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Benzoximate

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Benzoximate Basic information

Product Name:
Benzoximate
Synonyms:
  • ETHYL-O-BENZOYL-3-CHLORO-2,6-DIMETHOXY-BENZOHYDROXIMATE
  • CITRAZON
  • 3-chloro-2,6-dimethoxyl-α-ethoxyimino benzyl benzoate
  • Benzoic acid 3-chloro-α-ethoxyimino-2,6-dimethoxybenzyl
  • Benzoic acid 3-chloro-α-ethoxyimino-2,6-dimethoxybenzyl ester
  • 3-CHLORO-ALPHA-ETHOXYIMINO-2,6-DIMETHOXYBENZYLBENZOATE
  • Benzomate standard
  • Aazomate
CAS:
29104-30-1
MF:
C18H18ClNO5
MW:
363.79
EINECS:
249-439-1
Product Categories:
  • A-BPesticides&Metabolites
  • AcaricidesAlphabetic
  • Alpha sort
  • B
  • BA - BH
  • Pesticides
  • Pesticides&Metabolites
Mol File:
29104-30-1.mol
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Benzoximate Chemical Properties

Melting point:
73℃
Boiling point:
483.3±55.0 °C(Predicted)
Density 
1.21
storage temp. 
0-6°C
solubility 
DMSO (Slightly), Methanol, (Slightly)
form 
Solid
color 
White to Off-White
Water Solubility 
30.26mg/L(temperature not stated)
CAS DataBase Reference
29104-30-1
EPA Substance Registry System
Benzomate (29104-30-1)
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Safety Information

RTECS 
DF9700000
HS Code 
29280000
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Benzoximate Usage And Synthesis

Description

Benzoximate is an acaricide used to control all stages of spider mites on pome fruit, stone fruit, citrus fruit, vines and ornamentals. It was commercialized in Japan in 1971 but discontinued there in 1998 and is currently registered only in Italy, South Korea, South Africa and Switzerland.

Chemical Properties

Pure product is white crystal. m.p. 73℃, vapor pressure <1.33×10-2Pa (4.53×10-4Pa (25℃). solubility at 20℃: benzene 650g/L, dimethylformamide 1460g/L, xylene 710g/L (1296g/L), ethanol 70g/L (93g/L), hexane 8g/L, acetone 980g /L (1440g/L); almost insoluble in water. Stable to acid, easy to decompose in strong alkali medium, decomposition or isomerization at about 80℃.

Uses

Benzoximate is an acaricide that inhibits fruit tree red spider mite Panonychys ulmi (Koch)[1].

Mode of action

The mode of action of benzoximate is not known. Resistance has been reported in citrus red mite, European red mite and twospotted spider mite.

Toxicity evaluation

Benzoximate is relatively non-toxic to mammals and fish, but is moderately toxic to predatory mites.

References

[1] Kim YJ, et al. Multiple resistance and biochemical mechanisms of pyridaben resistance in Tetranychus urticae (Acari: Tetranychidae). J Econ Entomol. 2006 Jun;99(3):954-8. DOI:10.1603/0022-0493-99.3.954

Benzoximate Preparation Products And Raw materials

Raw materials

BenzoximateSupplier

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