LINALYL CINNAMATE
LINALYL CINNAMATE Basic information
- Product Name:
- LINALYL CINNAMATE
- Synonyms:
-
- 1,5-dimethyl-1-vinyl-4-hexen-1-ocinnamate
- 1,5-dimethyl-1-vinyl-4-hexen-1-ylcinnamate
- 2-propenoicacid,3-phenyl-,1,5-dimethyl-1-vinyl-4-hexen-1-ylester
- 2-Propenoicacid,3-phenyl-,1-ethenyl-1,5-dimethyl-4-hexenylester
- LINALYL CINNAMATE
- FEMA 2641
- 3,7-DIMETHYLOCTA-1,6-DIEN-3-YL (2E)-3-PHENYLPROP-2-ENOATE
- 3-phenyl-2-propenoicacid,1,5-dimethyl-1-vinyl-4-hexen-1-ylester
- CAS:
- 78-37-5
- MF:
- C19H24O2
- MW:
- 284.39
- EINECS:
- 201-110-3
- Product Categories:
-
- ester Flavor
- Mol File:
- 78-37-5.mol
LINALYL CINNAMATE Chemical Properties
- Boiling point:
- 396℃
- Density
- 0.989
- refractive index
- 1.4709 (estimate)
- FEMA
- 2641 | LINALYL CINNAMATE
- Flash point:
- 216℃
- storage temp.
- 2-8°C
- color
- An almost colourless oily or slightly viscous liquid
- Odor
- at 100.00 %. sweet balsam lily neroli labdanum amber
- Odor Type
- balsamic
- JECFA Number
- 668
- LogP
- 6.04
- CAS DataBase Reference
- 78-37-5
- EPA Substance Registry System
- 2-Propenoic acid, 3-phenyl-, 1-ethenyl-1,5-dimethyl-4-hexenyl ester (78-37-5)
LINALYL CINNAMATE Usage And Synthesis
Description
Linalyl cinnamate has a sweet, persistent odor with soft floral notes. It is clearly balsamic. It has a slightly fruity flavor. May be synthesized from linalyl formate plus methylcinnamate and sodium linalool: by "Roche" method from dehydrolinalool and cinnamic acid via the dehydro ester, which is hydrolyzed to the subject compound.
Chemical Properties
Linalyl cinnamate has a sweet, persistent odor with soft floral notes; clearly balsamic. It has a slightly fruity flavor.
Occurrence
Has apparently not been reported to occur in nature
Uses
It is used as a fragrance in soaps, detergents, creams, lotions, and perfumes.
Definition
ChEBI: Linalyl cinnamate is a cinnamate ester.
Preparation
From linalyl formate plus methylcinnamate and sodium linalool; by “Roche” method from dehydrolinalool and cinnamic acid via the dehydro ester, which is hydrolyzed to the subject compound.
Production Methods
Linayl cinnamate is formed from the reaction of linayl formate with methyl cinnamate and linalool sodium or from the reaction of dehydrolinalool with cinnamic acid.
Synthesis
Linalyl cinnamate is prepared:
1) from Linalyl formate plus Methylcinnamate
plus Linalool sodium.
2) from Dehydrolinalool and Cinnamic acid
via the Dehydro-ester, which is hydrolyzed
to the subject ester. ("Roche"-method).
LINALYL CINNAMATESupplier
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LINALYL CINNAMATE(78-37-5)Related Product Information
- 2-Methyl-3-buten-2-ol
- ALLYL CINNAMATE
- 1-HEXEN-3-YL ACETATE
- N-BUTYL CINNAMATE
- Linalyl acetate
- Ethyl linalool
- LINALYL CINNAMATE
- 3-METHYL-1-PENTEN-3-OL
- Linalool
- Propyl cinnamate
- LINALYL FORMATE
- tert-Butyl acrylate
- ALLYL CROTONATE
- CROTONIC ACID ISOPROPYL ESTER
- Isopropyl Cinnamate
- tert-Butylcinnamate
- CROTONIC ACID TERT-BUTYL ESTER
- sec-Butyl Crotonate