(-)-Camphanic acid chloride
(-)-Camphanic acid chloride Basic information
- Product Name:
- (-)-Camphanic acid chloride
- Synonyms:
-
- (-)-CAMPHANIC ACID CHLORIDE
- (-)-CAMPHANIC CHLORIDE
- (1S)-(-)-Camphanicacidchloride
- 3-oxa-2-oxobornane-4-carbonyl chloride
- (1S)-4,7,7-Trimethyl-3-oxo-2-oxabicyclo[2.2.1]heptane-1-carbonyl chlorid
- (1S)-(-)-Camphanicchloride,95%
- (1S,4R)-(-)-Camphanic chloride
- (1S)-(-)-Camphanic chloride, 98% (99% EE)
- CAS:
- 39637-74-6
- MF:
- C10H13ClO3
- MW:
- 216.66
- EINECS:
- 254-552-4
- Product Categories:
-
- Chiral Reagents
- Chiral Compound
- FINE Chemical & INTERMEDIATES
- Chemical intermediate for Efavirenz
- Bicyclic Monoterpenes
- Biochemistry
- for Resolution of Alcohols & Thiols
- Optical Resolution
- Synthetic Organic Chemistry
- Terpenes
- Mol File:
- 39637-74-6.mol
(-)-Camphanic acid chloride Chemical Properties
- Melting point:
- 71-73 °C(lit.)
- alpha
- -18 º (c=2, CCl4)
- Boiling point:
- 310.92°C (rough estimate)
- Density
- 1.2072 (rough estimate)
- refractive index
- 1.5390 (estimate)
- storage temp.
- 2-8°C
- solubility
- soluble in Dichloromethane, Ether, Ethyl Acetate, Methanol
- form
- Powder
- color
- Yellow to orange-brown
- optical activity
- [α]23/D 18°, c = 2 in carbon tetrachloride
- Water Solubility
- decomposes
- Sensitive
- Moisture Sensitive
- BRN
- 3590860
- InChIKey
- PAXWODJTHKJQDZ-RGURZIINSA-N
- CAS DataBase Reference
- 39637-74-6(CAS DataBase Reference)
Safety Information
- Hazard Codes
- C,Xi
- Risk Statements
- 34-29
- Safety Statements
- 26-36/37/39-45-8-27
- RIDADR
- UN 3261 8/PG 2
- WGK Germany
- 3
- F
- 10-21
- HazardClass
- 8
- PackingGroup
- II
- HS Code
- 29322090
MSDS
- Language:English Provider:(-)-Camphanic acid chloride
- Language:English Provider:SigmaAldrich
- Language:English Provider:ACROS
- Language:English Provider:ALFA
(-)-Camphanic acid chloride Usage And Synthesis
Chemical Properties
Off-White Powder
Uses
An optically active resolving agent
Uses
(1S)-(-)-Camphanic chloride is used as a resolving agent for alcohols as the diastereomeric esters by crystallization or chromatography and as a chiral derivatization reagent for determination of enantiomeric excess of alcohols and amines.
Uses
(1S)-(-)-Camphanic chloride may be used in esterification of enantiomers in volatiles releasedf from wheat, in order to determine the proportion of enantiomers and also in quantifying the esters.
General Description
(1S)-(-)-Camphanic chloride is a chiral derivatizing agent. It can be prepared by reacting (-)-(1S,4R)-camphanic acid with thionyl chloride.
Purification Methods
It is soluble in toluene (50g/100mL at 0o) and crystallises from pet ether (b 40-60o). It sublimes at 70o/5mm, Store it dry at 0o, max (CCl4) 1805s and 1780m cm-1. Armarego et al. J Chem Soc, Perkin Trans I 2229 1976, Gerlach Helv Chim Acta 51 1587 1968, Gerlach Helv Chim Acta 68 1815 1985, Beilstein 18/8 V 101.]
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