Basic information Uses Safety Supplier Related
ChemicalBook >  Product Catalog >  Chemical Reagents >  Organic reagents >  Phosphorus-containing compound >  2,8,9-Tri-i-butyl-2,5,8,9-tetraaza-1-phosphabicyclo[3.3.3]undecane

2,8,9-Tri-i-butyl-2,5,8,9-tetraaza-1-phosphabicyclo[3.3.3]undecane

Basic information Uses Safety Supplier Related

2,8,9-Tri-i-butyl-2,5,8,9-tetraaza-1-phosphabicyclo[3.3.3]undecane Basic information

Product Name:
2,8,9-Tri-i-butyl-2,5,8,9-tetraaza-1-phosphabicyclo[3.3.3]undecane
Synonyms:
  • 2,8 9-TRI-I-BUTYL-2,5,8 9-TETRAAZA-1-PHOSPHABICYCLO[3.3.3]UNDECANE
  • 2,8,9-TRIISOBUTYL-2,5,8,9-TETRAAZA-1-PHOSPHABICYCLO[3.3.3]UNDECANE
  • 2,8,9-Triisobutyl-2,5,8,9-tetraaza-1-phosphabicyclo[3.3.3]undecane,97%
  • Triisobutylazaphosphatrane
  • 2,8,9-Triisobutyl-2,5,8,9-tetraaza-1-phosphabicyclo[3.3.3]undecane 97%
  • 2,8,9-Triisobutyl-2,5,8,9-tetraaza-1-phosphabicyclo[3.3.3]undecane solution
  • 2,8,9-Tris(2-methylpropyl)-2,5,8,9-tetraaza-1-phosphabicyclo[3.3.3]undecane
  • 4,6,11-tris(2-methylpropyl)-1,4,6,11-tetraza-5-phosphabicyclo[3.3.3]undecane
CAS:
331465-71-5
MF:
C18H39N4P
MW:
342.5
Product Categories:
  • organophosphine ligand
Mol File:
331465-71-5.mol
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2,8,9-Tri-i-butyl-2,5,8,9-tetraaza-1-phosphabicyclo[3.3.3]undecane Chemical Properties

Boiling point:
397.4±41.0 °C(Predicted)
Density 
0.964 g/mL at 25 °C(lit.)
refractive index 
n20/D 1.5020(lit.)
Flash point:
155 °F
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
pka
8.90±0.20(Predicted)
form 
Liquid
color 
Clear colorless to yellow
Sensitive 
air sensitive, moisture sensitive
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Safety Information

Hazard Codes 
F,Xn
Risk Statements 
36/37/38-67-66-22-19-11
Safety Statements 
26-36/37/39-16
RIDADR 
UN1155 - class 3 - PG 1 - Diethyl ether
WGK Germany 
3
HS Code 
29310099

MSDS

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2,8,9-Tri-i-butyl-2,5,8,9-tetraaza-1-phosphabicyclo[3.3.3]undecane Usage And Synthesis

Uses

Exceedingly strong, non-ionic Brønsted and Lewis base useful in a variety of organic transformations.

Chemical Properties

Clear colorless to yellow liquid

Uses

Triisobutylazaphosphatrane is reported to be used as a catalyst for the preparation of biaryl and alkenylarenes via Stille cross-coupling reaction. It also acts a catalyst for the synthesis of α-aryl-substituted nitriles.

2,8,9-Tri-i-butyl-2,5,8,9-tetraaza-1-phosphabicyclo[3.3.3]undecane Preparation Products And Raw materials

Preparation Products

2,8,9-Tri-i-butyl-2,5,8,9-tetraaza-1-phosphabicyclo[3.3.3]undecaneSupplier

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