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ChemicalBook >  Product Catalog >  Organic Chemistry >  Organometallic compounds >  Organic iron >  5,10,15,20-TETRAPHENYL-21H,23H-PORPHINE IRON(III) CHLORIDE

5,10,15,20-TETRAPHENYL-21H,23H-PORPHINE IRON(III) CHLORIDE

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5,10,15,20-TETRAPHENYL-21H,23H-PORPHINE IRON(III) CHLORIDE Basic information

Product Name:
5,10,15,20-TETRAPHENYL-21H,23H-PORPHINE IRON(III) CHLORIDE
Synonyms:
  • 5,10,15,20-TETRAPHENYL-21H,23H-PORPHINE IRON(III) CHLORIDE
  • 5,10,15,20-TETRAPHENYL-21H,23H-PORPHYRIN IRON(III) CHLORIDE
  • MESO-TETRAPHENYLPORPHYRIN IRON(III) CHLORIDE
  • MESO-TETRAPHENYLPORPHYRIN IRON(III) CHLORIDE COMPLEX
  • IRON TPP
  • IRON (III) MESO-TETRAPHENYLPORPHINE CHLORIDE
  • IRON (III) TETRAPHENYLPORPHINE CHLORIDE
  • RARECHEM AS SA 0004
CAS:
16456-81-8
MF:
C44H28ClFeN4
MW:
704.03
Product Categories:
  • metal porphine (porphyrin) complex
Mol File:
16456-81-8.mol
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5,10,15,20-TETRAPHENYL-21H,23H-PORPHINE IRON(III) CHLORIDE Chemical Properties

Melting point:
300 °C
storage temp. 
Inert atmosphere,Room Temperature
form 
crystal
color 
purple
Water Solubility 
Insoluble in water.
Stability:
Stable. Incompatible with strong oxidizing agents, strong acids.
InChIKey
ZDYSAMCSFRQDMN-XBZZRTMISA-M
CAS DataBase Reference
16456-81-8
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Safety Information

Safety Statements 
22-24/25
WGK Germany 
3
HS Code 
29349990

MSDS

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5,10,15,20-TETRAPHENYL-21H,23H-PORPHINE IRON(III) CHLORIDE Usage And Synthesis

Chemical Properties

dark red or purple powder

Uses

Iron(III) meso-tetraphenylporphine chloride is used catalyzing reagent for silylation reactions.

Purification Methods

Purify it by extraction from a thimble (Soxhlet) with CHCl3. Concentrate the extract to ca 10mL and add ca 80mL of hot MeOH. Dark blue crystals separate on cooling. It can be recrystallised several times from CHCl3/MeOH. Avoid prolonged heating. It is quite soluble in organic solvents but insoluble in pet ether. [Rothemund & Manotti J Am Chem Soc 70 1808 1948, UV: Dorough et al. J Am Chem Soc 73 4315 1951, Beilstein 26 III 1960.]

5,10,15,20-TETRAPHENYL-21H,23H-PORPHINE IRON(III) CHLORIDESupplier

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