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GERANYL CAPROATE

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GERANYL CAPROATE Basic information

Product Name:
GERANYL CAPROATE
Synonyms:
  • (2E)-3,7-Dimethyl-2,6-octadienyl hexanoate
  • (E)-3,7-Dimethylocta-2,6-dien-1-yl n-hexanoate
  • (e)-3,7-dimethylocta-2,6-dien-1-yln-hexanoate
  • 2,6-Octadien-1-ol, 3,7-dimethyl-, hexanoate, (E)-
  • 3,7-dimethyl-,hexanoate,(e)-6-octadien-1-ol
  • 3,7-dimethyl-2,6-octadienylester,(e)-hexanoicaci
  • 3,7-dimethylocta-2,6-dien-1-ylester,(e)-hexanoicaci
  • Geranyl hexanoate
CAS:
10032-02-7
MF:
C16H28O2
MW:
252.39
EINECS:
233-102-0
Product Categories:
  • C15 to C19
  • Building Blocks
  • Chemical Synthesis
  • Ethers
  • New Products for Chemical Synthesis
  • Organic Building Blocks
  • Oxygen Compounds
Mol File:
10032-02-7.mol
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GERANYL CAPROATE Chemical Properties

Boiling point:
335.57°C (rough estimate)
Density 
0.892 g/mL at 25 °C
refractive index 
n20/D1.462
FEMA 
2515 | GERANYL HEXANOATE
Flash point:
93℃
color 
A colourless oily liquid.
Odor
at 100.00 %. rose geranium fruity waxy
Odor Type
floral
JECFA Number
70
LogP
6.23
EPA Substance Registry System
Hexanoic acid, (2E)-3,7-dimethyl-2,6-octadienyl ester (10032-02-7)
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Safety Information

WGK Germany 
2
RTECS 
RG5926000
Toxicity
Both the acute oral LD50 value in rats and the acute dermal LD50 value in rabbits exceeded 5 g/kg (Moreno, 1975).
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GERANYL CAPROATE Usage And Synthesis

Description

Geranyl hexanoate has a rose-geranium odor with a strong undertone reminiscent of pineapple and banana.

Chemical Properties

Geranyl hexanoate has a rose-geranium odor with a strong undertone reminiscent of pineapple and banana.

Occurrence

Reported found in the essential oil of palmarosa and in the leaves of Phebalium dentatum Also reported found in pawpaw, purple passion fruit, kumquat peel oil and babaco fruit (Carica pentagona Heilborn)

Uses

Occasionally used in perfume compositions for variations in the heavier, sweet-exotic floral fragrance types such as Ylang Ylang, Ginger Lily and Wistaria, and also in Magnolia, Peony, Freesia, etc. in more modest amounts.

Preparation

By an exchange reaction between methyl caproate and geraniol in the presence of a catalyst or sodium methylate.

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