DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM (II)
DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM (II) Basic information
- Product Name:
- DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM (II)
- Synonyms:
-
- Dichloro〔(R)-(+)-2,2-bis(diphenylphosphino)-1,1-binaphthyl)ruthenium(Ⅱ)
- Dichloro[(R)-(+)-2,2'-bis(diphenylphosphino)-1, 1'-binaphthyl]ruthenium(II), min. 95%
- Dichloro[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II),98% [(R)-BINAP]RuCl2
- [(R)-BINAP]RUCL2
- (R)-[2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl]dichlororuthenium(II)
- [(R)-(+)-2,2'-Bis-(diphenylphosphino)-1,1'-binaphthyl] ruthenium dichloride
- Dichloro[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]rutheniuM(II),95% [(R)-BINAP]RuCl2
- Dichloro [(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphathyl] rutheniuM(II)
- CAS:
- 132071-87-5
- MF:
- C44H32Cl2P2Ru
- MW:
- 794.65
- EINECS:
- 623-973-9
- Product Categories:
-
- Ru
- Catalysts for Organic Synthesis
- Classes of Metal Compounds
- Homogeneous Catalysts
- Metal Complexes
- Ru (Ruthenium) Compounds
- Synthetic Organic Chemistry
- Transition Metal Compounds
- Mol File:
- 132071-87-5.mol
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DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM (II) Chemical Properties
- Melting point:
- >300 ºC
- storage temp.
- under inert gas (nitrogen or Argon) at 2-8°C
- form
- Powder
- color
- orange
- Sensitive
- air sensitive
- InChI
- InChI=1S/C44H32P2.2ClH.Ru/c1-5-19-35(20-6-1)45(36-21-7-2-8-22-36)41-31-29-33-17-13-15-27-39(33)43(41)44-40-28-16-14-18-34(40)30-32-42(44)46(37-23-9-3-10-24-37)38-25-11-4-12-26-38;;;/h1-32H;2*1H;/q;;;+2/p-2
- InChIKey
- YEKBVMDAGDTOQB-UHFFFAOYSA-L
- SMILES
- C1(C2C3C=CC=CC=3C=CC=2P(C2=CC=CC=C2)C2=CC=CC=C2)C2C=CC=CC=2C=CC=1P(C1=CC=CC=C1)C1C=CC=CC=1.[Ru](Cl)Cl
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Safety Information
- Hazard Codes
- Xi
- Risk Statements
- 36/37/38
- Safety Statements
- 26-36/37/39-36/37
- HS Code
- 2931.90.6000
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DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM (II) Usage And Synthesis
Reaction
- Enantioselective catalyst for the asymmetric hydrogenation of α,β-unsaturated olefins.
- Efficient catalyst for the asymmetric reduction of carbonyl groups, such as β-ketoesters.
Uses
(R)?-?[2,?2''-?Bis(diphenylphosphin?o)?-?1,?1''-?binaphthyl]?dichlororuthenium is a catalyst used in the synthesis of helicobacter pylori lipopolysaccharide structures displaying anti-inflammatory activiy.
DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM (II)Supplier
xinxiang runyu material co.,Ltd Gold
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- 15690792173
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Leshan Bangsheng New Materials Co., Ltd Gold
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- 0833-2599138 19162614312
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J & K SCIENTIFIC LTD.
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TCI (Shanghai) Development Co., Ltd.
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- 021-67121386
- Sales-CN@TCIchemicals.com
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DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM (II)(132071-87-5)Related Product Information
- DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM (II)
- Dichloro(p-cymene)ruthenium(II) dimer
- [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II)
- [1,2-Bis(diphenylphosphino)ethane]dichloropalladium(II)
- [(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]PALLADIUM(II) CHLORIDE
- Dichloro[(R)-(+)-2,2’-bis(diphenylphosphino)-1,1-binaphthyl]paltinum(II)
- Dichloro[(S)-(-)-2,2’-bis(diphenylphosphino)-1,1-binaphthyl]paltinum(II)
- DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM (II)
- (S)-(-)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl
- 1,1'-BINAPHTHYL
- Ruthenium(IV) oxide hydrate
- Ruthenium dioxide
- Dichloro{(S)-(-)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(2S)-(+)-1,1-bis(4-methoxyphenyl)-3-methyl-1,2-butanediamine]ruthenium(II)
- Dichloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(2R)-(-)-1,1-bis(4-methoxyphenyl)-3-methyl-1,2-butanediamine]ruthenium(II)
- Chloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}(p-cymene)ruthenium(II)chloride
- DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL][(1R,2R)-(+)-1,2-DIPHENYLETHYLENEDIAMINE]RUTHENIUM (II)
- Dimethylammoniumdichlorotri(mu-chloro)bis[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]diruthenate(II)
- (R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHALENECHLORO(P-CYMENE)RUTHENIUM CHLORIDE