Basic information Reaction Safety Supplier Related

2,8,9-TRIMETHYL-2,5,8,9-TETRAAZA-1-PHOSPHABICYCLO[3.3.3]UNDECANE

Basic information Reaction Safety Supplier Related

2,8,9-TRIMETHYL-2,5,8,9-TETRAAZA-1-PHOSPHABICYCLO[3.3.3]UNDECANE Basic information

Product Name:
2,8,9-TRIMETHYL-2,5,8,9-TETRAAZA-1-PHOSPHABICYCLO[3.3.3]UNDECANE
Synonyms:
  • 2,8,9-TRIMETHYL-2,5,8,9-TETRAAZA-1-PHOSPHABICYCLO[3.3.3]UNDECANE
  • 2,8,9-TRIMETHYL-2,5,8,9-TETRAAZA-1- &
  • 2,89-Trimethyl-2,5,89-tetraaza-1-phosphabicyclo[3.3.3]undecaneverkadesuperbase
  • VERKADE SUPERBASE
  • 2,8,9-Trimethyl-1-phospha-2,5,8,9-tetraazabicyclo[3.3.3]undecane
  • Verkadebase
  • 4,6,11-trimethyl-1,4,6,11-tetraza-5-phosphabicyclo[3.3.3]undecane
  • 2,5,8,9-Tetraaza-1-phosphabicyclo[3.3.3]undecane, 2,8,9-trimethyl-
CAS:
120666-13-9
MF:
C9H21N4P
MW:
216.26
Product Categories:
  • Achiral Phosphine
  • Alkyl Phosphine
  • organophosphine ligand
Mol File:
120666-13-9.mol
More
Less

2,8,9-TRIMETHYL-2,5,8,9-TETRAAZA-1-PHOSPHABICYCLO[3.3.3]UNDECANE Chemical Properties

Melting point:
110-115 °C(lit.)
Boiling point:
263.9±39.0 °C(Predicted)
pka
10.43±0.20(Predicted)
form 
solid
color 
white waxy
Sensitive 
moisture sensitive, store cold
BRN 
4970285
More
Less

Safety Information

WGK Germany 
3
More
Less

2,8,9-TRIMETHYL-2,5,8,9-TETRAAZA-1-PHOSPHABICYCLO[3.3.3]UNDECANE Usage And Synthesis

Reaction

Exceedingly strong, non-ionic Brønsted and Lewis base useful in a variety of organic transformations.

Uses

2,8,9-Trimethyl-2,5,8,9-tetraaza-1-phosphabicyclo[3.3.3]undecane (CAS# 120666-13-9) is a useful catalyst for the direct α-?arylation of nitriles with aryl chlorides and aryl bromides. It is also used as a catalyst in carbon dioxide reduction to methylamines under metal-free conditions.

2,8,9-TRIMETHYL-2,5,8,9-TETRAAZA-1-PHOSPHABICYCLO[3.3.3]UNDECANE Preparation Products And Raw materials

Preparation Products

2,8,9-TRIMETHYL-2,5,8,9-TETRAAZA-1-PHOSPHABICYCLO[3.3.3]UNDECANESupplier

J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Email
jkinfo@jkchemical.com
Energy Chemical
Tel
021-021-58432009 400-005-6266
Email
sales8178@energy-chemical.com
Bide Pharmatech Ltd.
Tel
400-164-7117 13681763483
Email
product02@bidepharm.com
Jiangsu Aikon Biopharmaceutical R&D co.,Ltd.
Tel
025-66113011 18112977050
Email
cb6@aikonchem.com
Sigma-Aldrich
Tel
021-61415566 800-8193336
Email
orderCN@merckgroup.com