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Diisopropyl succinate

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Diisopropyl succinate Basic information

Product Name:
Diisopropyl succinate
Synonyms:
  • BUTANEDIOIC ACID, BIS(1-METHYL-ETHYL) ESTER
  • DIPS
  • DIISOPROPYL SUCCINATE
  • SUCCINIC ACID DIISOPROPYL ESTER
  • Bis(1-methylethyl)butanedioate
  • dipropan-2-yl butanedioate
  • Diisopropyl Succinate, 99.0%(GC)
  • Butanedioic acid, 1,4-bis(1-methylethyl) ester
CAS:
924-88-9
MF:
C10H18O4
MW:
202.25
EINECS:
213-110-0
Mol File:
924-88-9.mol
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Diisopropyl succinate Chemical Properties

Melting point:
263.0 °C
Boiling point:
228 °C
Density 
0,99 g/cm3
vapor pressure 
12.2Pa at 25℃
refractive index 
1.4170 to 1.4190
storage temp. 
Sealed in dry,Room Temperature
form 
solid
color 
Colorless to Almost colorless
LogP
2.2
CAS DataBase Reference
924-88-9(CAS DataBase Reference)
NIST Chemistry Reference
Succinic acid diisopropyl ester(924-88-9)
EPA Substance Registry System
Butanedioic acid, bis(1-methylethyl) ester (924-88-9)
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Safety Information

Risk Statements 
36/37/38-52/53
Safety Statements 
26-36/37/39
HS Code 
2917.19.1700
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Diisopropyl succinate Usage And Synthesis

Uses

Diisopropyl Succinate is used in preparation of Heterocyclic Pyrrolopyrrole Diketone quaternary Ammonium Salt as Copper electroplating leveling agent.

Synthesis

110-15-6

67-63-0

924-88-9

In a typical reaction, butanedioic acid (1 mol), isopropanol (1.5-2 mol) and AMA 2:3 (332 g, 0.6 mol) were mixed in a reaction glass tube equipped with a screw cap and a magnetic stirrer until a homogeneous wet mixture was formed. The reaction mixture was placed in a microwave reactor (Anton Parr Monowave 300) and irradiated at 80 °C for 8 min or at 120 °C for 20 min. Upon completion of the reaction, the mixture was cooled, diluted with dichloromethane (41 mL), filtered by gravity and the filtrate was washed with dichloromethane. Subsequently, the filtrate was washed sequentially with saturated sodium carbonate solution (Na2CO3) and water. The organic layer was separated, dried with anhydrous sodium sulfate (Na2SO4), filtered and concentrated under reduced pressure to give diisopropyl succinate.

References

[1] Synthetic Communications, 2014, vol. 44, # 16, p. 2386 - 2392
[2] Phosphorus, Sulfur and Silicon and the Related Elements, 2004, vol. 179, # 6, p. 1187 - 1191
[3] Journal of Organic Chemistry, 1983, vol. 48, # 18, p. 3106 - 3108
[4] Journal of the Chemical Society, 1948, p. 631

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