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Fluorotributyltin

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Fluorotributyltin Basic information

Product Name:
Fluorotributyltin
Synonyms:
  • Fluorotributylstannane
  • FLUOROTRI-N-BUTYLTIN
  • TRIBUTYLTIN FLUORIDE
  • TRIBUTYLTIN FLUORIDE, POLYMER
  • TRI-N-BUTYLFLUOROTIN
  • TRI-N-BUTYLTIN FLUORIDE
  • tributylfluorotin polymer
  • STANNANE,FLUOROTRIBUTYL-
CAS:
1983-10-4
MF:
C12H27FSn
MW:
309.05
EINECS:
217-847-9
Product Categories:
  • Organometallics
  • Alkyl Metals
  • Classes of Metal Compounds
  • Grignard Reagents & Alkyl Metals
  • Sn (Tin) Compounds
  • Synthetic Organic Chemistry
  • Typical Metal Compounds
Mol File:
1983-10-4.mol
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Fluorotributyltin Chemical Properties

Melting point:
269-271 °C(lit.)
Boiling point:
285°C (rough estimate)
Density 
1,28 g/cm3
Flash point:
>150°C
Specific Gravity
1.28
Water Solubility 
Soluble in nonpolar organic solvents. Insoluble in water.
Sensitive 
Moisture Sensitive
Exposure limits
ACGIH: TWA 0.1 mg/m3; STEL 0.2 mg/m3 (Skin)
NIOSH: IDLH 25 mg/m3; TWA 0.1 mg/m3
CAS DataBase Reference
1983-10-4(CAS DataBase Reference)
EPA Substance Registry System
Tributyltin fluoride (1983-10-4)
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Safety Information

Hazard Codes 
T,N
Risk Statements 
21-25-36/38-48/23/25-50/53
Safety Statements 
35-36/37/39-45-60-61
RIDADR 
UN 3261 8/PG 2
WGK Germany 
3
RTECS 
WH8275000
21
TSCA 
Yes
HazardClass 
6.1
PackingGroup 
III

MSDS

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Fluorotributyltin Usage And Synthesis

Uses

Tri-n-butyltin fluoride is a reagent used for the selective desilylation of bis(silyl) enol ethers. It is also used as antifoulant for marine paints; reagent.

General Description

A liquid.

Reactivity Profile

Fluorotributyltin is in the family of tin compounds widely used as stabilizers for plastics, additives to paint(as antifouling agents). Some have catalytic properties. Examples include butyl tin, dibutyl tin oxide. Their main hazard is associated with their high toxicity, in skin adsorption or inhalation. Fluorotributyltin is incompatible with strong oxidizers like: ammonium nitrate, barium nitrate, barium chlorate, etc.

Safety Profile

Poison by ingestion. Many tributyl tin compounds are hghly toxic to marine life. Mutation data reported.When heated to decomposition it emits toxic fumes of F-. See also TIN COMPOUNDS and FLUORIDES.

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