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4-Vinylbenzyl chloride

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4-Vinylbenzyl chloride Basic information

Product Name:
4-Vinylbenzyl chloride
Synonyms:
  • 1-(chloromethyl)-4-ethenyl-benzen
  • 1-(chloromethyl)-4-ethenyl-Benzene
  • 4-(CHLOROMETHYL)STYRENE
  • 4-VINYLBENZYL CHLORIDE
  • 1-(chloromethyl)-4-vinylbenzene
  • 4-VINYLBENZYL CHLORIDE, STAB.
  • 4-Vinylbenylchloride
  • 4-Vinylbenzyl chloride, tech., 90%
CAS:
1592-20-7
MF:
C9H9Cl
MW:
152.62
EINECS:
216-471-2
Product Categories:
  • Chloromethy styrene
  • Acyclic
  • Alkenes
  • Building Blocks
  • Chemical Synthesis
  • Organic Building Blocks
  • Intermediates of Dyes and Pigments
Mol File:
1592-20-7.mol
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4-Vinylbenzyl chloride Chemical Properties

Boiling point:
229 °C(lit.)
Density 
1.083 g/mL at 25 °C(lit.)
vapor density 
5.3 (vs air)
vapor pressure 
1 mm Hg ( 56.1 °C)
refractive index 
n20/D 1.572(lit.)
Flash point:
221 °F
storage temp. 
2-8°C
Water Solubility 
Insoluble in water
form 
Liquid
color 
Clear yellow
BRN 
2204384
InChIKey
ZRZHXNCATOYMJH-UHFFFAOYSA-N
CAS DataBase Reference
1592-20-7(CAS DataBase Reference)
EPA Substance Registry System
Benzene, 1-(chloromethyl)-4-ethenyl- (1592-20-7)
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Safety Information

Hazard Codes 
C
Risk Statements 
34-43-21/22
Safety Statements 
26-36/37/39-45
RIDADR 
UN 3265 8/PG 3
WGK Germany 
3
8-19
HazardClass 
8
PackingGroup 
III
HS Code 
29039990

MSDS

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4-Vinylbenzyl chloride Usage And Synthesis

Chemical Properties

clear yellow liquid

Uses

Component of ion exchange resins, photo-resist polymers, cross-linkable fibers, coupling agents and electroconducting polymers.
Starter for various copolymer preparations.
Dual functional monomer. Readily derivatized by chloride displacement.

Purification Methods

Purify 4-vinylbenzyl chloride by dissolving it in Et2O, washing it with 0.5% of aqueous NaOH, separating, drying the organic layer (Na2SO4), evaporating and distilling the residual oil under N2 in vacuo. Add 0.05% of 4-tert-butylcatechol as stabilizer. It is lachrymatory. [Nishikubo et al. Tetrahedron Lett 22 3872 1981, Tanimoto et al. Synth Commun 4 193 1974, Beilstein 6 IV 3818.]

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