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tert-Butyl acrylate

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tert-Butyl acrylate Basic information

Product Name:
tert-Butyl acrylate
Synonyms:
  • tert-butylpropenoate
  • ACRYLIC ACID TERT-BUTYL ESTER
  • TERTIARY-BUTYL ACRYLATE
  • TERT-BUTYL ACRYLATE
  • TBA
  • T-BUTYL ACRYLATE
  • 2-Propenoic acid, 1,1-dimethylethyl ester
  • 2-Propenoicacid,1,1-dimethylethylester
CAS:
1663-39-4
MF:
C7H12O2
MW:
128.17
EINECS:
216-768-7
Product Categories:
  • fine chemical
  • Medical Intermediates
  • A-BAlphabetic
  • Alpha Sort
  • B
  • BI - BZAnalytical Standards
  • AcrylateCarbonyl Compounds
  • Acrylic Monomers
  • Carbonyl Compounds
  • Chemical Class
  • EstersGasoline, Diesel,&Petroleum
  • Olefins
  • Substance classes
  • Volatiles/ Semivolatiles
  • C6 to C7
  • Esters
  • Monomers
  • Pyrazines
  • bc0001
  • K00001
Mol File:
1663-39-4.mol
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tert-Butyl acrylate Chemical Properties

Melting point:
-69°C
Boiling point:
61-63 °C/60 mmHg (lit.)
Density 
0.875 g/mL at 25 °C (lit.)
vapor pressure 
20hPa at 23.4℃
refractive index 
n20/D 1.410(lit.)
Flash point:
63 °F
storage temp. 
Flammables area
solubility 
Chloroform (Slightly), Methanol (Slightly)
form 
Liquid
color 
Clear
Water Solubility 
2 g/L
BRN 
1742329
LogP
2.32 at 25℃
CAS DataBase Reference
1663-39-4(CAS DataBase Reference)
NIST Chemistry Reference
Tert-butyl acrylate(1663-39-4)
EPA Substance Registry System
2-Propenoic acid, 1,1-dimethylethyl ester (1663-39-4)
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Safety Information

Hazard Codes 
F,Xn,N
Risk Statements 
11-20/21/22-37/38-43-52/53-51/53
Safety Statements 
16-25-37-61
RIDADR 
UN 1993 3/PG 2
WGK Germany 
2
10
TSCA 
Yes
HazardClass 
3
PackingGroup 
III
HS Code 
29161290
Hazardous Substances Data
1663-39-4(Hazardous Substances Data)

MSDS

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tert-Butyl acrylate Usage And Synthesis

Chemical Properties

clear liquid

Uses

Monomer for acrylic resins.

Uses

tert-Butyl acrylate is a monomer used in the production of poly(tert-butyl acrylate) polymers, poly(acrylic acid) polyelectrolyte brushes and 3-(3-methyl-but-3-enyloxy)-propionic acid tert-butyl ester. It is also used in paints, coatings, high polymer paper conditioner, nursing polymer products and carbonyl reforming polyolefin. Further, it serves as an important raw material in organic synthesis.

Uses

tert-Butyl acrylate is a monomer used to produce poly(tert-butyl acrylate) (PtBA) polymers and copolymers, and poly(acrylic acid) polyelectrolyte brushes. It undergoes radiation polymerization to form TBA-gels for radio-fluorogenic dose imaging applications. The monomer can be used to synthesize Poly(t-butyl acrylate). It may be used as a reactive diluent in a study.

Preparation

Acrylic acid, strongly acidic cation exchange resin, a polymerization inhibitor A, B polymerization inhibitor, liquefied isobutene was 320 parts by mass of the parts, 35 parts, 20 parts, 5 parts, 430 parts. After a dropping time of 3 hours, the esterification reaction temperature was maintained at 10 ° C. After the addition was completed, 10 ° C was under insulation, and thermal insulation was 7 hours. Quality copies obtained 450 parts of tert-butyl acrylate, and the yield was 99.7%.

Hazard

Toxic by ingestion and inhalation. Flammable, dangerous fire risk.

Flammability and Explosibility

Flammable

tert-Butyl acrylate Preparation Products And Raw materials

Preparation Products

tert-Butyl acrylateSupplier

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