ChemicalBook > Product Catalog > Chemical Reagents > Organic reagents > Borate > (4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)BENZENE
(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)BENZENE
(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)BENZENE Basic information
- Product Name:
- (4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)BENZENE
- Synonyms:
-
- (4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)benzene, 2-Phenyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
- Phenylpinacolborane
- Pinacol phenylboronate
- 1,3,2-Dioxaborolane,4,4,5,5-tetraMethyl-2-phenyl-
- (Pinacolboryl)benzene
- Phenylboronic acid pinacol ester 97%
- cyclic tetramethylethylene ester benzeneboronic acid
- PHENYL-BORONIC ACID PINACOL ESTER
- CAS:
- 24388-23-6
- MF:
- C12H17BO2
- MW:
- 204.07
- Mol File:
- 24388-23-6.mol
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(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)BENZENE Chemical Properties
- Melting point:
- 27-31 °C(lit.)
- Boiling point:
- 130°C/20mmHg(lit.)
- Density
- 0.99±0.1 g/cm3(Predicted)
- Flash point:
- 225 °F
- storage temp.
- Keep in dark place,Sealed in dry,Room Temperature
- form
- powder to lump
- color
- White to Almost white
- InChIKey
- KKLCYBZPQDOFQK-UHFFFAOYSA-N
- CAS DataBase Reference
- 24388-23-6(CAS DataBase Reference)
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Safety Information
- Hazard Codes
- Xn,Xi
- Risk Statements
- 22-36/37/38
- Safety Statements
- 26-36
- WGK Germany
- 3
- Hazard Note
- Irritant
- HS Code
- 29319090
MSDS
- Language:English Provider:SigmaAldrich
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(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)BENZENE Usage And Synthesis
Chemical Properties
White to light yellow crystal
Uses
Phenylboronic acid pinacol ester can be used:
- To prepare sulfinamide derivatives by reacting with diethylaminosulfur trifluoride (DAST) and potassium phenyltrifluoroborate.
- As a substrate in the study of Suzuki–Miyaura coupling of various aryl iodides over SiliaCat?Pd(0).
Uses
suzuki reaction
Synthesis Reference(s)
The Journal of Organic Chemistry, 60, p. 7508, 1995 DOI: 10.1021/jo00128a024
General Description
Phenylboronic acid, pinacol ester, also known as boronate ester, is generally used in metal-catalyzed C-C bond formation reactions like Suzuki–Miyaura?reaction.
(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)BENZENESupplier
J & K SCIENTIFIC LTD.
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(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)BENZENE(24388-23-6)Related Product Information
- Phenylboronic acid
- BENZYLBORONIC ACID PINACOL ESTER
- 2-Nitrobenzeneboronic acid pinacol ester
- 2-Aminophenylboronic acid pinacol ester
- (2-BROMOMETHYLPHENYL)BORONIC ACID, PINACOL ESTER
- 3-(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)PHENOL
- 4-Nitrophenylboronic acid pinacol ester
- (4-BENZYLOXYCARBONYLAMINOPHENYL)BORONIC ACID, PINACOL ESTER
- (2-CYANOMETHYLPHENYL)BORONIC ACID, PINACOL ESTER
- 4-(N-Boc-amino)phenylboronic acid pinacol ester
- 2,6-DIMETHYL-4-(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)PHENOL
- 3-AMINOMETHYLPHENYLBORONIC ACID, PINACOL ESTER, HCL
- 4-Aminophenylboronic acid pinacol ester
- 4-AMINOMETHYLPHENYLBORONIC ACID, PINACOL ESTER, HCL
- 4-Hydroxyphenylboronic acid pinacol ester
- 1-(3-Pyridyl)-4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)benzene
- 1,4-Benzenediboronic acid bis(pinacol) ester
- Trifluoromethylthio-4-(4,4,5,5-tetramethyl-[1,3,2]dioxaborolan-2-yl)-benzene