2-Chloro-1,3-dimethylimidazolidinium hexafluorophosphate
2-Chloro-1,3-dimethylimidazolidinium hexafluorophosphate Basic information
- Product Name:
- 2-Chloro-1,3-dimethylimidazolidinium hexafluorophosphate
- Synonyms:
-
- 2-CHLORO-1,3-DIMETHYL-2-IMIDAZOLINIUM HEXAFLUOROPHOSPHATE
- 2-CHLORO-1,3-DIMETHYLIMIDAZOLIDINIUM HEXAFLUOROPHOSPHATE
- 2-CHLORO-1,3-DIMETHYLIMIDAZOLINIUM HEXAFLUOROPHOSPHATE
- 2-CHLORO-1,3-DIMETHYLIMIDAZOLINIUM PF6
- CIP
- 2-Chlor-1,3-dimethyl-imidazolidinium-hexafluorophosphat
- 2-CHLORO-1,3-DIMETHYLIMIDAZOLINIUM HEXAFLUOROPHOSPHATE 98+%
- 2-Chloro-1,3-dimethy
- CAS:
- 101385-69-7
- MF:
- C5H10ClN2.F6P
- MW:
- 278.56
- EINECS:
- 628-484-4
- Product Categories:
-
- Biochemistry
- Condensation & Active Esterification
- Coupling Reactions (Peptide Synthesis)
- Peptide Synthesis
- Synthetic Organic Chemistry
- Mol File:
- 101385-69-7.mol
2-Chloro-1,3-dimethylimidazolidinium hexafluorophosphate Chemical Properties
- Melting point:
- 231-233 °C (lit.)
- storage temp.
- Keep in dark place,Sealed in dry,Room Temperature
- solubility
- acetonitrile: 0.1 g/mL, clear
- form
- powder to crystal
- color
- White to Almost white
- Sensitive
- Moisture & Light Sensitive
- BRN
- 5369058
- InChI
- InChI=1S/C5H10ClN2.F6P/c1-7-3-4-8(2)5(7)6;1-7(2,3,4,5)6/h3-4H2,1-2H3;/q+1;-1
- InChIKey
- CNAKHAGVVMOXFE-UHFFFAOYSA-N
- SMILES
- [P-](F)(F)(F)(F)(F)F.C1(Cl)=[N+](C)CCN1C
- CAS DataBase Reference
- 101385-69-7(CAS DataBase Reference)
MSDS
- Language:English Provider:SigmaAldrich
2-Chloro-1,3-dimethylimidazolidinium hexafluorophosphate Usage And Synthesis
Chemical Properties
White crystalline powder
Uses
Reactant for synthesis of:
Diazo-transfer reagents
Reagent for synthesis of:
Cannabinoid CB1 receptor agonists
Selective small-molecule melanocortin-4 receptor agonists
Imidazoles as selective cannabinoid CB2 receptor antagonists
Cyclic alpha-peptoids
Cyclic melanotropin peptide analogues selective for the human melanocortin-4 receptor
General Description
2-Chloro-1,3-dimethylimidazolidinium hexafluorophosphate is a reagent used for the coupling and esterification of sterically hindered amino acids.[1]
reaction suitability
reaction type: Coupling Reactions
Solubility in organics
2-Chloro-1,3-dimethylimidazolidinium hexafluorophosphate is soluble in DMF; partially soluble in H2O, MeOH, EtOAc, CH2Cl2, and CHCl3.
storage
2-Chloro-1,3-dimethylimidazolidinium hexafluorophosphate (CIP) can be stored refrigerated for at least 5 years without loss of reactivity. CIP is an irritant and should be used in a fumehood, when possible.
References
1. (a) Humphery, J. M.; Chamberlin, R., Chem. Rev. 1997, 97, 2243. (b) Albericio, F.; Carpino, L. A., Methods Enzymol. 1997, 289, 104
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2-Chloro-1,3-dimethylimidazolidinium hexafluorophosphate(101385-69-7)Related Product Information
- Chlorodimethylphenylsilane
- tert-Butyldimethylsilyl chloride
- 2-Chloro-1,3-dimethylimidazolidinium chloride
- 2-Fluoro-1,3-dimethylimidazolidinium hexafluorophosphate
- 2-Chloro-1,3-dimethylimidazolidinium tetrafluoroborate
- Tetramethylguanidine
- tert-Butyl carbamate
- Potassium hexafluorophosphate
- Lithium hexafluorophosphate
- Difluorochloromethane
- Hexafluorophosphate
- Hexafluorophosphoric acid
- CHLORO-N,N,N',N'-TETRAMETHYLFORMAMIDINIUM HEXAFLUOROPHOSPHATE
- 2-Chloro-1,3-dimethylimidazolidinium hexafluorophosphate