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Fenazaquin

Basic information Safety Supplier Related

Fenazaquin Basic information

Product Name:
Fenazaquin
Synonyms:
  • 4-((4-(1,1-dimethylethyl)phenyl)ethoxy)-quinazolin
  • Fenazaquin 0.1
  • 4-(4-(tert-Butyl)phenethoxy)quinazoline
  • 4-(4-(tert-Butyl)
  • phenethoxy)
  • Quetiapine mite ether
  • 4-((4-(1,1-dimethylethyl)phenyl)ethoxy)quinazoline
  • 4-(2-(4-(1,1-dimethylethyl)phenyl)ethoxy)quinazoline
CAS:
120928-09-8
MF:
C20H22N2O
MW:
306.4
EINECS:
410-580-0
Product Categories:
  • AcaricidesPesticides&Metabolites
  • Alpha sort
  • E-GAlphabetic
  • F
  • FA - FL
  • Pesticides
  • Pesticides&Metabolites
Mol File:
120928-09-8.mol
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Fenazaquin Chemical Properties

Melting point:
70-71° (Dreikorn); mp 77.5-80.0° (Gambie)
Boiling point:
447.01°C (rough estimate)
Density 
1.0970 (rough estimate)
vapor pressure 
3.4 x l0-6 Pa (25 °C)
refractive index 
1.5700 (estimate)
storage temp. 
Sealed in dry,Room Temperature
solubility 
Chloroform (Slightly), Ethyl Acetate (Slightly)
Water Solubility 
0.102 mg l-1 (20 °C, pH 7)
pka
2.88±0.30(Predicted)
BRN 
8331263
LogP
5.510
CAS DataBase Reference
120928-09-8(CAS DataBase Reference)
EPA Substance Registry System
Fenazaquin (120928-09-8)
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Safety Information

Hazard Codes 
T,N
Risk Statements 
20-25-50/53
Safety Statements 
37-45-60-61
RIDADR 
UN 2811 6.1/PG 3
WGK Germany 
3
RTECS 
VA1382000
Hazardous Substances Data
120928-09-8(Hazardous Substances Data)
Toxicity
LD50 orally in rats, mice (mg/kg): 134, 1480; dermally in rabbits (mg/kg): >5000; LC50 (96 hr) in bluegill, trout (mg/l): 34.1, 3.8 (Longhurst)

MSDS

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Fenazaquin Usage And Synthesis

Uses

Fenazaquin is a non-systemic acaricide/insecticide used widely in controlling mites and other related pests in fruits, vegetables and tea.

Uses

Fenazaquin is an acaricide mainly used for control of mites (Eutetranychus, Panonychus and Tetranychus spp.) on pome and citrus fruits and glasshouse-grown ornamental plants.

Uses

Acaricide and insecticide.

Definition

ChEBI: Fenazaquin is a member of quinazolines. It has a role as an acaricide and a mitochondrial NADH:ubiquinone reductase inhibitor.

Metabolic pathway

Fenazaquin is a lipophilic compound and hence is immobile in soils and is not translocated in plants. The main pathways of metabolism involve cleavage of the bridging group between the quinazoline and phenyl rings, oxidation of the tert-butyl sustituent and of the heterocyclic portion of the quinazoline ring and cleavage of that ring. Most of the information is taken from a pamphlet produced by the manufacturer of the compound in which full experimental details were not given (DowElanco, 1993).

Degradation

Fenazaquin is hydrolysed under acidic conditions but the rate is slow under neutral and alkaline conditions. Half-lives were 8,442 and 584 days (22 °C) at pH values of 5, 7 and 9, respectively. Hydrolysis occurs by cleavage of the ether linkage to form quinazolin-2-ol (2) and an alcohol (3) as shown in Scheme 1. The major route of degradation in aquatic environments is by photolysis, the main products (2 and 3) being formed by cleavage of the ether lmkage and include the alkene (4) (DowElanco, 1993).

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