ALLYL BENZOATE Chemical Properties

Boiling point:

83-84°C 5mm

Density 

1.05

refractive index 

1.5160-1.5190

solubility 

soluble in Methanol

form 

clear liquid

color 

Colorless to Light yellow to Light orange

Odor

at 100.00 %. sweet floral cherry berry

Odor Type

fruity

LogP

3.024 (est)

CAS DataBase Reference

583-04-0

EPA Substance Registry System

Benzoic acid, allyl ester (583-04-0)

Safety Information

HS Code 

2916399090

ALLYL BENZOATE Usage And Synthesis

Chemical Properties

Colorless liquid. (Yellowish if made by old cross-esterification method). B.P. 230℃. Sp.Gr. 1.058. Insoluble in water.

Uses

Allyl Benzoate is a versatile reactant used in the preparation of stable potassium alkyltrifluoroborates for Suzuki-Miyaura cross-coupling reactions with aryltriflates and arylhalides.

Definition

ChEBI: Allyl benzoate is a benzoate ester.

Preparation

Allyl benzoate is produced by direct esterification (azeotropic) of Allyl alcohol and Benzoic acid.

Synthesis Reference(s)

The Journal of Organic Chemistry, 57, p. 2166, 1992 DOI: 10.1021/jo00033a048
Tetrahedron Letters, 29, p. 4513, 1988 DOI: 10.1016/S0040-4039(00)80534-1
Synthetic Communications, 5, p. 213, 1975 DOI: 10.1080/00397917508064112

Solubility in organics

Allyl Benzoate is miscible with alcohol, perfume oils. Poorly soluble in Propylene glycol.

ALLYL BENZOATE(583-04-0)Related Product Information

• PROPYL BENZOATE
• Phenyl benzoate
• ALLYL BENZOATE
• LINALYL ANTHRANILATE
• ALLYL ANTHRANILATE
• ANTHRANILIC ACID CINNAMYL ESTER
• DIALLYL ISOPHTHALATE
• LINALYL BENZOATE
• 3-methyl-2-butenyl salicylate
• BENZOIC ACID 3-METHYL-2-BUTENYL ESTER
• Diallyl phthalate
• Triallyl trimellitate
• 2,4,5-TRIMETHYLANILINE
• TETRAALLYL PYROMELLITATE
• (-)-TETRA-O-BENZOYL-2-HYDROXY-D-GLUCAL
• ALLYL SALICYLATE
• TRANS-2-HEXENYL SALICYLATE
• TRIALLYL 1,3,5-BENZENETRICARBOXYLATE