Basic information Safety Supplier Related

Dipotassium hexachloroiridate

Basic information Safety Supplier Related

Dipotassium hexachloroiridate Basic information

Product Name:
Dipotassium hexachloroiridate
Synonyms:
  • IRIDIUM POTASSIUM CHLORIDE
  • dipotassium,(oc-6-11)-iridate(2-hexachloro-
  • dipotassiumhexachloroiridate
  • hexachloro-,dipotassium,(OC-6-11)-Iridate(2-)
  • hexachloroiridium(2-)
  • Potassium hexachloroiridate(IV), 99.99% metals basis
  • POTASSIUM HEXACHLOROIRIDATA(IV)
  • Potassium hexachloroiridate(IV), Ir 39% min
CAS:
16920-56-2
MF:
Cl6IrK-
MW:
444.02
EINECS:
240-976-7
Product Categories:
  • chemical reaction,pharm,electronic,materials
  • halometallate salt
  • Materials Science
  • Metal and Ceramic Science
  • Potassium Salts
  • Metal and Ceramic Science
  • Potassium Salts
  • Salts
Mol File:
16920-56-2.mol
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Dipotassium hexachloroiridate Chemical Properties

Melting point:
>385 °C (lit.)
Density 
3,546 g/cm3
storage temp. 
2-8°C, protect from light, stored under nitrogen
form 
Powder
Specific Gravity
3.546
color 
black
Water Solubility 
Insoluble in water.
Sensitive 
Hygroscopic
Stability:
Stable. Incompatible with strong reducing agents.
InChI
InChI=1S/6ClH.Ir.K/h6*1H;;/q;;;;;;+4;+1/p-6
InChIKey
BRVVRIMRECYICB-UHFFFAOYSA-H
SMILES
[Ir+4]([Cl-])([Cl-])([Cl-])([Cl-])([Cl-])[Cl-].[K+]
CAS DataBase Reference
16920-56-2(CAS DataBase Reference)
EPA Substance Registry System
Iridate(2-), hexachloro-, dipotassium, (OC-6-11)- (16920-56-2)
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Safety Information

Hazard Codes 
Xn
Risk Statements 
20/21/22-36/37/38
Safety Statements 
26-36
WGK Germany 
3
TSCA 
Yes

MSDS

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Dipotassium hexachloroiridate Usage And Synthesis

Chemical Properties

Black Crystalline Powder

Uses

Black pigment (porcelain decoration). The iridium (III) salt is also known: K3IrCl6, greenishyellow.

Uses

Iridium potassium chloride (K2IrCl6) is used as a black pigment to make black porcelain kitchen and bathroom fixtures.

Uses

Potassium Hexachloroiridate(IV) is a reagent with biocatalytic activity

Purification Methods

Crystallise it from hot aqueous solution containing a few drops of HNO3 to keep it in the oxidised state. It forms small shiny red-black octahedral crystals which are dried at 100o and give a red powder on grinding [Grube in Handbook of Preparative Inorganic Chemistry (Ed. Brauer) Academic Press Vol II pp 1593-1594 1965].

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