2164.
4. Nishiuchi, Y.; Nishio, H.; Inui, T.; Kimura, T.; Sakakibara, S., Tetrahedron Lett. 1996, 37, 7529.
5. Mez, G.; Mihala, N.; Kóczán, G.; Hudecz, F., Tetrahedron 1998, 54, 6757.
Cyclohexyl chloroformate Preparation Products And Raw materials
Raw materials
Preparation Products
Cyclohexyl chloroformate Suppliers
- Tel
- 021-021-58432009 400-005-6266
- Fax
- 021-58436166
- sales8178@energy-chemical.com
- Country
- China
- ProdList
- 44801
- Advantage
- 61
- Tel
- 010-010-82967028 13522913783
- Fax
- +86-10-82967029
- 2355560935@qq.com
- Country
- China
- ProdList
- 12000
- Advantage
- 60
- Tel
- 13817811078
- Fax
- 86-021-50426522,50426273
- sales@jingyan-chemical.com
- Country
- China
- ProdList
- 9976
- Advantage
- 60
- Tel
- 021-54306202 13764082696
- info@hanhongsci.com
- Country
- China
- ProdList
- 42934
- Advantage
- 64
- Tel
- 15527768836
- 1791901229@qq.com
- Country
- China
- ProdList
- 6950
- Advantage
- 52
- Tel
- Fax
- E-Mail Inquiry
- info@syntechem.com
- Country
- China
- ProdList
- 12984
- Advantage
- 57
- Tel
- 010-51268198
- Fax
- 010-63833209
- leadershipchem@126.com
- Country
- China
- ProdList
- 2546
- Advantage
- 58
- Tel
- 021-58958189
- Fax
- 021-58957967
- wouchina@126.com
- Country
- China
- ProdList
- 2666
- Advantage
- 55
- Tel
- 021-58957966 18930537195
- Fax
- 021-60899437
- wouchina@126.com
- Country
- China
- ProdList
- 3027
- Advantage
- 58
- Tel
- 021-60899189-8001 18918189673
- Fax
- 021-60899304
- gtchem@126.com
- Country
- China
- ProdList
- 2656
- Advantage
- 58
- Tel
- 021-61556450 15800904410
- Fax
- 021-61556450
- Country
- China
- ProdList
- 2832
- Advantage
- 58
- Tel
- 86-027-59601310
- Fax
- +86 (27) 8740-1357
- Country
- China
- ProdList
- 41
- Advantage
- 58
- Tel
- 13564638271
- Fax
- 021-68948280
- shhjiang1977@163.com
- Country
- China
- ProdList
- 2987
- Advantage
- 55
- Tel
- 025-87193546 18652950785
- Fax
- 025-87193546
- chemweiao@163.com
- Country
- China
- ProdList
- 9021
- Advantage
- 60
- Tel
- 18936048580
- chemxilang@163.com
- Country
- China
- ProdList
- 3909
- Advantage
- 58
- Tel
- 0311-89250318 031166536426
- Fax
- 4000311741
- master@sjzsdyn.com
- Country
- China
- ProdList
- 3495
- Advantage
- 58
- Tel
- 4009903999 13395398332
- Fax
- 0539-6365991
- sales@xiyashiji.com
- Country
- China
- ProdList
- 20794
- Advantage
- 60
- Tel
- 571-89925085
- Fax
- 0086-571-89925065
- sales@amadischem.com
- Country
- China
- ProdList
- 131957
- Advantage
- 58
- Tel
- 020-84383047
- Fax
- 020-84380294
- sales@jhd.com.cn
- Country
- China
- ProdList
- 9186
- Advantage
- 65
- Tel
- 18001959627(微信同号) 18001959627
- jjlchem2@163.com
- Country
- China
- ProdList
- 9981
- Advantage
- 58
- Tel
- 0539-6362799 20）
- Fax
- 0539-6362799（To 20）
- Country
- China
- ProdList
- 9998
- Advantage
- 58
- Tel
- 025-58851090 15955137747
- Fax
- (6)02557626880
- sales01@aikonchem.com
- Country
- China
- ProdList
- 15949
- Advantage
- 58
- Tel
- 400-668-9898
- Fax
- 010-51582189
- service@3achem.com
- Country
- China
- ProdList
- 20557
- Advantage
- 58
- Tel
- 18061688856
- easichem@126.com
- Country
- China
- ProdList
- 477
- Advantage
- 58
- Tel
- +86-0551-65418671 +8618949823763
- Fax
- 0551-65418697
- sales@tnjchem.com
- Country
- China
- ProdList
- 34563
- Advantage
- 58
- Tel
- +8615986615575
- Fax
- 0086-13651442114
- info@codchem.com
- Country
- China
- ProdList
- 20342
- Advantage
- 58
- Tel
- +86-0571-88938639 +8617705817739
- Fax
- +86-571-88938652，+86-571- 88492614
- info@dycnchem.com
- Country
- China
- ProdList
- 52846
- Advantage
- 58
- Tel
- 02137285211 18964703211
- Fax
- 02137285211
- info@yudiaochem.com
- Country
- CHINA
- ProdList
- 238
- Advantage
- 58
- Tel
- +86-5922680277 +86-13806087780
- sale@simagchem.com
- Country
- China
- ProdList
- 17346
- Advantage
- 58
- Tel
- 0371-63284658 18135795563
- Fax
- QQ:2885349392
- 2885349392@qq.com
- Country
- China
- ProdList
- 9992
- Advantage
- 58
- Tel
- +86-86-5926051114 +8615060885618
- sales@amoychem.com
- Country
- China
- ProdList
- 6369
- Advantage
- 58
- Tel
- +86-023-6139-8061 +86-86-13650506873
- sales@chemdad.com
- Country
- China
- ProdList
- 39927
- Advantage
- 58
- Tel
- +8618523575427
- sales@conier.com
- Country
- China
- ProdList
- 49975
- Advantage
- 58
- Tel
- 027-13163388153 13163388153
- yeqiu416@163.com
- Country
- China
- ProdList
- 9810
- Advantage
- 58
- Tel
- 027-59225746 18062681621
- Fax
- 027-59225746
- 730880265@qq.com
- Country
- China
- ProdList
- 4877
- Advantage
- 58
- Tel
- 18001895509
- Fax
- QQ2934193566;
- 986383309@qq.com
- Country
- China
- ProdList
- 2680
- Advantage
- 58
- Tel
- 15002184385 15021598081 15002184385
- product001@xiushipharm.com
- Country
- China
- ProdList
- 4719
- Advantage
- 58
- Tel
- 027-83855310 13476018176
- Fax
- 13476018176
- 408614617@qq.com
- Country
- China
- ProdList
- 996
- Advantage
- 58
- Tel
- --
- Fax
- --
- sarah@mainchem.com
- Country
- China
- ProdList
- 6547
- Advantage
- 58
- Tel
- 021-51816796-820 13611835272
- Fax
- 021-5161 3951
- sales2@sunwaypharm.com
- Country
- China
- ProdList
- 44119
- Advantage
- 58
- Tel
- 13303867194
- 3001317055@qq.com
- Country
- China
- ProdList
- 9681
- Advantage
- 58
- Tel
- 0551-77777777-5 13333333333
- Fax
- 0319 5925599
- Country
- China
- ProdList
- 9998
- Advantage
- 58
- Tel
- 0319-5925599 13315915972
- 13313090628@163.com
- Country
- China
- ProdList
- 2916
- Advantage
- 58
- Tel
- 400-1647117 13681763483
- product02@bidepharm.com
- Country
- China
- ProdList
- 59936
- Advantage
- 58
- Tel
- 029-029-029-81148696 18161915376
- 1040@dideu.com
- Country
- China
- ProdList
- 10001
- Advantage
- 58
- Tel
- 13129948835
- 2756772312@qq.com
- Country
- China
- ProdList
- 4830
- Advantage
- 58
- Tel
- 0513-66017706 18551496367
- 2186883463@qq.com
- Country
- China
- ProdList
- 5001
- Advantage
- 58
- Tel
- 13125175253
- 1005221305@qq.com
- Country
- China
- ProdList
- 3095
- Advantage
- 58
- Tel
- 15827338311
- 1802085297@qq.com
- Country
- China
- ProdList
- 4002
- Advantage
- 58
- Tel
- 18202564928
- 214896283@QQ.COM
- Country
- China
- ProdList
- 600
- Advantage
- 58
View Lastest Price from Cyclohexyl chloroformate manufacturers
- Product
- Cyclohexyl chloroformate 13248-54-9
- Price
- US $1.00/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- Customized
- Release date
- 2018-12-15