Acid dye
Acid dye refers to the dyestuff containing a sulfonic acid group, a carboxyl, a hydroxy or other soluble group in the molecular structure and used in acid or neutral dye bath. According to the chemical structure it can be divided into azo type, triphenylmethane type, anthraquinone type, anthracene oxygen type and nitroso type pyrazolone type. Acid dyestuff is widely used, mainly as direct dyestuff for protein fibers (such as wool, silk) and polyamide fibers, protein. And the dyeing needs to be conducted in an acidic solution. It’s mainly used for nylon, wool, leather, silk and others. Direct dyes or basic dyes are applied in paper dyeing far more often than acid dyestuff.
According to the molecular structure and dyeing conditions of the acid dyestuff, it can be divided into strong acid dyes, weak acid dyes, acid mordant dyes, acid-premetallized dyes and neutral dyes. Acid dyestuff is mainly used for wool, silk, leather and nylon and other fibers with its vivid luster and wild chromatogram.
Strong acid dyes whose molecules are relatively small, have bright color and good levelness but a stronger affinity for the wool fibers, and need to be used in strong acidic dye bath (pH≤4). The main chemical structures of Strong acid dyes are azo, anthraquinone, triarylmethane and oxygen anthracene type. For example, acid Bright Yellow 2G (C. I. Acid Yellow 17), acid anthraquinone blue (C. I. Acid Blue 25), acid Lake Blue A (C. I. Acid Blue 7) and acid Rose Red B (C. I. Acid Red 52), etc. are all strong acid dyes.
Weak acid dyes have more complex molecules than strong acid dyes, and relatively less water-soluble groups. They have weaker affinity for wool fiber, and can be used in weakly acidic or nearly neutral dye bath. In addition to the ionic bonds between the anions of dyes and the cations of wool molecules, the two non-polar molecules combine by means of van der Waals attraction. So weak acid dyes have a poor levelness but an excellent wash fastness, therefore they are also known as milling dyes. The main chemical structures of weak acid dyes are the types of azo and anthraquinone. For example, weak acid black BR (C. I. Acid Black 24), weakly acidic Brilliant Blue RAW (C. I. Acid Blue 80) are weak acid dyes.
After treated by metal mordant (Chromium salts), acid mordant dyes generate the dye-metal complex on the fiber, which can improve their resistance to sunlight exposure and wetness. But such treatment will leave the dyed products in a darker hue, make their shade and color-matching less manageable and complicate the dyeing procedures.
Acidic metal complex dyes are a class acid dyes that can generate inner complex with some transition metals (such as copper, network, cobalt, etc.). In contrast with acid mordant dyes, acidic metal complex dyes generate the dye-metal complex with complexing agent first, and then dye the fiber, which is simpler than the dyeing procedure of acid mordant dyes.
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- Chemical Name:
- Acid Green 28
- CAS:
- 12217-29-7
- MF:
- C34H32N2Na2O10S2
- Structure:
- Chemical Name:
- Acid Blue 138
- CAS:
- 1324-53-4
- MF:
- C32H36N2Na2O8S2
- Structure:
- Chemical Name:
- Acid Red 374
- CAS:
- 6507-78-4
- MF:
- C38H29N4Na3O11S3
- Structure:
- Chemical Name:
- ALIZARIN RUBINOL R
- CAS:
- 4478-76-6
- MF:
- C24H19N2NaO5S
- Structure:
- Chemical Name:
- ACID BLUE 29
- CAS:
- 5850-35-1
- MF:
- C22H14N6Na2O9S2
- Structure:
- Chemical Name:
- Acid Red 142
- CAS:
- 6406-66-2
- MF:
- C22H17N4NaO7S2
- Chemical Name:
- Acid Scarlet RS
- Structure:
- Chemical Name:
- GERANINE G
- CAS:
- 8003-84-7
- MF:
- C24H15N3Na2O7S3
- Chemical Name:
- Acid Brown 283
- CAS:
- 12219-66-8
- Structure:
- Chemical Name:
- ALPHAZURINE A
- CAS:
- 3486-30-4
- MF:
- C37H37N2NaO6S2
- Chemical Name:
- Acid Blue 350
- CAS:
- 138067-74-0
- Chemical Name:
- Acid Blue 230
- CAS:
- 12219-37-3
- MF:
- C24H21N2NaO5S
- Structure:
- Chemical Name:
- ACID YELLOW 17
- CAS:
- 6359-98-4
- MF:
- C16H13Cl2N4NaO7S2
- Structure:
- Chemical Name:
- ACID RED 13
- CAS:
- 6039-95-8
- MF:
- C20H12N2Na2O7S2
- Structure:
- Chemical Name:
- ACID YELLOW 40
- CAS:
- 6372-96-9
- MF:
- C23H19ClN4O7S2.Na
- Structure:
- Chemical Name:
- ACID YELLOW 25 (C.I. 18835)
- CAS:
- 6359-85-9
- MF:
- C23H20N5NaO6S2
- Structure:
- Chemical Name:
- ACID VIOLET 7
- CAS:
- 4197-09-5
- MF:
- C20H16N4Na2O9S2
- Structure:
- Chemical Name:
- ACID RED 114
- CAS:
- 6459-94-5
- MF:
- C37H28N4Na2O10S3
- Structure:
- Chemical Name:
- ACID ORANGE 51
- CAS:
- 8003-88-1
- MF:
- C36H26N6Na2O11S3
- Chemical Name:
- Acid Red 3GX
- Structure:
- Chemical Name:
- ACID BLUE 15
- CAS:
- 5863-46-7
- MF:
- C42H46N3NaO6S2
- Chemical Name:
- Neutral Red 2gl
- CAS:
- 12239-05-3
- MF:
- C17H14IN5O4S
- Structure:
- Chemical Name:
- Acid Orange 56
- CAS:
- 6470-20-8
- MF:
- C32H22N6Na2O8S2
- Structure:
- Chemical Name:
- Acid Red 154
- CAS:
- 6507-79-5
- MF:
- C40H34N4Na2O10S2
- Structure:
- Chemical Name:
- Acid Yellow 199
- CAS:
- 70865-20-2
- MF:
- C19H15N4NaO6S
- Chemical Name:
- 249 ACID RED 249
- Chemical Name:
- Acid Orange 89
- CAS:
- 12269-95-3
- MF:
- C32H22N10O8.Cr.Na
- Chemical Name:
- Acid Yellow 128
- CAS:
- 51053-43-1
- MF:
- C16H16N4O5S
- Chemical Name:
- Acid Turquoise Blue
- Structure:
- Chemical Name:
- ACID BLUE 92
- CAS:
- 3861-73-2
- MF:
- C26H20N3NaO10S3
- Structure:
- Chemical Name:
- Acid Violet 43
- CAS:
- 4430-18-6
- MF:
- C21H16NNaO6S
- Structure:
- Chemical Name:
- Acid Violet 49
- CAS:
- 1694-09-3
- MF:
- C39H42N3NaO6S2
- Chemical Name:
- Acid black 29
- CAS:
- 12217-14-0
- Structure:
- Chemical Name:
- Acid Yellow 61
- CAS:
- 12217-38-8
- MF:
- C24H22Cl2N5NaO6S2
- Chemical Name:
- Acid Yellow 79
- CAS:
- 12220-70-1
- MF:
- C47H40N10Na2O12S4
- Structure:
- Chemical Name:
- Acid Red 186
- CAS:
- 52677-44-8
- MF:
- C20H12CrN4NaO8S2
- Chemical Name:
- Acid Brown 348
- CAS:
- 72827-72-6
- Chemical Name:
- ACID BLACK NT
- Chemical Name:
- Acid Yellow 220
- CAS:
- 71603-79-7
- MF:
- C24H18IN4NaO7S
- Structure:
- Chemical Name:
- Acid Brown 440
- CAS:
- 93376-15-9
- MF:
- C34H25N8NaO14S3
- Structure:
- Chemical Name:
- CROCEIN SCARLET 7B
- CAS:
- 6226-76-2
- MF:
- C24H18N4Na2O7S2
- Structure:
- Chemical Name:
- SOLWAY BLUE RN
- CAS:
- 4403-89-8
- MF:
- C22H19N2NaO5S
- Chemical Name:
- VITAMIN FOLIC ACID ASSAY MEDIUM
- Structure:
- Chemical Name:
- Acid Red 57
- CAS:
- 12217-34-4
- MF:
- C24H22N4O6S2
- Chemical Name:
- Acid Brown 282
- CAS:
- 12219-65-7
- Chemical Name:
- Acid Red 336
- CAS:
- 12239-11-1
- Chemical Name:
- Acid Brown 161
- CAS:
- 61724-13-8
- Chemical Name:
- Acid Green 73
- CAS:
- 12219-93-1
- Chemical Name:
- Acid Blue 168
- CAS:
- 12219-24-8
- MF:
- C20H15CuN5O5S
- Chemical Name:
- Acid Brown 163
- Structure:
- Chemical Name:
- ACID BLACK 48
- CAS:
- 1328-24-1
- MF:
- C28H18N3NaO7S
- Chemical Name:
- Acid Yellow 110
- CAS:
- 12220-74-5
- Chemical Name:
- Neutral Brown Rl
- CAS:
- 12238-94-7
- MF:
- C15H14O5
- Structure:
- Chemical Name:
- disodium 6-amino-4-hydroxy-5-[(4-nitro-2-sulphonatophenyl)azo]naphthalene-2-sulphonate
- CAS:
- 6441-91-4
- MF:
- C16H10N4Na2O9S2
- Chemical Name:
- Week Acid Dyes
- Chemical Name:
- C.I.Acid Yellow 23
- Structure:
- Chemical Name:
- sodium 4-hydroxy-5-[(2-methoxy-4-nitrophenyl)azo]-6-(phenylamino)naphthalene-2-sulphonate
- CAS:
- 6222-55-5
- MF:
- C23H17N4NaO7S
- Structure:
- Chemical Name:
- sodium 6-amino-4-hydroxy-5-[[2-(trifluoromethyl)phenyl]azo]naphthalene-2-sulphonate
- CAS:
- 67786-14-5
- MF:
- C17H13F3N3NaO4S
- Chemical Name:
- Acid Orange 86
- CAS:
- 12220-07-4
- Chemical Name:
- Acid Orange 127
- CAS:
- 12269-96-4
- MF:
- C24H19N4NaO4S
- Chemical Name:
- Acid Yellow RXL
- Chemical Name:
- Acid Brown 365
- CAS:
- 63641-88-3
- Chemical Name:
- Acid Brown 191
- CAS:
- 61724-16-1
- Chemical Name:
- C.I.Acid Brown 37
- Structure:
- Chemical Name:
- ACID BLUE 41
- CAS:
- 2666-17-3
- MF:
- C23H20N3NaO6S
- Structure:
- Chemical Name:
- ACID BLUE 158
- MF:
- C20H12N2Na2O8S2
- Structure:
- Chemical Name:
- disodium 4-[[2,4-dihydroxy-3-[(4-sulphonatophenyl)azo]phenyl]azo]naphthalene-1-sulphonate
- CAS:
- 5850-15-7
- MF:
- C22H14N4Na2O8S2
- Structure:
- Chemical Name:
- sodium 5-[(2-hydroxynaphthyl)azo]naphthalenesulphonate
- CAS:
- 5850-93-1
- MF:
- C20H13N2NaO4S
- Structure:
- Chemical Name:
- sodium 3-[[4-(benzoylethylamino)-2-methylphenyl]azo]-4-hydroxynaphthalene-1-sulphonate
- CAS:
- 6245-59-6
- MF:
- C26H24N3NaO5S
- Chemical Name:
- Acid Violet 109
- CAS:
- 12220-63-2
- Chemical Name:
- ACID BROWN 422
- CAS:
- 126851-39-6
- Chemical Name:
- Acid Blue 182
- CAS:
- 12219-26-0
- MF:
- C23H17N3O9S2·2Na
- Chemical Name:
- C.I.Acid Red 337
- MF:
- C17H11F3N3NaO4S
- Chemical Name:
- ACID DYES
- Chemical Name:
- Acid Orange 95
- CAS:
- 12217-33-3
- Structure:
- Chemical Name:
- Acid Black 60
- CAS:
- 12218-95-0
- MF:
- C38H33CrN8O10S2
- Chemical Name:
- Acid Red 226
- CAS:
- 12269-99-7
- MF:
- C32H22N10O8.Cr.Na
- Chemical Name:
- Acid Orange 171
- Structure:
- Chemical Name:
- Acid Brown 98
- CAS:
- 12269-88-4
- MF:
- C48H39FeN15O21S3
- Chemical Name:
- ACID BLUE 82
- CAS:
- 12217-19-5
- Chemical Name:
- C.I.Acid Brown 75
- Structure:
- Chemical Name:
- ACID BLACK 24
- CAS:
- 3071-73-6
- MF:
- C36H26N5NaO6S2
- Structure:
- Chemical Name:
- ACID YELLOW 14 (C.I. 18960)
- CAS:
- 6359-97-3
- MF:
- C16H13Cl2N4NaO4S
- Structure:
- Chemical Name:
- Acid Blue 277
- CAS:
- 25797-81-3
- MF:
- C24H24N3NaO8S2
- Structure:
- Chemical Name:
- Acid Yellow 127
- CAS:
- 73384-78-8
- MF:
- C26H20Cl2N9NaO4S
- Structure:
- Chemical Name:
- disodium 4,4'-[methylenebis(4,1-phenyleneimino)]bis[1-amino-9,10-dihydro-9,10-dioxoanthracene-2-sulphonate]
- CAS:
- 25826-34-0
- MF:
- C41H29N4NaO10S2
- Chemical Name:
- Acid Brown 58
- CAS:
- 12269-87-3
- Chemical Name:
- Acid Brown 215
- Chemical Name:
- Acid Brilliant Blue RL
- Chemical Name:
- Acid dyestuff levelling agent
- Structure:
- Chemical Name:
- ACID BLACK 52
- CAS:
- 5610-64-0
- MF:
- C60H36Cr2N9Na3O21S3
- Chemical Name:
- Acid Red 213
- CAS:
- 12715-60-5
- MF:
- C16H13N3O4S
- Chemical Name:
- 214 ACID BROWN 214
- Structure:
- Chemical Name:
- ACID RED 8
- CAS:
- 4787-93-3
- MF:
- C18H17N2NaO7S2
- Chemical Name:
- Acid Orange 3RL
- Structure:
- Chemical Name:
- ACID BLUE 25
- CAS:
- 6408-78-2
- MF:
- C20H13N2NaO5S
- Chemical Name:
- Acid Blue BGA
- Chemical Name:
- Acid Yellow 2GL
- Structure:
- Chemical Name:
- ACID BLUE 40
- CAS:
- 6424-85-7
- MF:
- C22H16N3NaO6S
- Structure:
- Chemical Name:
- Acid Red 137
- CAS:
- 6222-63-5
- MF:
- C20H17N4NaO6S