STANNOUS ACETATE Chemical Properties

Melting point:

180-182 °C(lit.)

Boiling point:

155°C 0,1mm

Density 

2,31 g/cm³

storage temp. 

Inert atmosphere,Room Temperature

solubility 

DMSO (Slightly), Methanol (Slightly)

form 

Powder

color 

White

Specific Gravity

2.11

Water Solubility 

Decomposes in water. Soluble in dilute HClSoluble in dilute hydrochloric acid, dimethyl sulfoxide and methanol.

Hydrolytic Sensitivity

7: reacts slowly with moisture/water

Sensitive 

Hygroscopic

Merck 

14,8781

Exposure limits

ACGIH: TWA 0.1 mg/m3; STEL 0.2 mg/m3 (Skin)
NIOSH: IDLH 25 mg/m3; TWA 0.1 mg/m3

InChI

1S/2C2H4O2.Sn/c2*1-2(3)4;/h2*1H3,(H,3,4);/q;;+2/p-2

InChIKey

PNOXNTGLSKTMQO-UHFFFAOYSA-L

SMILES

CC(=O)O[SnH2]OC(C)=O

CAS DataBase Reference

638-39-1(CAS DataBase Reference)

Safety Information

Hazard Codes 

Xn

Risk Statements 

20/21/22

Safety Statements 

36

RIDADR 

UN 3146 6.1/PG 3

WGK Germany 

3

TSCA 

No

HazardClass 

6.1

PackingGroup 

III

HS Code 

2915290000

Storage Class

6.1C - Combustible acute toxic Cat.3
toxic compounds or compounds which causing chronic effects

Hazard Classifications

Acute Tox. 4 Dermal
Acute Tox. 4 Inhalation
Acute Tox. 4 Oral

MSDS

• Language:English Provider:ACROS
• Language:English Provider:SigmaAldrich
• Language:English Provider:ALFA

STANNOUS ACETATE Usage And Synthesis

Chemical Properties

STANNOUS ACETATE is white to light beige powder

Uses

Reducing agent.

Uses

Tin(II) acetate is used as a precursor in the production of tin anode, Sn-Cu bimetallic nanoparticles, high surface area tin oxide catalysts. It acts as Lewis acid catalysts for the esterification and transesterification reactions. It serves as an efficient catalytic system for carbon-hydrogen activation of methoxy group of anisole in presence of palladium(II) acetate. It plays an important role in stannous oral care compositions.

Uses

STANNOUS ACETATE is used in stannous oral care compositions.

Hazard

Toxic by ingestion.

reaction suitability

core: tin
reagent type: catalyst

Synthesis

A process for the preparation of stannous acetate (propyl hydrocarbon propionate), characterized in that it includes the following specific steps: (1) Weighing stannous oxide, weighing deionized water at a mass ratio of 1-2:1 with stannous oxide, and adding it to a reaction kettle; (2) Turn on the stirring, slowly add the weighed stannous oxide in step (1); (3) Increase the temperature, until the temperature rises to 75-85 ?? C gradually add glacial acetic acid solution, stirring while adding, within 30min to complete the addition; (4) Continue to heat up to 95-100 ?? C, hold 3h; (6)Maintain the temperature 100 ?? insulation, distillation under reduced pressure, to no low-boiling material distillation, the material is white solid to stop distillation; (6) stop, take out the product, crushed in 100 ?? oven drying that is the desired stannous acetate (hydrocarbon propionate) products.

STANNOUS ACETATE(638-39-1)Related Product Information

• TIN(IV) ACETATE
• Lithium acetate
• Sodium acetate
• Bornyl acetate
• CADMIUM ACETATE HYDRATE
• Hydrazine acetate
• Cobalt acetate
• Ruthenium acetate
• Lead acetate trihydrate
• Guanidineacetic acid
• STRONTIUM ACETATE
• Potassium Acetate
• MANGANESE(II) ACETATE
• PENTAFLUOROPHENYL ACETATE
• LUTETIUM ACETATE
• RUBIDIUM ACETATE
• Silver acetate
• Magnesium acetate