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ETHYL 2-(BROMOMETHYL)ACRYLATE

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ETHYL 2-(BROMOMETHYL)ACRYLATE Basic information

Product Name:
ETHYL 2-(BROMOMETHYL)ACRYLATE
Synonyms:
  • 2-(BROMOMETHYL)ACRYLIC ACID ETHYL ESTER
  • ETHYL 2-(BROMOMETHYL)ACRYLATE
  • 2-Propenoic acid, 2-(bromomethyl)-, ethyl ester
  • 2-(Bromomethyl)-2-propenoic Acid Ethyl Ester
  • 2-Carbethoxyallyl Bromide
  • Ethyl 2-(Bromomethyl)-2-propenoate
  • Ethyl 3-Bromo-2-(methylene)propanoate
  • Ethyl Bromomethacrylate
CAS:
17435-72-2
MF:
C6H9BrO2
MW:
193.04
EINECS:
628-033-1
Product Categories:
  • All Aliphatics
  • Aliphatics
  • AcrylateCarbonyl Compounds
  • Acrylic Monomers
  • C6 to C7
  • Esters
  • Monomers
  • NULL
  • Benzothiophenes ,Thiophenes
Mol File:
17435-72-2.mol
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ETHYL 2-(BROMOMETHYL)ACRYLATE Chemical Properties

Melting point:
134-136℃
Boiling point:
38 °C0.8 mm Hg(lit.)
Density 
1.398 g/mL at 25 °C(lit.)
refractive index 
n20/D 1.479(lit.)
Flash point:
178 °F
storage temp. 
2-8°C
form 
Liquid
color 
Colorless to pale yellow
BRN 
970108
InChIKey
MTCMFVTVXAOHNQ-UHFFFAOYSA-N
CAS DataBase Reference
17435-72-2(CAS DataBase Reference)
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Safety Information

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36
RIDADR 
UN 2810 6.1 / PGII
WGK Germany 
3
10-19-23
HS Code 
29161900

MSDS

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ETHYL 2-(BROMOMETHYL)ACRYLATE Usage And Synthesis

Chemical Properties

Colourless Oil

Uses

ETHYL 2-(BROMOMETHYL)ACRYLATE is an intermediate used for the synthesis of aza inhibitors of chorismate mutase.

Purification Methods

If it contains some free acid, add H2O, cool, and neutralise with NaHCO3 until evolution of CO2 ceases. Extract the mixture with Et2O (3x) and dry the combined extracts (Na2SO4, 3hours). Evaporate Et2O and distil the ester collecting fraction b 39-40o/0.9mm and check spectra. [Preparation and NMR: Ramarajan et al. Org Synth Coll Vol VII 211 1990, Beilstein 2 IV 1541.]

ETHYL 2-(BROMOMETHYL)ACRYLATESupplier

Changzhou Pesan Chemical Co., Ltd. Gold
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